光谱学与光谱分析 |
|
|
|
|
|
Adsorption Behaviors of Protonation Modified Chitosan and the Analysis of Spectra |
GUO Ying-juan, XUE Juan-qin, ZHANG Jie, MA Jing, QUAN Xue-ting, LIU Yao |
School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China |
|
|
Abstract In order to improve adsorbing performance and stability of chitosan in acid simultaneously, cross-linking was employed after the protection of amino groups for improving its stability, then the protection of amino groups was removed and protonated to obtain high adsorption performance. With formaldehyde as amino-group protective agent and glutaraldehyde as cross-linking reagent, cross-linked chitosan(CCTS) was prepared by reversed phase suspension method in this paper, then it was protonated to make protonation modified chitosan adsorbent(P-CCTS). The adsorption performance of sulfate ion onto P-CCTS was firstly studied and investigated by static adsorption test. Elemental analysis by energy dispersive spectrometer of X-rays (EDS) and identifying of functional groups by Fourier transform infrared spectroscopy (FTIR) were used to analyze the preparation and adsorption of the adsorbent, and the reaction mechanism of cross-linking and adsorption was investigated. The results show that the adsorption performance of P-CCTS towards sulfate ion is 10 times higher than that of unmodified chitosan, and formaldehyde and glutaraldehyde mainly react with amino (—NH2) and part of hydroxy (C6—OH) of chitosn. A salt of chitosan protonated amino chlorine was formed through the process of the protonation of amino, the adsorption of sulfate ion mainly occurs on the protonated amino on which ion exchange happened between chlorine ion and sulfate ion.
|
Received: 2013-04-03
Accepted: 2013-07-10
|
|
Corresponding Authors:
GUO Ying-juan
E-mail: asha_001@126.com
|
|
[1] Wan Ngah W S, Teong L C, Hanafiah M A K M. Carbohydrate Polymers, 2011, 83(4): 1446. [2] Miretzky P, Cirelli A F. Journal of Fluorine Chemistry, 2011, 132(4): 231. [3] LI Yong-fu, MENG Fan-ping, DU Xiu-ping, et al(李永福, 孟范平, 杜秀萍,等). Periodical of Ocean University of China(中国海洋大学学报), 2012, 42(6): 35. [4] Xie Yanhua, Li Shiyu, Wang Fei, et al. Chemical Engineering Journal, 2010, 156(1): 56. [5] Viswanathan Natrayasamy, Sundaram C Sairam, Meenakshi S. Journal of Hazardous Materials, 2009, 161(1-3): 423. [6] Guo Yingjuan, Xue Juanqin, Bi Qiang, et al. Advanced Materials Research, 2010, 160-162: 1797. [7] Wade L G Jr. Organic Chemistry(有机化学). Translated by WAN You-zhi, et al(万有志,等译). Beijing:Chemical Industry Press(北京:化学工业出版社), 2006. 776. [8] MENG Fan-ping, YI Huai-chang(孟范平, 易怀昌). Chemical Industry and Engineering Progress(化工进展), 2009, 28(10): 1861. [9] LI Yan-mei, ZHAO Sheng-yin, WANG Lan-ying(李艳梅, 赵圣印, 王兰英). Organic Chemistry(有机化学). Beijing: Science Press(北京: 科学出版社), 2011. 165. [10] Anitha A, Deepagan V G, Divya Rani V V, et al. Carbohydrate Polymers, 2011, 84(3): 1158. |
[1] |
CHENG Jia-wei1, 2,LIU Xin-xing1, 2*,ZHANG Juan1, 2. Application of Infrared Spectroscopy in Exploration of Mineral Deposits: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 15-21. |
[2] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
[3] |
YANG Cheng-en1, 2, LI Meng3, LU Qiu-yu2, WANG Jin-ling4, LI Yu-ting2*, SU Ling1*. Fast Prediction of Flavone and Polysaccharide Contents in
Aronia Melanocarpa by FTIR and ELM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 62-68. |
[4] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
[5] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
[6] |
BAO Hao1, 2,ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
[7] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
[8] |
LI Xiao-dian1, TANG Nian1, ZHANG Man-jun1, SUN Dong-wei1, HE Shu-kai2, WANG Xian-zhong2, 3, ZENG Xiao-zhe2*, WANG Xing-hui2, LIU Xi-ya2. Infrared Spectral Characteristics and Mixing Ratio Detection Method of a New Environmentally Friendly Insulating Gas C5-PFK[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3794-3801. |
[9] |
HU Cai-ping1, HE Cheng-yu2, KONG Li-wei3, ZHU You-you3*, WU Bin4, ZHOU Hao-xiang3, SUN Jun2. Identification of Tea Based on Near-Infrared Spectra and Fuzzy Linear Discriminant QR Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3802-3805. |
[10] |
LIU Xin-peng1, SUN Xiang-hong2, QIN Yu-hua1*, ZHANG Min1, GONG Hui-li3. Research on t-SNE Similarity Measurement Method Based on Wasserstein Divergence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3806-3812. |
[11] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
[12] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
[13] |
DANG Rui, GAO Zi-ang, ZHANG Tong, WANG Jia-xing. Lighting Damage Model of Silk Cultural Relics in Museum Collections Based on Infrared Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3930-3936. |
[14] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
[15] |
LUO Li, WANG Jing-yi, XU Zhao-jun, NA Bin*. Geographic Origin Discrimination of Wood Using NIR Spectroscopy
Combined With Machine Learning Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3372-3379. |
|
|
|
|