胺化葡萄糖及其铜配合物的光谱特性

doi:10.3964/j.issn.1000-0593(2008)11-2588-04

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Abstract Characteristics of an aminated glucose and its complex with Cu (Ⅱ) were investigated by FTIR, ¹H-NMR and UV spectroscopy, respectively. Compared with glucose, the FTIR spectrum of an aminated glucose showed a moderate peak at 1 629-1 608 cm^-1 which was attributed to δ_NH vibration, suggesting that glucose reacted with ethylenediamine. The ¹H-NMR spectrum of an aminated glucose demonstrated the signal of the C₁ hydroxy proton and one of the amino proton at 4.82-4.79 ppm, illustrating that the amino of ethylenediamine was substituted for the hydroxy group of C₁. As for UV spectra, an aminated glucose did not show absorbance in the ultraviolet region while its complex with Cu(Ⅱ) had obvious absorption peak at about 236 nm. The complex ratio of the aminated glucose to Cu(Ⅱ) was about 1 to 1 and the stability constant of its Cu(Ⅱ) complex was 6.8×10⁷ L·mol^-1.

Key words：D-glucose;Ethylenediamine;Complex;Spectroscopy

Received: 2007-09-26 Accepted: 2007-12-28

ZTFLH:

O629.1

Corresponding Authors: LIAO Qiang-qiang E-mail: liaoqq1971@yahoo.com.cn

Cite this article:

LIAO Qiang-qiang,LI Yi-jiu,XIANG Bo, et al. Spectra Characteristics of an Aminated Glucose and Its Complex with Cu(Ⅱ)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(11): 2588-2591.

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https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2008)11-2588-04 OR https://www.gpxygpfx.com/EN/Y2008/V28/I11/2588

[1] Kim B S, Lim S T. Carbohydrate Polym., 1999, 39(3): 217.
[2] Zhang Xiaodong, Liu Xin, Li Wenying. J. Appl. Polym. Sci., 2003, 89(11): 3016.
[3] Xu Shi-mei, Feng Shun, Yue Fan, et al. J. Appl. Polym. Sci., 2004, 92(2): 728.
[4] WANG Yu-qin, YANG Wei, CUI Dan(王玉芹, 杨巍, 崔丹). Acta Polymerica Sinica(高分子学报)，1996，(1)：111.
[5] JIN Man-tong(金漫彤). Technology of Water Treatment(水处理技术)， 2001, 27(3)：167.
[6] Carol K W, Gene H, Bram R, et al. J. Appl. Polym. Sci., 1986, 31(6): 1797.
[7] XIANG Bo, LI Yi-jiu, NI Ya-ming(相波，李义久，倪亚明). Nonferrous Metals(有色金属)，2003，55(4)：78.
[8] Li Yi Jiu, Xiang Bo, Ni Ya Ming. J. Appl. Polym. Sci., 2004，92(4)：3881.
[9] XIANG Bo, LIU Ya-fei, LI Yi-jiu, et al(相波，刘亚菲，李义久，等). Industrial Water Treatment(工业水处理)，2004，24(5)：10.
[10] XIANG Bo, LI Qian-qian, LI Yi-jiu, et al(相波，李倩倩，李义久，等). Technology of Water Treatment(水处理技术)，2006，32(8): 38.
[11] GUO Zhen-chu, HAN Liang, HU Bo, et al(郭振楚，韩亮，胡博，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2002，22(6)：963.
[12] GUO Zhen-chu, PENG Bin, HAN Liang, et al(郭振楚，彭斌，韩亮，等). Chinese Journal of Applied Chemistry(应用化学)，2001，18(6)：498.
[13] SUN Sheng-ling, WANG Ai-qin, GAO Yi-ci(孙胜玲, 王爱勤, 高忆慈). Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2005, 25(3): 374.
[14] Suvigya Mathur, Sartaj Tabassum. Chemistry ＆ Biodiversity, 2006, 3: 312.
[15] YANG Yan-min, WENG Shi-fu, WU Jin-guang, et al(杨延民，翁诗甫，吴瑾光，等). Chemical Journal of Chinese University(高等学校化学学报), 1994, 15(5): 646.
[16] Hegetschweiler K. Chem. Soc. Rev., 1999, 28: 239.
[17] Duus J Φ, Gotfredsen C H, Bock K. Chem. Rev., 2000, 100(12): 4589.
[18] Yano S, Mikata Y. Bull. Chem. Soc. Jpn., 2002, 75(10): 2097.
[19] GAO Ji-gang, ZHOU Jie, SHENG Feng, et al(高吉刚，周杰，盛锋，等). Chinese Journal of Analytical Chemistry(分析化学)，2002，30(5)：594.