| 光谱学与光谱分析 |
|
|
|
|
|
| Spectroscopic Analysis of Substituted Tetraphenylporphyrin Iron, Manganese, Cobalt, Copper and Zinc Complexes |
| WANG Lan-zhi1,2,SHE Yuan-bin1* |
1. Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing 100124, China
2. The College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050011, China |
|
|
|
|
Abstract A full IR, UV-Vis, FIR, spectroscopic analysis on substituted porphyrin iron, manganese, cobalt, copper and Zinc complexes was performed, and the spectroscopic patterns were found for the metalloporphyrin compounds with various structures. Base on molecular structures theory, the reasons for the spectroscopic patterns were discussed deeply. Considering the inconsistency of the far-infrared spectra of the Fe-Cl axial bonds in chloro-iron tetraphenylporphyrins reported in the literature. Their far-infrared absorptions were investigated by using both theoretical analysis and experimental determination, and the results showing that their vibrational frequencies of the Fe—Cl bonds in different substitution chloro-iron tetraphenylporphyrins were associated with their structures, and were linearly related to the length of Fe—Cl bonds.
|
|
Received: 2007-11-10
Accepted: 2008-02-08
|
|
|
|
Corresponding Authors:
SHE Yuan-bin
E-mail: sheyb@bjut.edu.cn
|
|
[1] MA Hui-min, LIANG Shu-quan(马会民，梁树权). Chemistry Bulletin(化学通报), 1999, (10): 29.
[2] YU Jia, MENG Ji-wu, LI Ying, et al(于 佳, 孟继武, 李 颖, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(8): 981.
[3] WANG L Z, SHE Y B, ZHONG R G, et al. Organic Process Research & Development,2006, 10(4): 757.
[4] AN Qing-da, YANG Da-zhi, SHI Tong-shun, et al(安庆大, 杨大智, 师同顺, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(4): 478.
[5] YIN Chun-feng(尹春凤). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1996, 16(4): 29.
[6] LUO Guo-tian, TENG Li-li, LAI Xiao-qi, et al(罗国添, 滕莉丽, 赖晓绮, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(2): 173.
[7] Adler A D, Longo F R, Finarelli J D, et al. J. Org. Chem., 1967, 32: 476.
[8] LEI Yu-wu, GUO Can-cheng, ZENG De-zhang(雷裕武，郭灿城，曾德璋). Chemical Regent(化学试剂), 1994，16(2): 105.
[9] XU Zhi-gu(徐志固). Modern Coordination Chemistry(现代配位化学). Beijing: Chemical Industry Press(北京: 化学工业出版社), 1987. 236.
[10] Ogoshi H, Watanabe E, Yoshida Z, et al. J. Am. Chem. Soc., 1973, 95: 9.
[11] Ogoshi H, Watanabe E, Yoshida Z, et al. Inorg. Chem., 1975, 14(6): 1344.
[12] Guo C C, Huang G, Li Z P, et al. J. Mol. Catal.,2001, 170: 43.
[13] SHI Tong-shun, LIU Guo-fa, CAO Xi-zhang(师同顺，刘国发，曹锡章). Chemical Journal of Chinese Universities(高等学校化学学报)，1994，15(2): 257.
[14] JIAO Xiang-dong, HUANG Jin-wang, JI Liang-nian(焦向东，黄锦汪，计亮年). Journal of South China University of Technology(华南理工大学学报), 1997，25(7): 26.
[15] JIAO Xiang-dong, HUANG Jin-wang, JI Liang-nian(焦向东, 黄锦汪, 计亮年). Chemistry Bulletin(化学通报), 1997，(1): 25.
[16] Kristine P, Thomas G S. J. Am. Chem. Soc., 1992, 114: 3793. |
| [1] |
CHENG Jia-wei1, 2，LIU Xin-xing1, 2*，ZHANG Juan1, 2. Application of Infrared Spectroscopy in Exploration of Mineral Deposits: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 15-21. |
| [2] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
| [3] |
YANG Cheng-en1, 2, LI Meng3, LU Qiu-yu2, WANG Jin-ling4, LI Yu-ting2*, SU Ling1*. Fast Prediction of Flavone and Polysaccharide Contents in
Aronia Melanocarpa by FTIR and ELM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 62-68. |
| [4] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
| [5] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
| [6] |
BAO Hao1, 2，ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
| [7] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
| [8] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
| [9] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
| [10] |
DANG Rui, GAO Zi-ang, ZHANG Tong, WANG Jia-xing. Lighting Damage Model of Silk Cultural Relics in Museum Collections Based on Infrared Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3930-3936. |
| [11] |
LI Xiao-dian1, TANG Nian1, ZHANG Man-jun1, SUN Dong-wei1, HE Shu-kai2, WANG Xian-zhong2, 3, ZENG Xiao-zhe2*, WANG Xing-hui2, LIU Xi-ya2. Infrared Spectral Characteristics and Mixing Ratio Detection Method of a New Environmentally Friendly Insulating Gas C5-PFK[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3794-3801. |
| [12] |
HU Cai-ping1, HE Cheng-yu2, KONG Li-wei3, ZHU You-you3*, WU Bin4, ZHOU Hao-xiang3, SUN Jun2. Identification of Tea Based on Near-Infrared Spectra and Fuzzy Linear Discriminant QR Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3802-3805. |
| [13] |
LIU Xin-peng1, SUN Xiang-hong2, QIN Yu-hua1*, ZHANG Min1, GONG Hui-li3. Research on t-SNE Similarity Measurement Method Based on Wasserstein Divergence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3806-3812. |
| [14] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
| [15] |
LUO Li, WANG Jing-yi, XU Zhao-jun, NA Bin*. Geographic Origin Discrimination of Wood Using NIR Spectroscopy
Combined With Machine Learning Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3372-3379. |
|
|
|
|
