| 光谱学与光谱分析 |
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| Visible Spectral Character of Heme Iron in Biomacromolecules |
| LI Ren-qiang1, CHEN Yao2, JIANG Feng-yi1 |
1. Department of Biotechnology, Ji’nan University, Guangzhou 510632, China
2. Department of Chemistry, Ji’nan University, Guangzhou 510632, China |
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Abstract The visible spectra of hemin, hemoglobin, cytochrome C, peroxidase and so on were compared and analyzed based on the experiments. The fifth and sixth coordinate bond of heme iron in biomacromolecule may affect their visible spectra in peak form and position. The sixth coordinate bond of ferrous heme iron that is in low-spin displays two peaks, and in high-spin, ferrous heme without the sixth coordinate bond of iron gives only one peak. That is in favor of our understanding of the character, function and stability of heme-containing biomacromolecule. The spectral character of iron coordinate bonds is due to that these coordinate bonds change the iron position related to porphyrin plane and its spin state.
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Received: 2002-09-08
Accepted: 2003-02-06
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Corresponding Authors:
LI Ren-qiang
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| Cite this article: |
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LI Ren-qiang,CHEN Yao,JIANG Feng-yi. Visible Spectral Character of Heme Iron in Biomacromolecules [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(01): 95-97.
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http://www.gpxygpfx.com/EN/Y2004/V24/I01/95 |
[1] Perutz M F. Annu. Rev. Physiol., 1990, 52: 1.
[2] Dickerson R E, Geis I. Hemoglobin: Structure, Function, Evolution and Pathology, California: Benjamin/Cummings, 1983.
[3] Hayaishi O. Oxygenases, London: Academic Press, 1962.
[4] 陶慰孙，李 惟，姜涌明. 蛋白质分子基础. 北京：高等教育出版社，1995.
[5] 中国大百科全书·生物学 Ⅲ. 北京：中国大百科全书出版社，1992.
[6] Sugita Y, Yoneyama Y. J. Biol. Chem., 1971, 246: 389.
[7] [英]哈里森 P M，霍尔 R J著. 赵清正译. 生物化学中的金属. 北京：科学出版社，1986.
[8] JIA Ying-ping, ZHENG Xue-fang, HU Jie-han(贾颖萍，郑学仿，胡皆汉). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2001，21(2)：222.
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