| 光谱学与光谱分析 |
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| Study on the Synthesis of a New Reagent 3-(4′-Fluorophenyl)-5-(2′- Arsenoxylphenylazo)-Rhodanine and the Fluoresence Determination of Bismuth(Ⅲ) |
| YU Jing-hua1, 2，OU Qing-yu2，LU Yan1，WANG Lai-guo1，LI Tao1 |
1. Ji′nan University, Ji′nan 250022，China
2. Lanzhou Institute of Chemical Physics, Lanzhou 730000，China |
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Abstract A new fluorescence reagent, 3-(4′-fluorophenyl)-5-(2′-arsenoxylphenylazo)-rhodanine，was synthesized. The structure of the reagent was clarified by elemental analysis and IR. At pH 5.4，the reagent can react with trace bismuth (Ⅲ) to form a chelate which reduces the fluorescence intensity greatly. And when λex／λem=305／407 nm, the fluorescence is intensive. There is a linear relationship between the decrease of fluorescence intensity and the concentration of bismuth (Ⅲ) in the range of 0-0.025 μg·mL-1. The detection limit is 1.2×10-10 g·mL-1. A new method of fluorescence spectrophotometric determination of bismuth (Ⅲ) was developed.
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Received: 2002-11-22
Accepted: 2003-05-16
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Corresponding Authors:
YU Jing-hua
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| Cite this article: |
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YU Jing-hua,OU Qing-yu,LU Yan, et al. Study on the Synthesis of a New Reagent 3-(4′-Fluorophenyl)-5-(2′- Arsenoxylphenylazo)-Rhodanine and the Fluoresence Determination of Bismuth(Ⅲ) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(09): 1093-1095.
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http://www.gpxygpfx.com/EN/Y2004/V24/I09/1093 |
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