| 光谱学与光谱分析 |
|
|
|
|
|
| Synthesis, Characterization and Fluorescence Properties of Binary and Ternary Rare Earth Complexes with N-Phenylanthranilic Acid and 1,10-Phenanthroline |
| WANG Xi-gui1, WU Hong-ying1, ZHAO Hui1, ZHAO Si-qin1, WENG Shi-fu2, WU Jin-guang2 |
1. Department of Chemistry, Inner Mongolia Normal University, Huhhot 010022, China
2. State Key Laboratory of Rare Earth Materials Chemistry and Application, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China |
|
|
|
|
Abstract Some novel binary and ternary complexes of rare earth (Tb) with N-phenylanthranilic acid and 1,10-phenanthroline were synthesized and their compositions were characterized by elemental analysis. The compositions of the complexes have been confirmed to be TbL3·4H2O and TbL3phen·2H2O (L: N-phenylanthranilic acid, phen: 1,10-phenanthroline). The spectroscopic properties of the complexes were discussed. The result shows that the luminescence intensities of binary and ternary complexes were decreased by N-phenylanthranilic acid and 1,10-phenanthroline. It is indicated that the intensity of Tb depends on the structure of ligands. The structure, energy transfer and energy matching were studied, and it is concluded that the structure of complex affects the luminescence properties of the complexes.
|
|
Received: 2003-08-04
Accepted: 2003-12-19
|
|
|
|
Corresponding Authors:
WANG Xi-gui
|
|
| Cite this article: |
|
WANG Xi-gui,WU Hong-ying,ZHAO Hui, et al. Synthesis, Characterization and Fluorescence Properties of Binary and Ternary Rare Earth Complexes with N-Phenylanthranilic Acid and 1,10-Phenanthroline [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(03): 428-431.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2005/V25/I03/428 |
[1] WU Rong-hu, SONG Hui-ning, SU Qing-de(伍荣护, 宋慧宁, 苏庆德). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(1): 119.
[2] XU Guang-xian(徐光宪). Rare Earth(稀土·第二版). Beijing: Metallurgical Ｉndustry Press(北京：冶金工业出版社), 1995.
[3] TAO Dong-liang, ZHANG Ting, XU Yi-zhuang et al(陶栋梁, 章 婷, 徐怡庄等). Chinese J. Rare Earth(中国稀土学报), 2001, 19(6): 543.
[4] YIN Xian-hong, YANG Man-ya, SHI Hua-hong et al(尹显洪, 杨满芽, 史华红等). Chinese J. Rare Earth(中国稀土学报), 2000, 18(3): 211.
[5] MAO Yu-chun, CHEN Wei-wie, XIA Guo-yao et al(毛煜春, 陈纬纬, 夏国尧等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(6): 869.
[6] YANG Yan-sheng, ZENG Hai-yan, HUANG Shi-hua et al(杨燕生, 曾海燕, 黄世华等). Chinese Journal of Luminescence(发光学报), 1995, 16(4): 354.
[7] WU Jin-guang, LI Yong, GAO Xin et al(吴瑾光, 李 勇, 高 新等). Chinese J. Rare Earth(中国稀土学报), 2001, 19(6): 548.
[8] DUAN Ning, ZHANG Xi-qing, GAO Xin, LIU Shu-man, XU Xu-rong et al(段 宁, 张希清, 高 新，刘舒曼，徐叙瑢等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(3): 267.
[9] ZHANG Gan-bing, HU Xue-lin, LI Jian-ping et al(张干兵, 胡学林, 李建平等). Journal of Hubei University, Nature Science Edition(湖北大学学报·自然科学版)，1998, 20(3): 264.
|
| [1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [2] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [3] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [4] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
| [5] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
| [6] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2，WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
| [7] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
| [8] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
| [9] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
| [10] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
| [11] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
| [12] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
| [13] |
CHEN Wen-jing, XU Nuo, JIAO Zhao-hang, YOU Jia-hua, WANG He, QI Dong-li, FENG Yu*. Study on the Diagnosis of Breast Cancer by Fluorescence Spectrometry Based on Machine Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2407-2412. |
| [14] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
| [15] |
LIU Xian-yu1, YANG Jiu-chang1, 2, TU Cai1, XU Ya-fen1, XU Chang3, CHEN Quan-li2*. Study on Spectral Characteristics of Scheelite From Xuebaoding, Pingwu County, Sichuan Province, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2550-2556. |
|
|
|
|
