光谱学与光谱分析 |
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Synthesis and UV/Vis Spectra of a Dialkyloxy Substituted Phthalocyanine |
WU Shao-feng, XU Xiu-zhi, LIN Mei-jin, WANG Jun-dong*,CHEN Nai-sheng, HUANG Jin-ling |
Institute of Functional Materials, Department of Chemistry, Fuzhou University, Fuzhou 350002, China |
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Abstract A dialkyloxy substituted metal-free phthalocyanine was synthesized by using 3-(2’,2’,4’-trimethyl-3’-pentoxy)-1,3- diiminoisoindoles and 1,3,3-trichloroisoindolenine as starting materials, and characterized by element analysis, 1H NMR, IR and UV/Vis spectra. The dependences of wavelength of UV/Vis spectra and its split of Q band absorption on the number of substituents and, dielectric constant of solvents are discussed based on the comparison with tetraalkyloxy substituted metal-free phthalocyanine
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Received: 2004-12-26
Accepted: 2005-06-12
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Corresponding Authors:
WANG Jun-dong
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Cite this article: |
WU Shao-feng,XU Xiu-zhi,LIN Mei-jin, et al. Synthesis and UV/Vis Spectra of a Dialkyloxy Substituted Phthalocyanine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(03): 513-516.
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URL: |
https://www.gpxygpfx.com/EN/Y2006/V26/I03/513 |
[1] McKeown N B. Phthalocyanine Materials, Oxford: Cambridge University Press, 1998. [2] Gema de la Torre, Nicolau M, Torres T. Supramolecular Photosensitive and Electroactive Materials(Eds Nalwa H S). San Diego: Academic Press, 2001, 1. [3] QIU Wen-feng, LIU Yun-qi, ZHU Dao-ben(邱文丰, 刘云圻, 朱道本). Functional Materials(功能材料), 2000, 31: 9. [4] Garcia-Frutos E M, Fernandez-Lazaro F, Maya E M , et al. J. Org. Chem., 2000, 65(21): 6841. [5] Leznoff C C, Hall T W. Tetrahedron Lett., 1982, 23: 3023. [6] Kobayashi N, Kondo R, Nakajima S, et al. J. Am. Chem. Soc., 1990, 112: 9640. [7] LI Bu-hong, XIE Shu-sen, LU Zu-kang(李步洪, 谢树森, 陆祖康). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(6): 902. [8] Young J G. The Synthesis of Di-Disubstituted Phthalocyanines, Ph.D Clemson University, 1987. [9] Young J G, Onyebuagu W. J. Org. Chem., 1990, 55: 2155. [10] Farbenfabrinken Bayer. US Patent 2 701 255, Feb 1, 1955. [11] CHEN Zhi-min, ZUO Xia, WU Yi-qun, et al(陈志敏, 左 霞, 吴谊群, 等). Chinese Journal of Synthetic Chemistry(合成化学), 2004, 12: 167. [12] XU Xiu-zhi, WANG Jun-dong, CHEN Nai-sheng, et al(许秀枝, 王俊东, 陈耐生, 等). The Second Conference on Chemistry and Applications of Phthalocyanines and Pophyrins, Chinese Chemical Society(中国化学会第二届酞菁与卟啉化学及其应用学术会议论文集), 2002, 10, Jinan(济南), 2002. [13] LIN Mei-jin, WANG Jun-dong, CHEN Nai-sheng, et al(林梅金, 王俊东, 陈耐生, 等). The Seventh Conference on Chemistry, Chinese Chemical Society(中国化学会第七界应用化学学术会议论文集), 2003, 10, Xi’an(西安), 2003. [14] HUANG Jin-ling, PENG Yi-ru, CHEN Nai-sheng(黄金陵, 彭亦如, 陈耐生). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(1): 1. [15] HUANG Jian-dong, LIU Er-sheng, YANG Su-ling, et al(黄剑东, 刘尔生, 杨素苓, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(1): 95. [16] Ogunsipe A, Maree D, Nyokong T. J. Mol. Struct., 2003, 650: 131. [17] Wing-Fong Law, Roger C W Liu, Jianzhuang Jiang, et al. Inorg. Chim. Acta, 1997, 256: 147.
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