光谱学与光谱分析 |
|
|
|
|
|
Determination of Sinigrin in Semen Thlaspi From Sichuan and Tibet Using Near Infrared Diffuse Reflectance Spectroscopy |
WANG Lei-lei1, CHEN Cong1, ZHOU Min1, WANG Jian-zhong1, LUO Xia2, HUANG Guo3, YE Li-ming1* |
1. West China School of Pharmacy, Sichuan University, Chengdu 610041, China 2. Sichuan Institute of Chinese Medicine,Chengdu 610041, China 3. Bruker Instruments LTD., Beijing 100081, China |
|
|
Abstract The objective of the present study was to develop a method for the determination of sinigrin in semen Thlaspi from Sichuan using near infrared diffuse reflectance spectroscopy. Near infrared spectra (NIR) in the region of 7 502.1-5 446.2 cm-1 were recorded for the 246 semen Thlaspi samples containing sinigrin in the content of 1.962%-3.917%. Calibration models were established using the PLS (partial least squares). Different spectra pretreatment methods were compared. The study showed that spectral information can be extracted thoroughly by minimum and maximum normalization pretreatment methods. In this calibration model, the correlation coefficient (R2) was 0.928 0, the SEC (standard deviation of the calibration sets) was 0.314 and the SEP (standard deviation of the prediction sets) was 0.388. Results indicated that near infrared diffuse reflectance spectroscopy method can be used to rapidly analyze the valid component in traditional Chinese medicine, and also can be used in the quality control of traditional Chinese medicine.
|
Received: 2008-08-28
Accepted: 2008-11-29
|
|
Corresponding Authors:
YE Li-ming
E-mail: dyelimin@126.com
|
|
[1] Delectis Floral Republicae Popularis Sinica Agendac Academial Sinica Edita(中国科学院中国植物志编辑委员会编). Flora of China(中国植物志)(52 Volumes). Beijing: Science Press(北京: 科学出版社), 1989. 79. [2] Jen Jen-Fon, Lin Tsaihung, Huang Jennwen, et al. Journal of Chromatography A, 2001, 912: 363. [3] YANG Nan-lin, CHEN Yi-yu, WU Yong-jiang, et al(杨南林,程翼宇,吴永江,等). Acta Chimica Sinica(化学学报), 2003, 61(3): 393. [4] Gabriele Reich. Advanced Drug Delivery Reviews, 2005, 57: 1109. [5] Swierenga H, de Groot P J, de Weijer A P, et al. Chemometrics and Intelligent Laboratory, 1998, 41: 237. [6] LU Wan-zhen, YUAN Hong-fu, XU Guang-tong, et al(陆婉珍,袁洪福,徐广通,等). Modern Analysis Technique of NIR(现代近红外光谱分析技术). Beijing: China Petrochemical Press(北京:中国石化出版社),2000. 170. [7] YE Li-ming, ZHOU Min, ZHANG Hao, et al(叶利明,周 旻,张 浩,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(2): 324.
|
[1] |
LI Yu1, ZHANG Ke-can1, PENG Li-juan2*, ZHU Zheng-liang1, HE Liang1*. Simultaneous Detection of Glucose and Xylose in Tobacco by Using Partial Least Squares Assisted UV-Vis Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 103-110. |
[2] |
JIA Hao1, 3, 4, ZHANG Wei-fang1, 3, LEI Jing-wei1, 3*, LI Ying-ying1, 3, YANG Chun-jing2, 3*, XIE Cai-xia1, 3, GONG Hai-yan1, 3, DING Xin-yu1, YAO Tian-yi1. Study on Infrared Fingerprint of the Classical Famous
Prescription Yiguanjian[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3202-3210. |
[3] |
LIU Wen-bo, LIU Jin, HAN Tong-shuai*, GE Qing, LIU Rong. Simulation of the Effect of Dermal Thickness on Non-Invasive Blood Glucose Measurement by Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2699-2704. |
[4] |
LUO Dong-jie, WANG Meng, ZHANG Xiao-shuan, XIAO Xin-qing*. Vis/NIR Based Spectral Sensing for SSC of Table Grapes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2146-2152. |
[5] |
WANG Bin1, 2, ZHENG Shao-feng2, GAN Jiu-lin1, LIU Shu3, LI Wei-cai2, YANG Zhong-min1, SONG Wu-yuan4*. Plastic Reference Material (PRM) Combined With Partial Least Square (PLS) in Laser-Induced Breakdown Spectroscopy (LIBS) in the Field of Quantitative Elemental Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2124-2131. |
[6] |
CHENG Xiao-xiang1, WU Na2, LIU Wei2*, WANG Ke-qing2, LI Chen-yuan1, CHEN Kun-long1, LI Yan-xiang1*. Research on Quantitative Model of Corrosion Products of Iron Artefacts Based on Raman Spectroscopic Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2166-2173. |
[7] |
ZHANG Mei-zhi1, ZHANG Ning1, 2, QIAO Cong1, XU Huang-rong2, GAO Bo2, MENG Qing-yang2, YU Wei-xing2*. High-Efficient and Accurate Testing of Egg Freshness Based on
IPLS-XGBoost Algorithm and VIS-NIR Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1711-1718. |
[8] |
XU Wei-xin, XIA Jing-jing, WEI Yun, CHEN Yue-yao, MAO Xin-ran, MIN Shun-geng*, XIONG Yan-mei*. Rapid Determination of Oxytetracycline Hydrochloride Illegally Added in Cattle Premix by ATR-FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 842-847. |
[9] |
LI Zi-yi1, LI Rui-lan1, LI Can-lin1, WANG Ke-ru2, FAN Jiu-yu3, GU Rui1*. Identification of Tibetan Medicine Zhaxun by Infrared Spectroscopy
Combined With Chemometrics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 526-532. |
[10] |
WANG Chao1, LIU Yan1*, XIA Zhen-zhen2, WANG Qiao1, DUAN Shuo1. Fast Evaluation of Freshness in Crayfish (Prokaryophyllus clarkii) Cased on Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 156-161. |
[11] |
ZHAO Jian-ming, YANG Chang-bao, HAN Li-guo*, ZHU Meng-yao. The Inversion of Muscovite Content Based on Spectral Absorption
Characteristics of Rocks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 220-224. |
[12] |
LI Qing-bo1, BI Zhi-qi1, CUI Hou-xin2, LANG Jia-ye2, SHEN Zhong-kai2. Detection of Total Organic Carbon in Surface Water Based on UV-Vis Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3423-3427. |
[13] |
OUYANG Ai-guo, LIN Tong-zheng, HU Jun, YU Bin, LIU Yan-de. Optimization of Hardness Testing Model of High-Speed Iron Wheel by Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3109-3115. |
[14] |
YUAN Ke-yan 1, WANG Rong2, WANG Xiang-xiang2, XUE Li-ping2, YU Li2*. Identification and Restoration of Pseudo-Hydrolyzed Animal Protein of Lacteus Camelus Based on iPLS Model of Near-Infrared Measurement Spectrum of 6 mm Detection Plate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3143-3147. |
[15] |
ZHAO Zhi-lei1, 2, 3, 4,WANG Xue-mei1, 2, 3,LIU Dong-dong1, 2, 3,WANG Yan-wei1, 2, 3,GU Yu-hong5,TENG Jia-xin1,NIU Xiao-ying1, 2, 3, 4*. Quantitative Analysis of Soluble Solids and Titratable Acidity Content in Angeleno Plum by Near-Infrared Spectroscopy With BP-ANN and PLS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2836-2842. |
|
|
|
|