|
|
|
|
|
|
| Research Progress on Detection of Chemical Warfare Agent Simulants and Toxic Gases by Photoacoustic Spectroscopy |
| FU Wen-xiang, DONG Li-qiang, YANG Liu* |
State Key Laboratory of NBC Protection for Civilian, Beijing 102205, China
|
|
|
|
|
Abstract Photoacoustic spectroscopy is a novel gas detection technology. Photoacoustic spectroscopy is an indirect absorption spectroscopy technology. Gas concentration inversion is performed by detecting acoustic signals. It has the advantages of simple structure, response speed, and small system size. It is one of the widely used high-sensitivity trace gas sensing methods currently under development and is becoming one of the research focus in detecting toxic gases, explosives and chemical warfare agent simulants. This paper focuses on the research work of photoacoustic spectroscopy in the rapid detection of chemical warfare agent simulants and toxic gases. Photoacoustic spectroscopy can use different laser systems. When the laser emission range is in the mid-infrared band, chemical warfare agent simulants will have characteristic absorption peaks in these bands, so they can also be used to detect chemical warfare agent simulants. This paper introduces the methods of photoacoustic spectroscopy in foreign countries for the detection of chemical warfare agents and simulants. It introduces the method information such as the optical path configuration, laser light source, etc. in the method, as well as the structural characteristics of the newly built gas absorption cell. The characteristic absorption wavelength range of photoacoustic spectroscopic detection of chemical warfare agents and simulants was analyzed. In addition to the traditional detection of chemical poisons in gas absorption cells, methods and systems for the open optical path telemetry of photoacoustic spectroscopy in the range of several centimeters to tens of meters have been continuously developed in recent years to detect chemical warfare agent simulants. The article also reported the method of photoacoustic spectroscopy in detecting ammonia, hydrogen sulfide, HF, sulfur dioxide and other toxic and harmful gases. This paper analyzes the related work on light sources and methods, acoustic wave transducers, characteristic spectra of chemical poison simulants, and detection performance. The foreign short-range telemetry photoacoustic spectroscopy prototype is reported, and the potential development of photoacoustic spectroscopy short-range spectral telemetry technology is reviewed.
|
|
Received: 2022-05-25
Accepted: 2022-11-03
|
|
|
|
Corresponding Authors:
YANG Liu
E-mail: yangliujinjin@sian.com
|
|
[1] Milan S Trtica, Bojan Radak，Dubravka Milovanovic, et al. Eur. Phys. J. Plus., 2018，133：268.
[2] Priyanka Patel, Modi Hardik, Palak Patel, et al. International Journal of Pharmaceutical Erudition, 2013, 3(1)：41.
[3] Hodgkinson J，Tatam R P. Meas. Sci. Technol., 2013, 24：012004.
[4] Knobelspies S，Bierer B，Ortiz Perez A，et al. Sens. Actuators B Chem.，2016, 236：885.
[5] Patel C K N. Eur. Phys. J. Special. Topics., 2008, 153: 1.
[6] Kristan Gurton，Melvin Felton. ARL-TR-4782., 2009.
[7] Anadi Mukherjee, Ilya Dunayevskiy, Manu Prasanna, et al. Applied Optics, 2008，47(10)：1543.
[8] Ellen Holthoff, John Bender, Paul Pellegrino，et al. Sensors, 2010, 10：1986.
[9] Maravic D S, Trtica M S, Miljanic S S, et al. Anal. Chim. Acta，2006, 555：259.
[10] Luo X，Shi F Y，Lin J X. International Journal of Infrared and Millimeter Waves, 1991，12：141.
[11] Rao K S, Razdan A K, Tyaji A, et al. Spectrochimica Acta Part A，2018，204(5)：696.
[12] Ramesh C Sharma，Subodh Kumar, Gaolam S, et al. sensors and Actuators B: Chemical，2017，243：59.
[13] Deepak Kumar, Subodh Kumar，Saurabh G, et al. J. Laser Opt. Photonics, 2016, 3: 2.
[14] Ramesh C Sharma, Subodh Kumar, Parmar A, et al. Scientific Reports, 2020，10：15053.
[15] Michael B Pushkarsky, Michael E Webber, MacDonalal T, et al. Proceedings Optically Based Biological and Chemical Sensing for Defence，2004, 5617.
[16] Van Neste C W, Senesac L R, Thundat T, et al. Applied Physics Letters, 2008，92：234102.
[17] Gupta Deepa, Chen Xing, Wang Chencha, et al. Chemosensors, 2018, 6：6.
[18] Gupta D，Wang C C，Khurgin J, et al. SPIE News Room，2016.
[19] Choa Fow-Sen, Wang Chen-Chia, Khurgin Jacob, et al. In Proceedings of the Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XVII, Baltimore, MD, USA, 18-20. 2016，98240M.
[20] Baptista-Filho M，da Silva M G，Sthel M S, et al. Appl. Opt.，2006, 45：4966.
[21] Baptista-Filho M，Gonc H，Gomes M, et al. Sens. Actuators B Chem., 2011, 158：241.
[22] Lima G R, Mota L, Miklós A，et al. Applied Physics B, 2014, 117：333.
[23] Ulasevich A L，Gorelik A V. Appl. Phys. B，2014, 117：549.
[24] Pushkarsky M B，Webber M E. Appl. Phys. B, 2003, 77：381.
[25] Bonilla-Manrique O E，Posada-Roman，Garcia Souto J A, et al. Sensors, 2019, 19：2890.
[26] Bonilla-Manrique O E，Moser H，Martin-Mateos P, et al. J. Sens., 2019, 2019：6437431.
[27] Dumitras D C，Banita S, Bratu A M, et al. Technol., 2010, 53：308.
[28] Varga A，Bozóki Z，Szakáll M，et al. Appl. Phys. B Lasers Opt., 2006, 85：315.
[29] Szabó A，Mohácsi A，Gulás G, et al. Meas. Sci. Technol., 2013, 24：065501.
[30] Yin X，Dong L，Wu H，et al. Appl. Phys. Lett., 2017, 111：031109.
[31] Besson J，Schilt S，Thévenaz L, et al. Spectrochimica Acta Part A，2004, 60(14)：3449.
[32] Besson J P，Schilt S，Thévenaz L, et al. Appl. Phys. B., 2008, 90：191.
[33] Ma Y，He Y，Yu X，et al. Sens. Actuators B Chem., 2016, 233：388.
[34] Matthias Dressler, Günther Helmrich. Proc. of SPIE, 2008，7003：70031F.
[35] Yin Xukun, Wu Hongpeng, Dong Lei, et al. ACS Sens.，2020, 5：549.
[36] Waclawek J P，Lewicki R，Moser H, et al. Applied Physics B, 2014，117：113.
[37] Johannes P Waclawek, Harald Moser, Harald Moser, et al. Optics Express，2016，24(6)：6559.
[38] Mohammad Reza Mohebbifar. Microw Opt. Technol. Lett., 2021，63: 2517.
[39] CHENG Gang, CAO Ya-nan, TIAN Xing，et al（程 刚，曹亚南，田 兴，等）. Spectroscopy and Spectral Analysis（光谱学与光谱分析）, 2020, 40(8): 2345.
|
| [1] |
ZHENG Hong-quan, DAI Jing-min*. Research Development of the Application of Photoacoustic Spectroscopy in Measurement of Trace Gas Concentration[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 1-14. |
| [2] |
XU Qiu-yi1, 3, 4, ZHU Wen-yue3, 4, CHEN Jie2, 3, 4, LIU Qiang3, 4 *, ZHENG Jian-jie3, 4, YANG Tao2, 3, 4, YANG Teng-fei2, 3, 4. Calibration Method of Aerosol Absorption Coefficient Based on
Photoacoustic Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 88-94. |
| [3] |
CHENG Gang1, CAO Ya-nan1, TIAN Xing1, CAO Yuan2, LIU Kun2. Simulation of Airflow Performance and Parameter Optimization of
Photoacoustic Cell Based on Orthogonal Test[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3899-3905. |
| [4] |
CHEN Tu-nan1, 2, LI Kang1, QIU Zong-jia1, HAN Dong1, 2, ZHANG Guo-qiang1, 2*. Simulation Analysis and Experiment Verification of Insulating Material-Based Photoacoustic Cell[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2922-2927. |
| [5] |
JIN Hua-wei1, 2, 3, WANG Hao-wei1, 2, LUO Ping1, 2, FANG Lei1, 2. Simulation Design and Performance Analysis of Two-Stage Buffer
Photoacoustic Cell[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2375-2380. |
| [6] |
LI Zhen-gang1, 2, SI Gan-shang1, 2, NING Zhi-qiang1, 2, LIU Jia-xiang1, FANG Yong-hua1, 2*, CHENG Zhen1, 2, SI Bei-bei1, 2, YANG Chang-ping1, 2. Research on Long Optical Path and Resonant Carbon Dioxide Gas
Photoacoustic Sensor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 43-49. |
| [7] |
WANG Qi, WANG Shi-chao, LIU Tai-yu, CHEN Zi-qiang. Research Progress of Multi-Component Gas Detection by Photoacoustic Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 1-8. |
| [8] |
ZHANG Lin1, WEN Bao-ying2, LIU Wei-wei1, FU Wen-xiang1, KONG Jing-lin1*, LI Jian-feng2*. Rapidly Detection of Chemical Warfare Agent Simulants by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 110-114. |
| [9] |
REN Zhong1, 2*, LIU Tao1, LIU Guo-dong1, 2. Classification and Identification of Real or Fake Blood Based on OPO Pulsed Laser Induced Photoacoustic Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2734-2741. |
| [10] |
NAN Di-na, DONG Li-qiang, FU Wen-xiang, LIU Wei-wei, KONG Jing-lin*. Fast Identification of Hazardous Liquids Based on Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1806-1810. |
| [11] |
WAN Liu-jie1, 2, ZHEN Chao3, QIU Zong-jia1, LI Kang1, MA Feng-xiang3, HAN Dong1, 2, ZHANG Guo-qiang1, 2*. Research of High Precision Photoacoustic Second Harmonic Detection Technology Based on FFT Filter[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 2996-3001. |
| [12] |
CHEN Jie1, 2, 3, QIAN Xian-mei1, 3, LIU Qiang1, 3*, ZHENG Jian-jie1, 2, 3, ZHU Wen-yue1, 3, LI Xue-bin1, 3. Research on Optical Absorption Characteristics of Atmospheric Aerosols at 1 064 nm Wavelength[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 2989-2995. |
| [13] |
XIE Ying-chao1,2, WANG Rui-feng1,2, CAO Yuan1,2, LIU Kun1*, GAO Xiao-ming1,2. Research on Detecting CO2 With Off-Beam Quartz-Enhanced Photoacoustic Spectroscopy at 2.004 μm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2664-2669. |
| [14] |
CHENG Gang1, CAO Ya-nan1, TIAN Xing1, CAO Yuan2, LIU Kun2*. Influence of Photoacoustic Cell Geometrical Shape on the Performance of Photoacoustic Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2345-2351. |
| [15] |
WANG Qiao-yun, YIN Xiang-yu, YANG Lei, XING Ling-yu. Geometrical Optimization of Resonant Ellipsoidal Photoacoustic Cell in Photoacoustic Spectroscopy System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1351-1355. |
|
|
|
|
