| 光谱学与光谱分析 |
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| Study on the Absorption and Fluorescence Spectra of Ethylene Glycol and Glycerol |
| XU Hui1,ZHU Tuo2*,YU Rui-peng3 |
1. School of Communication and Control Engineering,Southern Yangtze University,Wuxi 214122,China
2. School of Science,Southern Yangtze University,Wuxi 214122,China
3. Test Center,Southern Yangtze University,Wuxi 214122,China |
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Abstract The absorption and fluorescence spectra of ethylene glycol and glycerol solution induced by UV light were studied respectively in the present paper. The most intense absorption wavelength for both of them was located at 198 nm. Moreover,fluorescence was detected when induced by suitable UV light,and the corresponding fluorescence spectra were listed. But there is no obvious relationship found between the fluorescence intensity and the excited wavelength,and a further research should be done. From the first derivative fluorescence spectra of ethylene glycol,it was concluded that under the UV light of 210 nm,the variation speed for relative intensity proved to be the fastest. In contrast,when excited by 225 nm,the speed proved to be the slowest. In addition,based on the quantum calculation and the transition from HOMO to LUMO of electronics in one-dimensional quantum well,the authors attempted to give out the value of absorption wavelength. In consideration of the bond-length variety brought out by the chain processing,the error between the experimental and calculation values should be apprehensible,and the latter can serve as some reference value in theory.
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Received: 2006-05-10
Accepted: 2006-08-20
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Corresponding Authors:
ZHU Tuo
E-mail: tzhu@sytu.edu.cn
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| Cite this article: |
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XU Hui,ZHU Tuo,YU Rui-peng. Study on the Absorption and Fluorescence Spectra of Ethylene Glycol and Glycerol[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(07): 1381-1384.
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https://www.gpxygpfx.com/EN/Y2007/V27/I07/1381 |
[1] XU Shou-chang(徐寿昌). Organic Chemistry(有机化学). Beijing: Higher Education Press(北京: 高等教育出版社),1993.
[2] Anne P,Constanca C. Cryobiology,2002,44: 150.
[3] Fahy G M,Levy D. Cryobiology,1987,24: 196.
[4] HUA Ze-zhao,REN He-sheng(华泽钊，任禾盛). Biological Medical Technology of the Low Temperature(低温生物医学技术). Beijing: Science Press(北京: 科学出版社)，1994.
[5] Vigier G,Vassoille R. Cryobiology,1987,24: 345.
[6] Bronshteyn L V,Steponkus P L. Cryobiology,1995,32: 1.
[7] Klaus Suhling,Daniel M Davis,et al. Proceedings of SPIE,2001,4259： 251.
[8] Alexey N Bashkatov,Elina A Genina,et al. Proceedings of SPIE,2002,4628，372.
[9] LIANG Ai-hui,JIANG Zhi-liang(梁爱惠，蒋治良). Journal of Analytical Science(分析科学学报),2005，21(5): 542.
[10] HUANG Chong,OUYANG Yan-dong,FANG Yi-wen(黄 翀，欧阳艳冬，方奕文). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005，25(2): 260.
[11] LIU Jun-jie,ZHENG Hai-fei(刘俊杰,郑海飞). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005，25(11): 1817.
[12] YUAN Cai-xia(苑彩霞). Hebei Chemical Engineering and Industry(河北化工),1995,(4): 50.
[13] FAN Hu,SHENG Liang-quan,TONG Hong-wu,et al(樊 虎，盛良全，童红武，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(10)： 1627.
[14] XU Qing-qin,DU Li-ming,WANG Jing-ping(许庆琴，杜黎明，王静萍). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2002，22(3)： 444.
[15] TANG Bo,JIANG Chong-qiu,et al(唐 波，江崇球，等). Journal of Shandong Teachers’ University(山东师范大学学报)，1996，11(1)： 57.
[16] ZHANG Shu-fang(张淑芳). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2006，26(3)： 535.
[17] LIN Fang,HE Guo-fang(林 芳，贺国芳). Medical Herald(医药导报),2006,25(7): 701.
[18] TANG Lian-jun,LI Hong-mei,et al(唐莲君，李红玫，等). Chinese Journal of Spectroscopy Laboratory(光谱实验室)，2003，20(4)： 60.
[19] House J E. Fundamentals of Quantum Chemistry. Amsterdan: Elsevier Academic Press,2004. |
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