基于中红外光谱和二维相关红外对不同产地山茱萸快速鉴别

doi:10.3964/j.issn.1000-0593(2025)03-0761-07

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Abstract Mid-infrared spectroscopy combined with a two-dimensional correlation infrared method will be used to identify Corni fructose from different regions quickly. Mid-infrared technology scanned 30 batches of Corni fructose medicinal materials from seven production areas in three provinces. The original spectra were preprocessed with baseline correction and smoothing, and then the differences in average infrared and second-order derivative spectra were analyzed. At the same time, the infrared spectra of Corni fructose were compared and analyzed with the infrared spectra of three standard substances, namely login, mononucleosis, and ursolic acid, to establish a two-dimensional infrared correlation spectrum. Use analysis software to perform principal component and cluster analysis on infrared spectral data and analyze the causes of differences based on climate factors in different regions. The peak positions and shapes of the average spectra from the seven production areas have high similarity, while the differences in the second derivative spectra and two-dimensional infrared correlation spectrum results showed in three bands: 2 370～2 400, 2 200～2 300, and 1 500～1 650 cm^-1. The results of the principal component analysis show that the spatial distribution of Corni fructose from different regions is independent of each other. The clustering analysis results show that the seven production areas can be divided into three characteristic groups, with Shaanxi Danfeng, Shaanxi Foping, Shaanxi Shangluo, and Shaanxi Zhouzhi clustered into one group, Zhejiang Lin'an clustered into one group, and Henan Xixia and Henan Luanchuan clustered into one group. The combination of mid-infrared spectroscopy with chemical stoichiometry and two-dimensional correlated infrared spectroscopy can rapidly identify Corni fructose's origin from different origins.

Key words：Mid-infrared spectrum; Corni frucutus; Two-dimensional correlation infrared spectrum; Origin identification

Received: 2024-03-05 Accepted: 2024-07-23

ZTFLH:

S153.6

Corresponding Authors: QIAO Lu E-mail: bridgeroad@163.com

Cite this article:

WANG Lei,CHEN Yuan-jie,LI Lei, et al. Rapid Identification of Corni Frucutus From Different Habitats Based on Mid-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2025, 45(03): 761-767.

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https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2025)03-0761-07 OR https://www.gpxygpfx.com/EN/Y2025/V45/I03/761

[1] GUO Jun-shuang，MI Li，ZHOU Yang(郭君双，米鹂，周扬). Sheng Nong's Herbal Classic(神农本草经). Beijing：China Traditional Chinese Medicine Press(北京：中国中医药出版社)，2015：34.
[2] Chinese Pharmacopoeia Commission(国家药典委员会). Pharmacopoeia of the People's Republic of China(中华人民共和国药典). Beijing：China Medical Science Press(北京：中国医药科技出版社)，2020：29.
[3] ZHOU Ying-chun，ZHANG Lian-jie，ZHANG Yan-li(周迎春，张廉洁，张燕丽). Information on Traditional Chinese Medicine(中医药信息)，2020，37(1)：114.
[4] SUN Ling，FAN Xiao-lan，DAI Xiao-li(孙玲，樊晓兰，戴小丽). China Pharmacy(中国药房)，2018，29(15)：2063.
[5] HUANG Xiao，LI Min，LIU Cong，et al(黄潇，李敏，刘聪，等). Pharmacy and Clinics of Chinese Materia Medica(中药与临床)，2015，6(2)：4.
[6] Bian X, Lu Z, van Kollenburg G. Anal. Methods, 2020, 12(27): 3499.
[7] SHEN Ting-ting，FU Chang-lu，MU Zong-gang(申婷婷，付常璐，牟宗刚). Journal of University of Jinan (Science and Technology)[济南大学学报(自然科学版)]，2007，21(2)：124.
[8] XU Rong，SUN Su-qin，LIU You-gang(徐荣，孙素琴，刘友刚). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2010，30(4)：897.
[9] WANG Chuan-bei，ZHANG Zheng-fang，TANG Jun，et al(王传贝，张正方，唐军，等). Chinese Journal of Spectroscopy Laboratory(光谱实验室)，2009，26(4)：918.
[10] CHEN Lin-jie，CHENG Jun-wen，WEI Hai-long，et al(陈林杰，程俊文，魏海龙，等). China Food Additives(中国食品添加剂)，2020，31(9)：1.
[11] SUN Ji-gui，LIU Jie，ZHAO Lian-yu(孙吉贵，刘杰，赵连宇). Journal of Software(软件学报)，2008，(1)：48.
[12] DONG Cheng-ming，SHI Ying-qiang，MA Yu，et al(董诚明，史应强，马瑜，等). Chinese Journal of Experimental Traditional Medical Formulae(中国实验方剂学杂志)，2010，16(8)：87.
[13] CUI Yong-xia，WANG Li-li，GUO Tao，et al(崔永霞，王利丽，郭涛，等). Lishizhen Medicine and Materia Medica Research(时珍国医国药)，2020，31(7)：1594.
[14] SU Peng-chao，LIN Bei-bei，CHEN Chen(苏鹏超，蔺蓓蓓，陈琛). Journal of Shaanxi University of Technology (Natural Science Edition)[陕西理工大学学报(自然科学版)]，2020，36(6)：49.