| 光谱学与光谱分析 |
|
|
|
|
|
| The Study on the Characteristics of Organic Pollution in Typical Herbicide Plant Wastewater |
| CHEN Yu-hui1, 2, 3, XI Hong-bo2, 3, YU Dong4, ZHOU Yue-xi2, 3*, CHEN Xue-min1, FU Xiao-yong1 |
1. School of Environmental and Municipal Engineering of Lanzhou Jiaotong University, Lanzhou 730070, China
2. State Key Laboratory of Environmental Criteria and Risk Assessment, Beijing 100012, China
3. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Science, Beijing 100012, China
4. Research Institute of Jilin Petrochemical Co. Ltd., PetroChina, Jilin 132021, China |
|
|
|
|
Abstract Herbicide wastewater is one of tne industrial wastewater, it has high salt content, poor biodegradability, biodegradable characteristics. Nitrogen-containing organic compounds are dominated in dissolved organic matter and dissolved organic matter of wastewater, BOD∶COD=0.045，C∶N∶P=692∶426∶1. Applying static headspace, purg and trap, solid-phase extraction, solid-phase microextraction and liquid-liquid extraction as pretreatment methods combined with gas chromatography/mass spectrometry (GC/MS), which qualitatively analyzed the organic components of the Atrazine, acetochlor herbicide production wastewater and researched the UV spectrum, three-dimensional fluorescence spectroscopy of the wastewater and its major pollutants. The study of GC/MS indicated that Wastewater contained chlorinated hydrocarbons, BTEX and triazines, amides herbicides etc. 38 kinds of volatile and semi-volatile organic compounds, atrazine and acetochlor herbicides accounted for 87.99%. Affected monocyclic or heterocyclic substances, the ultraviolet absorption spectrum of the wastewater in 210～230 and 250～270 nm in that the amino group lead to the UV absorption red shift 20 nm. Wastewater generated 5 fluorescence peak in λex/λem=200～280/300～400 nm, such as a(225/305 nm), b(265/365 nm), c(275/305 nm), d(285/390 nm), e(320/375 nm). Based on three-dimensional fluorescence results of the different functional groups of the characteristics organic, fluorescent area of unsaturated bond is in λex/λem=215～230/290～340 nm, the main contribution of the fluorescent substance in the region were olefins, benzene, heterocyclic in the wastewater; fluorescent area of Phenolic hydroxyl and carbonyl is in λex/λem=270/300 nm, the main contribution of the fluorescent substance in the region were phenols, ketones.
|
|
Received: 2015-01-14
Accepted: 2015-04-08
|
|
|
|
Corresponding Authors:
ZHOU Yue-xi
E-mail: zhouyuexi@263.net
|
|
[1] JIAO Cai-shan, PENG Mei-yuan, WANG Zhong-wei(矫彩山，彭美媛，王中伟). Agrocheincals(农药), 2007, 46(2): 77.
[2] ZHANG Zi-jie(张自杰). Sewerage(排水工程). Beijing: China Architecture & Building Press(北京: 中国建筑工业出版社), 2001. 8.
[3] Huber J F K, Fogy I, Fioresi C. Chromatographia, 1980, 13(7): 408.
[4] Santilio A, Girolimetti S, Attard Barbini D. Food Additives & Contaminants: Part A, 2014, (5): 845.
[5] Mills M S, Michael E M. Environmental Science & Technology, 1994, (1): 73.
[6] Liang P, Wang J, Liu G. Food Analytical Methods, 2014, 7: 1530.
[7] Liang P, Wang J, Liu G. Journal of Separation Science, 2014, 37(17): 2380.
[8] Jean W Munch, Paul E Grimmett. Ethernet for Plant Automation: Method 525. 3, 2012.
[9] Munch J W. Ethernet for Plant Automation: Method 507, Revision 2.1, 1995.
[10] Edited by Munch J W. Ethernet for Plant Automation: Method 505, Revision 2.1, 1995.
[11] Munch D J, Hautman D P. Ethernet for Plant Automation: Method 551.1, 1995.
[12] CHANG Qing-yun, ZHOU Xin, GAO Shu-tao(常青云，周 欣，高书涛). Analytical Chemistry(分析化学), 2012, 40(4): 523.
[13] XIE Wen-ming, FAN Zhi-xian, ZHANG Ling-jin(谢文明，范志先，张玲金). Rock and Mineral Analysis(岩矿测试), 2003, 22(2): 93.
[14] CHU Xiao-gang, YONG Wei, LING Yun(储晓刚，雍 炜，凌 云). Analytical Chemistry(分析化学), 2008, 36(3): 325.
[15] ZHOU Yan-ming, SUN Xin(周艳明，孙 鑫). Science and Technology of Food Industry(食品工业科技), 2009 (6): 333.
[16] YAN Hong-fei, HUANG Zhi-qiang, ZHANG Ying(颜鸿飞，黄志强，张 莹). Chinese Journal of Chromatography(色谱), 2009, 27(3): 288.
[17] YANG Wen-wu, MA Yong-gang, ZHANG Zong-xiang(杨文武，马永刚，张宗祥). The Administration and Technique of Environmental Monitoring(环境监测管理与技术), 2010, 6: 55.
[18] YANG Mei, MA Yong-an, LIN Zhong-sheng(杨 梅，马永安，林忠胜). Journal of Instrumental Analysis(分析测试学报), 2008, 27(1): 38.
[19] HU Xiao-fang, GUO Wei-min, LU Jia-ming(胡晓芳，郭卫民，鲁佳铭). Environmental Science and Technology(环境科学与技术), 2012, 34(12): 160.
[20] ZUO Hai-gen, MIAO Shan-shan, YANG Hong(左海根，苗珊珊，杨 红). Journal of Nanjing Agricultural University(南京农业大学学报), 2012, 35(5): 175.
[21] SUN Zheng, ZENG Xiao-qing, WANG Wei-gang(孙 政，曾小庆，王炜罡). Journal of the Chinese Chemical Society(化学学报), 2006, 64(3): 218.
[22] CAO Hong-cui(曹红翠). Journal of Gansu Lianhe University(Natural Science Edition)(甘肃联合大学学报·自然科学版), 2005, (1)：34.
[23] Buffle J. Chemical Geology, 1989, (2): 161.
[24] CHEN Mao-fu, WU Jing, Lü Yan-li(陈茂福, 吴 静, 律严励). Acta Optica Sinica(光学学报), 2008, 28(3): 578.
[25] HAO Rui-xia, CAO Ke-xin, DENG Yi-wen(郝瑞霞, 曹可心, 邓亦文). Chinese Journal of Analysis Laboratory(分析试验室), 2007, (10): 41.
[26] Andy Baker, Michael Curry. Water Research, 2004, 38: 2605.
[27] FU Ping-qing, LIU Cong-qiang, YIN Zuo-ying(傅平青，刘丛强，尹祚莹). Geochemistry(地球化学), 2004, (3): 301. |
| [1] |
ZHENG Pei-chao, YIN Yi-tong, WANG Jin-mei*, ZHOU Chun-yan, ZHANG Li, ZENG Jin-rui, LÜ Qiang. Study on the Method of Detecting Phosphate Ions in Water Based on
Ultraviolet Absorption Spectrum Combined With SPA-ELM Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 82-87. |
| [2] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [3] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [4] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2，WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
| [5] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
| [6] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
| [7] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
| [8] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
| [9] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
| [10] |
QIU Cun-pu1, 2, TANG Xiao-xue2, WEN Xi-xian4, MA Xin-ling2, 3, XIA Ming-ming2, 3, LI Zhong-pei2, 3, WU Meng2, 3, LI Gui-long2, 3, LIU Kai2, 3, LIU Kai-li4, LIU Ming2, 3*. Effects of Calcium Salts on the Decomposition Process of Straw and the Characteristics of Three-Dimensional Excitation-Emission Matrices of the Dissolved Organic Matter in Decomposition Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2301-2307. |
| [11] |
SHI Chuan-qi1, LI Yan2, HU Yu3, YU Shao-peng1*, JIN Liang2, CHEN Mei-ru1. Fluorescence Spectral Characteristics of Soil Dissolved Organic Matter in the River Wetland of Northern Cold Region, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1517-1523. |
| [12] |
LI Yuan-jing1, 2, CHEN Cai-yun-fei1, 2, LI Li-ping1, 2*. Spectroscopy Study of γ-Ray Irradiated Gray Akoya Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1056-1062. |
| [13] |
WANG Jin-mei, HE Shi, ZHANG Hang-xi, YANG Chen, YIN Yi-tong, ZHANG Li, ZHENG Pei-chao*. Study on the Detection Method of Nitrate Nitrogen in Water Based on
Ultraviolet Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1037-1042. |
| [14] |
LIU Xia-yan1, CAO Hao-xuan1, MIAO Chuang-he1, LI Li-jun2, ZHOU Hu1, LÜ Yi-zhong1*. Three-Dimensional Fluorescence Spectra of Dissolved Organic Matter in Fluvo-Aquic Soil Profile Under Long-Term Composting Treatment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 674-684. |
| [15] |
LÜ Yang1, PEI Jing-cheng1*, ZHANG Yu-yang2. Chemical Composition and Spectra Characteristics of Hydrothermal Synthetic Sapphire[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3546-3551. |
|
|
|
|
