光谱学与光谱分析 |
|
|
|
|
|
Near-Infrared Luminescence and Energy Transfer of ACaPO4∶Eu2+, Nd3+(A=Li, K, Na) |
XIAO Quan-lan1, ZOU Shao-yu1, LIU Guan-xi1, PENG Wen-fang1, WAN Chui-ming1, XIE Li-juan1, MENG Jian-xin2* |
1. Department of Chemistry, Jinan University, Guangzhou 510632, China 2. Institute of Nanochemistry, Jinan Univesity, Guangzhou 510632, China |
|
|
Abstract Near-infrared (NIR) luminescence phosphors ACaPO4∶Eu2+,Nd3+(A=Li, K, Na) were prepared by conventional solid state method and the sensitization of Nd3+ near-infrared luminescence by Eu2+ was investigated. The characteristic NIR luminescence of Nd3+ in ACaPO4 matrix is greatly enhanced by co-doping of Eu2+. The fluorescence properties of ACaPO4∶Eu2+, the NIR luminescence properties of ACaPO4∶Eu2+,Nd3+ and the fluorescence lifetime were studied. The effect of emission wavelength of Eu2+ on NIR luminescence of Nd3+ was investigated; The energy transfer mechanism between Eu2+ and Nd3+ was also discussed. Emission peak wavelength of Eu2+ In ACaPO4 matrixes was found red shift with the series of A=Li, K, Na and the extent of the overlap with the different excitation peaks of Nd3+ changes obviously. It was concluded that the emission peak position of Eu2+ is a very important factor for energy transfer, and the optimal wavelength range for Eu2+→Nd3+ energy transfer is 500 to 550 nm.
|
Received: 2010-10-19
Accepted: 2011-04-14
|
|
Corresponding Authors:
MENG Jian-xin
E-mail: tmjx@jnu.edu.cn
|
|
[1] Sharma Y K, Surana S S L, Singh R K. Opt. Mater., 2007, 29: 598. [2] Meng J X, Li K F, Yuan J. Chem. Phys. Lett., 2000, 332: 313. [3] Slooff L H, Van B A, Polman A, et al. J. Appl. Phys., 2002, 91: 3955. [4] Krasilnik Z F, Andreev B A, Kryzhkov D I, et al. J. Mater. Res., 2006, 21: 574. [5] Kuriki K, Koike Y, Okamoto Y. Chem. Rev., 2002, 102: 2347. [6] Strumpel C, Mccann M, Beaucarne G, et al. Solar Energy Materials and Solar Cells, 2007, 91: 238. [7] Meng J X, Cheaeh K W, Shi Z P, et al. Appl. Phys. Lett., 2007, 91: 151107. [8] Meng J X, Li J Q, Shi Z P, et al. Appl. Phys. Lett., 2008, 93: 221908. [9] YANG Li-li, WAN Wen-jiao, LI Jin-qing, et al(杨丽丽, 万文娇, 李锦清, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2011, 31(1): 43. [10] Gaft M, Reisfeld R, Panczer G, et al. J. Alloys and Compounds, 2008, 451: 56. [11] Yang W J, Chen T M. Appl. Phys. Lett., 2006, 88: 101903. [12] Liu J, Wu Z, Gong M. Appl. Phys. B, 2008, 93: 583. [13] Tang Y S, Hu S F. Appl. Phys. Lett., 2007, 90: 151108. [14] DexterD L. J. Chem. Phys., 1953, 21(5): 8362850. [15] HUANG Shi-hua, LOU Li-ren(黄世华, 楼立人). Chin. J. Lumin(发光学报), 2008, 29(4): 646. |
[1] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
[2] |
ZHAO Yuan, LÜ Zhao-yue*, DENG Jian, ZENG Guo-qing. The Emissive Mechanism of C545T Thin Layer at the Exciplex and Non-Exciplex Interfaces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3711-3715. |
[3] |
ZHANG Yong1,2, ZHU Jin-ming1, YANG Li-li1*, Lü Shi-quan1, WU Yan-qun1,CHU Xue-juan1. Effect of Dy3+ on Luminescence Properties of Tb3+ Activated Silicate Oxyfluoride Scintillating Glass[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1412-1419. |
[4] |
ZHENG Jia-jin1, 2, LU Qiang1, ZHENG Rui-lin1, ZOU Hui1, YU Ke-han1, WEI Wei1. Preparation and Photoluminescence Properties of Fluorophosphate Glasses with High Efficient White Light Emission[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 39-44. |
[5] |
CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2. Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1949-1957. |
[6] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
[7] |
CHEN Yue-e1, SHAO Qiu-feng2, JIA Li-xiao1. Judd-Ofelt Theory Analysis and Spectroscopic Properties of Nd3+-Doped Cadmium Aluminium Silicate Glasses[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1345-1349. |
[8] |
WAN Ying,HE Jiu-yang, MA Yuan-yuan, ZHOU Zhi-xuan, Taximaiti·Yusufu, Aierken·Sidike*. Synthesis and Luminescence Properties of a New Type of Green Fluorescent Powder BaAl2Si2O8∶Tb3+, Ce3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1595-1600. |
[9] |
FU Zhen-xing1, LIU Bi-rui1, YANG Bing-xiong2 . Spectroscopic Properties of Energy Transfer Effect in Sm3+/Eu3+ Doped LaF3 Nanocrystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2686-2691. |
[10] |
WEI Jian1, SHEN Chang-yu1*, SUN Yu-huan2, ZHANG Hong1, WANG Le1*, LI Chen-xia1 . Preparation and Luminescent Properties of Blue Emitting Phosphor of Sr3(PO4)2∶Eu2+ for White LED[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3028-3031. |
[11] |
MA Yuan-yuan, HE Jiu-yang, Aziguli·Reheman, Bahadeer·Rouzi, Aierken·Sidike* . Photoluminescence of Sinthetic Scapolite Na4Ca4Al6Si9O24 Phosphors Activated with Ce3+ and Tb3+ and Energy Transfer from Ce3+ to Tb3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3241-3246. |
[12] |
DONG Guo-shuai, LIU Hai-bo, LUO Li*, WANG Yin-hai . Study on Synthesis and Luminescence Mechanism of Novel Green Sr3Y(PO4)3∶Ce3+, Tb3+ Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(08): 2189-2193. |
[13] |
CHEN Xiao-bo1, ZHOU Gu1, ZHOU Yong-fen2, WU Zheng-long1, GUO Yu-ying1, WANG Shui-feng1, ZOU Qiu-yan3, ZHUANG Jian4, 5, CHEN Xiao-duan1, LI Chun-mi1, YAO Wen-ting1, CHENG Huan-li1 . Near-Infrared Quantum Cutting Downconversion Luminescence of Yb3+ Ion Cooperative Energy Transferred from YVO4 Matrix Donor [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(02): 315-319. |
[14] |
XIAO Yu, CONG Yan*, YANG Qi, ZHANG Zhi-hong, LIU Peng-zu . Upconversion Emission from Er3+-Yb3+-Mo6+ Co-Doped ZrO2-Al2O3 Composites [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(11): 2913-2916. |
[15] |
YANG Yan-min, SU Xian-yuan, JIAO Fu-yun, LI Zi-qiang, ZHANG Shao-yang . Synthesis and Luminescence Properties of Mg2Y8Si6O26∶Ce3+, Mn2+ Phosphor [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(04): 940-944. |
|
|
|
|