|
|
|
|
|
|
Synthesis and Luminescence Properties of a New Type of Green Fluorescent Powder BaAl2Si2O8∶Tb3+, Ce3+ |
WAN Ying,HE Jiu-yang, MA Yuan-yuan, ZHOU Zhi-xuan, Taximaiti·Yusufu, Aierken·Sidike* |
College of Physics and Electronic Engineering of Xinjiang Normal University,Key Laboratory of Mineral Luminescent Material and Microstructure of Xinjiang,Urumqi 830054,China |
|
|
Abstract The blue phosphors designed as BaAl2Si2O8∶Tb3+, Ce3+ were prepared with high temperature solid-state reaction. The luminescence properties and mechanism of Tb3+, Ce3+, Tb3+ and Ce3+ Co-doped samples were discussed. Energy transfer between Ce3+ and Tb3+ in the sample was analyzed. The samples were tested with XRD, fluorescence spectra, color coordinates and so on. The results have shown that a small number of Tb3+, Ce3+ ions doping fail to change the crystal structure of BaAl2Si2O8. BaAl2Si2O8∶Tb3+ shows bright green. Emission spectra are the narrow-band spectral lines composed by peak-to-peak value of 487, 545, 583 and 621 nm, which are the typical emission peak generated due to 5D4→7FJ(J=6, 5, 4, 3) transition of Tb3+ ions. The incorporation of Ce3+ not only makes the excitation spectra of BaAl2Si2O8∶Tb3+ from the narrow band excitation to broadband excitation increases the spectral band diversity. The luminous intensity has obvious enhancement, and the color also has some coordination, which makes it more flexible in practical application. The reason for the enhancement of luminescence intensity is not only because of the sensitization of Ce3+ ions, but also due to the energy transfer between Tb3+ and Ce3+. The critical distance of energy transfer has been calculated with the concentration quenching method, which is 153.45 nm. The energy transfer mechanism is ascribed to the dipole-dipole interaction. When the Tb3+ion concentration was increased to 0.07 the transfer efficiency increased to 76.04%.
|
Received: 2016-06-06
Accepted: 2016-10-28
|
|
Corresponding Authors:
Aierken·Sidike
E-mail: aierkenjiang@sina.com
|
|
[1] Ma M X, Zhu D C, Zhao C, et al. Mater. Sci.,2012,57:1728.
[2] Ma M X, Zhu D C, Zhao C. Opt. Commun.,2012,285:665.
[3] Aierken S, Rahman A Z M S, He J Y. J. Lumin.,2011,131:1840.
[4] Ma Y Y, He J Y, Rahman A Z M S. Spectrosc. Spectr. Anal.,2015,35:3241.
[5] Pawade V B, Dhoble N S, Dhoble S J. J. Rare Earth,2014,32:593.
[6] Wang T, Xu X H, Zhou D C. J. Rare Earth, 2015, 33: 361.
[7] Fang H W, Huang S, Wei X T. J. Rare Earth, 2015, 33: 825.
[8] Xia Z G, Liang Y J, Yu D Y. Opt. Laser. Tech.,2014,56:387.
[9] Lei Z G, Chang T C, Cui J M. Chin. J. Lumin.,2013,34:1476.
[10] Dou X H, Zhao W R, Song E H. J. Rare Earth, 2012, 30: 739.
[11] Fu X Y, Fang L J, Niu S Y, et al. J. Lumin., 2013, 142: 163.
[12] Geng D L, Li G G, Shang M M, et al. Mater. Chem., 2012, 22: 14262.
[13] Huang C H, Chen T M. J. Phys. Chem. C, 2011, 115: 2349. |
[1] |
LI Zhao, WU Kun-yao, WANG Ya-nan, CAO Jing, WANG Yong-feng, LU Yuan-yuan. Synthesis and Luminescence Properties of Yellow-Emitting Phosphor Y2.93Al5O12∶0.07Ce3+ Under Blue Light Excitation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 381-385. |
[2] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
[3] |
ZHAO Yuan, LÜ Zhao-yue*, DENG Jian, ZENG Guo-qing. The Emissive Mechanism of C545T Thin Layer at the Exciplex and Non-Exciplex Interfaces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3711-3715. |
[4] |
FENG Ai-ming1, WANG Fu-qiang1, ZHANG Hong1*, AN Peng2, LI Yang-hui1, 3, WANG Le1*. Significantly Improved Luminescence Properties of YAG Phosphor via Localized Surface Plasmon Resonance of Nanotitania[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3081-3085. |
[5] |
FAN Bin1, LIU Jun2, QI Shi-mei3, ZHAO Wen-yu1*. Preparation and Luminescent Properties of Green Phosphors LaGaO3∶Tb3+,Sn4+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 65-70. |
[6] |
ZHANG Yong1,2, ZHU Jin-ming1, YANG Li-li1*, Lü Shi-quan1, WU Yan-qun1,CHU Xue-juan1. Effect of Dy3+ on Luminescence Properties of Tb3+ Activated Silicate Oxyfluoride Scintillating Glass[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1412-1419. |
[7] |
ZHENG Jia-jin1, 2, LU Qiang1, ZHENG Rui-lin1, ZOU Hui1, YU Ke-han1, WEI Wei1. Preparation and Photoluminescence Properties of Fluorophosphate Glasses with High Efficient White Light Emission[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 39-44. |
[8] |
ZHANG Na1,2, ZHUO Ning-ze1,2,3*, CHENG Shao-wen4, ZHU Yue-hua1,2, WANG Hai-bo2*. Preparation of ZnO∶Zn Green Phosphors via Sintering Temperatures with Solid State Reaction and Their Application in Near-UV LEDs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(10): 3030-3035. |
[9] |
CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2. Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1949-1957. |
[10] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
[11] |
ZANG Xue-mei1, ZHANG Yu-hang2, LI De-sheng2, ZHAO Xin2, WANG Zhi-qiang1, LIN Hai1, 2*. Photoluminescence Properties of Near-Ultraviolet SrAl2Si2O8∶Ce3+ Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3360-3364. |
[12] |
FU Zhen-xing1, LIU Bi-rui1, YANG Bing-xiong2 . Spectroscopic Properties of Energy Transfer Effect in Sm3+/Eu3+ Doped LaF3 Nanocrystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2686-2691. |
[13] |
XU Shi-hua1, HUANG Zhong-jing1*, LIU Guo-cong2*, WEI Qing-min3 . Study on the Hydrothermal Synthesis and Fluorescence of LaF3∶Tb3+, Ce3+ Nanocrystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 759-764. |
[14] |
YANG Peng1, 2, ZHAO Xin1, WANG Zhi-qiang2, LIN Hai1, 2* . Ce3+/Tb3+ Doped Alkaline-Earth Borate Glasses Employed in Enhanced Solar Cells [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3291-3295. |
[15] |
MA Yuan-yuan, HE Jiu-yang, Aziguli·Reheman, Bahadeer·Rouzi, Aierken·Sidike* . Photoluminescence of Sinthetic Scapolite Na4Ca4Al6Si9O24 Phosphors Activated with Ce3+ and Tb3+ and Energy Transfer from Ce3+ to Tb3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3241-3246. |
|
|
|
|