|
|
|
|
|
|
| Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics |
| CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2 |
1. Applied Optics Beijing Area Major Laboratory and Physics Department, Beijing Normal University, Beijing 100875, China
2. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
3. School of Materials Science and Technology, Shanghai Institute of Technology, Shanghai 200235, China |
|
|
|
|
Abstract In this paper, the spectral modulation by the quantum-cutting luminescence of Er3+Yb3+ ion-pairs in nanophase oxyfluoride vitroceramics is studied. We obtained X-ray diffraction spectra, surface topographies, excitation, absorption, and luminescence spectra of Er3+Yb3+ nanophase oxyfluoride vitroceramics, and compared them with the corresponding parameters of a Tb3+Yb3+-codoped sample. We find that the 652.0 nm wavelength red luminescence intensity is enhanced by the factors of 680.85 and 303.80 for (A) Er(1%)Yb(8.0%)∶FOV and (B) Er(0.5%)Yb(3.0%)∶FOV, respectively, when they are excited by 378 nm light than when they are excited by 522 nm light. It is also found that the 652.0 nm red luminescence intensity is enhanced 491.05 and 184.12 times for (A) Er(1%)Yb(8.0%)∶FOV and (B) Er(0.5%)Yb(3.0%)∶FOV than (C) Er(0.5%)∶FOV when they are both being excited by 378 nm light. the results show that the {978.0 and 1 012.0 nm} infrared luminescence intensities of (A) Er(1%)Yb(8.0%)∶FOV and (B) Er(0.5%)Yb(3.0%)∶FOV are {58.00 and 293.62} and {25.11 and 67.50} times, respectively, larger than the corresponding ones of (C) Er(0.5%)∶FOV when both excited with 378 nm light. And further, the intensities of the 378.5 nm excitation peak of (A) Er(1%)Yb(8.0%)∶FOV and (B) Er(0.5%)Yb(3.0%)∶FOV are about 606.02 time and 199.83 times, respectively, larger than (C) Er(0.5%)∶FOV when 652.0 nm luminescence wavelength is selected as the fluorescence receiving wavelength to measure the visible excitation spectra in the range of 250～628 nm. Meanwhile, we also find that the first-order quantum-cutting infrared 1 012 or 978 nm luminescence intensities of (A) Er(1%)Yb(8.0%)∶FOV and (B) Er(0.5%)Yb(3.0%)∶FOV are about 101.38 and 29.19 times larger than the second-order quantum-cutting infrared 976 nm luminescence intensity of (D) Tb(0.7%)Yb(5.0%)∶FOV. To the best of our knowledge, present quantum-cutting obtained in our study is the most intense quantum-cutting reported to date. Therefore, we believe that present first-order quantum-cutting luminescence of Er3+Yb3+-codoped oxyfluoride vitroceramics may be intense for the material’s use as a quantum-cutting layer to enhance the photovoltaic conversion efficiency of crystal silicon solar cell. The results can facilitate the probing of next-generation environmentally friendly spectral-modulation solar cells, which are currently the focus of global attention.
|
|
Received: 2017-07-05
Accepted: 2017-12-26
|
|
|
|
[1] Vergeer P, Vlugt T J H, Meijerink A, et al. Phys. Rev. B, 2005, 71(1): 014119.
[2] Zhou J J, Teng Y, Qiu J R, et al. Phys. Chem. Chem. Phys., 2010, 12(41): 13759.
[3] Hu J X, Xia H P, Hu H Y, et al. J. Appl. Phys., 2012, 112(7): 073518.
[4] Dexter D L. Phys. Rev., 1957, 108(3): 630.
[5] Song Zengfu. Principle and Application of Atomic Spectroscopy and Crystal Spectroscopy. Beijing: Science Press, 1987.
[6] Zhu W J, Chen D Q, Wang Y S, et al. Nanoscale, 2014, 6(18): 10500.
[7] Wang Y Z, Yu D C, Zhang Q Y, et al. J. Appl. Phys., 2013, 114(20): 203510.
[8] Chen X B, Li S, Hu L. L, et al. Sci. Rep., 2017, 7: 1976.
[9] Sun J Y, Sun Y N, Zeng J H, et al. Opt. Mat., 2013, 35(6): 1276.
[10] Reisfeld R, Jorgensen C K. Lasers and Excited States of Rare-Earth (Springer-Verlag), 1977.
[11] Ende B M van der, Aarts L, Meijerink A. Phys. Chem. Chem. Phys., 2009, 11(47): 11081.
[12] Zhou J J, Teng Y, Qiu J R, et al. Chem. Phys. Lett., 2010, 486(4-6): 116.
[13] Hao Y Y, Wang Y, Hu X Y, et al. Ceramics International, 2016, 42(8): 9396.
[14] Richards B S. Sol. Energy Mater. Sol. Cells, 2006, 90(9): 1189.
[15] Chen Xiaobo, Li Song, Liu Quanlin, et al. Spectroscopy and Spectral Analysis, 2017, 37(8): 2619.
[16] Trupke T, Green M A, Wurfel P. J. Appl. Phys., 2002, 92(3): 1668. |
| [1] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
| [2] |
ZHAO Yuan, LÜ Zhao-yue*, DENG Jian, ZENG Guo-qing. The Emissive Mechanism of C545T Thin Layer at the Exciplex and Non-Exciplex Interfaces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3711-3715. |
| [3] |
ZHANG Yong1,2, ZHU Jin-ming1, YANG Li-li1*, Lü Shi-quan1, WU Yan-qun1，CHU Xue-juan1. Effect of Dy3+ on Luminescence Properties of Tb3+ Activated Silicate Oxyfluoride Scintillating Glass[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1412-1419. |
| [4] |
ZHENG Jia-jin1, 2, LU Qiang1, ZHENG Rui-lin1, ZOU Hui1, YU Ke-han1, WEI Wei1. Preparation and Photoluminescence Properties of Fluorophosphate Glasses with High Efficient White Light Emission[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 39-44. |
| [5] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
| [6] |
CHEN Xiao-bo1, LI Song1, GUO Jing-hua1, ZHOU Gu1, FAN Ting-ting1, YU Chun-lei2, ZHENG Dong1, ZHAO Guo-ying3, TAO Jing-fu1, LIN Wei1, CHEN Luan1, HU Li-li2. Two-Photon, Three-Photon, Four-Photon Near-Infrared Quantum Cutting Luminescence of Er3+ Activator in Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(08): 2619-2626. |
| [7] |
WAN Ying，HE Jiu-yang, MA Yuan-yuan, ZHOU Zhi-xuan, Taximaiti·Yusufu, Aierken·Sidike*. Synthesis and Luminescence Properties of a New Type of Green Fluorescent Powder BaAl2Si2O8∶Tb3+, Ce3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1595-1600. |
| [8] |
ZHOU Jian-ping1*, LI Xin-yu1, ZHU Feng2, CHEN Xiao-hong2*, XU Zheng3 . Efficient Polymer Solar Cells Using ZnO Electron Transporting Layer with Layered Magentron Sputtered ZnO Film and/or Modified with Functionalized Carbon Nanopartilces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 517-521. |
| [9] |
YANG Bing-yang1,2, HE Da-wei1,2*, ZHUO Zu-liang1,2, WANG Yong-sheng1,2 . Influence of Dimethyl Sulfoxide as Processing Additive for Improving Efficiency of Polymer Solar Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(01): 287-292. |
| [10] |
HUANG Di, XU Zheng*, ZHAO Su-ling, ZHAO Jiao, LI Yang, ZHAO Ling . Understanding the Effected Efficiencies of Polymer Solar Cells Employing Different Fullerene Multiadducts as Acceptors [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2363-2367. |
| [11] |
FU Zhen-xing1, LIU Bi-rui1, YANG Bing-xiong2 . Spectroscopic Properties of Energy Transfer Effect in Sm3+/Eu3+ Doped LaF3 Nanocrystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2686-2691. |
| [12] |
CHEN Xiao-bo1, LI Song1, CHEN Xiao-duan1, WANG Jie-liang1, HE Li-zhu2, WANG Shui-feng1, DENG Zhi-wei1, CHENG Huan-li1, GAO Yan3, LIU Quan-lin2. The Concentration Effect of Near-Infrared Quantum Cutting Luminescence of Tm3+ Ion Sensitized with Bi3+ Ion in YNbO4 Phosphor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(07): 2042-2047. |
| [13] |
ZHAO Huan-bin, SUN Qin-jun*, ZHOU Miao, GAO Li-yan, HAO Yu-ying*, SHI Fang. Study on the Effects of Alq3∶CsF Composite Cathode Buffer Layer on the Performances of CuPc/C60 Solar Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 331-335. |
| [14] |
YANG Peng1, 2, ZHAO Xin1, WANG Zhi-qiang2, LIN Hai1, 2* . Ce3+/Tb3+ Doped Alkaline-Earth Borate Glasses Employed in Enhanced Solar Cells [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3291-3295. |
| [15] |
MA Yuan-yuan, HE Jiu-yang, Aziguli·Reheman, Bahadeer·Rouzi, Aierken·Sidike* . Photoluminescence of Sinthetic Scapolite Na4Ca4Al6Si9O24 Phosphors Activated with Ce3+ and Tb3+ and Energy Transfer from Ce3+ to Tb3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3241-3246. |
|
|
|
|
