Abstract:A rapid and non-destructive method was used to discriminate between calligraphies by means of Fourier transform infrared (FTIR) and FT-Raman spectroscopy in this paper. In order to discriminate two real calligraphies of Ouyang Zhong-shi from two counterfeit ones, the authors investigated the inkpad and the rice paper of the calligraphies by means of FT-Raman spectroscopy and tested the inkpad and the ink mark of the calligraphies by means of FTIR spectroscopy. It could be seen that the tiny, delicated varied chemical components of the real and the counterfeit calligraphies lead to different characters in vibration frequencies of IR and Raman functional groups and also the real calligraphies have the perfect reiteration. So the authors can discriminate between the real and the counterfeit calligraphies. It is proved that FTIR and FT-Raman are useful in the non-destructive identification of calligraphies and more precise and quicker than traditional approaches.
[1] LIU Jin(刘 进). Joural of Jiangsu Public Security College(江苏公安专科学校学报),2001,15(1):150. [2] ZHANG Jin-ping(张金萍). Southeast Culture(东南文化),2000,(3):123. [3] HU Qiang, HU Ji-ming(胡 强, 胡继明). Chinese Chemistry Bulletin(化学通报),1992,(3):27. [4] XIONG Xian-li(熊贤礼). Relics From South(南方文物),2000,(3):27. [5] ZHOU Chong-yun(周崇云). Archives Science Bulletin(档案学通讯),2000, (3):61. [6] LU Li(鲁 力). Southeast Culture(东南文化),1999, (2):119. [7] HE Wen-quan,CHENG Huan-sheng,DING Yan-fang et al(何文权,承焕生,丁艳芳等). Nuclear Techniques(核技术),1999,22(1):53. [8] WANG Zhi-guo,SUN Su-qin,ZHOU Qun et al(王志国,孙素琴,周 群等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(6):794. [9] ZHANG Xuan,SUN Su-qin,WANG Jian(张 宣,孙素琴,王 俭). Chinese Journal of Analytical Chemistry(分析化学),2001,29(2):242. [10] SUN Su-qin,LIU Jun,ZHOU Qun(孙素琴,刘 军,周 群). Chinese Journal of Analytical Chemistry(分析化学),2002,30(2):140. [11] CHENG Huan-sheng,HE Wen-quan,MA Cheng-ying et al(承焕生,何文权,马承英等). Science of Conservation and Archaeology(文物保护与考古科学),1997,9(1):16. [12] ZHANG Xue-lian(张雪莲). Science of Conservation and Archaeology(文物保护与考古科学),1997,9(1):60. [13] LI Shu-ling(李淑玲). Rock and Mineral Analysis(岩矿测试),1998,17(4):312. [14] WU Jin-guang(吴瑾光). Techniques and Applications of Modern Fourier Transform Infrared Spectroscopy(近代傅里叶变换红外光谱技术及应用). Beijing: Scientific and Technical Documents Publishing House(北京: 科学技术文献出版社), 1994. [15] ZHOU Guang-ming,SHENG Rong-sheng,ZENG Yun-e (周光明,盛蓉生,曾云鹗). Chinese Journal of Analytical Chemistry(分析化学),1996,24(6):729.