Abstract:The concentration of dissolved organic matter(DOM) is an important index to assess natural water quality. Fluorescence measures can be used to scale the DOM loading in natural water in a highly sensitive, highly selective and online way. The relations between the fluorescence intensity and the solution concentration, pH, and metal ion content were studied. The experiment results show that the fluorescence intensity and the solution concentration have a linear relationship when the concentration is below 10 mg·L-1 and the pH is in the range of 6.5-7.5. The metal ions have a strong quenching effect on the fluorescence intensity of DOM, and the quenching effect is correlated with the coodination characters of the ions.
[1] CHEN Guo-zhen, HUANG Xian-zhi, ZHENG Zhu-zi, et al(陈国珍,黄贤智,郑朱梓, 等),Fluoresence Analysis Method(Second Edition)(荧光分析法·第2版). Beijing: Science Press(北京:科学出版社),1990. [2] Barbini R, Colao F, Fantoni R, et al. Journal of Marine Science, 1998, 55: 793. [3] Bengraiyne K, Marhaba T F. Journal of Hazardous Materials, 2004, B108: 207. [4] Babichenko S, Leeben A, Poryvkina L, et al. Journal of Environmental Monitoring, 2000, 2: 378. [5] Ahmad S R, Reynolds D M. Water Research, 1999, 33(9): 2069. [6] Sne1s M, Guarini1 R, Dell’Aglio M. Proceedings of SPIE, 2000, 4070: 100. [7] Bristow M, Nielsen D, Bundy D, et al. Applied Optics, 1981, 20(17): 2889. [8] ZHANG Qian-qian, LEI Shu-he, WANG Xiu-lin(张前前,类淑河,王修林). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(10): 1227. [9] Marhaba T F, Yong P, Doanh Van. Journal of Hazardous Materials, 2000, A73: 221. [10] Kalbitz K, Geyer S, Geyer W. Chemosphere, 2000, 40: 1305. [11] Marhaba T F, Doanh Van, Lippincott R L. Water Research, 2000, 34(14): 3543. [12] Komada T, Schofield O M E, Reimers C E. Marine Chemistry, 2002, 79: 81. [13] Lu Y F, Herbert E A. Water Research, 2002, 36: 5083. [14] Edward T, Calos R, Stephen E B, et al. Geochimica et Cosmochimica Acta, 2002, 66(18): 3211.