|
|
|
|
|
|
Detecting H2S Gas Concentration by 1,8-Naphthalimides Fluorescent Probe |
TANG Dong-lin1, WANG Qiao1, CHU Yi-neng2, LI Rui-hai2 |
1. Key Laboratory of Petroleum-Gas Equipments of Ministry of Education, College of Mechanical and Electrical Engineering, Southwest Petroleum University, Chengdu 610500, China
2. College of Polymer Science & Engineering, Sichuan University, Chengdu 610065, China |
|
|
Abstract Aiming at the low sensitivity of traditional hydrogen sulfide detection method, a small-molecule fluorescent probe was designed and synthesized for hydrogen sulfide detection via introducing oxidizing group of nitro on the 1,8-naphthalimide fluorescence group, based on the nitro group could be reduced by hydrogen sulfide to produce the corresponding amino group. The fluorescence intensity of probe was very weak, and the fluorescence peaks were at λ=467 nm and λ=522 nm. After reacting with H2S, fluorescent effect disappeared at 522 nm, it significantly enhanced at 467 nm. The fluorescence spectrum of fluorescent probe was measured after being introduced into H2S, and the fluorescence intensity at 467 nm was analyzed. The experimental result showed an excellent linear relationship between H2S gas concentration and fluorescence intensity, while the linear correlation coefficient was up to 0.979 3. Meanwhile, the minimum H2S gas concentration that could be detected was only 0.88×10-6 mol·L-1. Fluorescence spectrometric detection of 1,8-naphthalimides solution can be used for the H2S gas rapid determination in oil and gas fields.
|
Received: 2016-12-21
Accepted: 2017-05-06
|
|
|
[1] Lin Riyi, Song Duopei, Zhou Guangxiang, et al. Acta Petrolei Sinica, 2014, 35(6): 1153.
[2] Hughes M N, Centelles M N, Moore K P. Free Radical Biology and Medicine, 2009, 47(10): 1346.
[3] Guenther E A, Johnson K S, Coale K H. Analytical Chemistry, 2001, 73(14): 3481.
[4] Doeller J E, Isbell T S, Benavides G, et al. Analytical Biochemistry, 2005, 341(1): 40.
[5] Radfordknoery J, Cutter G A. Analytical Chemistry, 1993, 65(8): 976.
[6] Ubuka T, Abe T, Kajikawa R, et al. Journal of Chromatography B: Biomedical Sciences and Applications, 2001, 757(1): 31.
[7] Hou Dianfei, Zhang Qian, Wang Xiaodong, et al. Chinese Journal of Analysis Laboratory, 2016, 35(3): 319.
[8] Morita T, Perrella M A, Lee M E, et al. Proceedings of the National Academy of Sciences, 1995, 92(5): 1475.
[9] Gadalla M M, Snyder S H. Journal of Neurochemistry, 2010, 113(1): 14.
[10] Sun K, Liu X L, Wang Y Y, et al. The Royal Society of Chemistry Advances. 2013, 3(34): 14543.
[11] Peng H J, Cheng Y F, Dai C F, et al. Angew. Chem. Int. Ed., 2011, 50(41): 9672.
[12] Liu C R, Peng B, Li S, et al. Organic Letters, 2012, 14(8): 2184.
[13] Wang X, Sun J, Zhang W, et al. Chemical Science, 2013, 4(6): 2551.
[14] Yan X L, Xu C C, Zheng M, et al. Photocraphic Science and Photochemistry, 2000, 18(2): 112.
[15] Montoya L A, Pluth M D. Chem. Commun., 2012, 48(39): 4767.
[16] Gronowitz S, Westerlund C, Hornfeldt A B. Acta Chem. Scand. Sect. B, 1975, 29: 224.
[17] Huber D, Andermann G, Leclerc G. Tetrahedron Lett.,1988, 29: 635.
[18] Zhang L, Duan D, Liu Y, et al. J. Am. Chem. Soc., 2014, 136(1):226.
[19] Xia Shengqin, Li Chengzhi, Wu Zhenguo, et al. Acta Sci. Nat. Univ. Norm. Hunan, 2000, 23(4): 51.
[20] Cao Xizhang. Inorganic Chemistry. Beijing: Higher Education Press, 1994. 363. |
[1] |
TAN Ai-ling1, WANG Si-yuan1, ZHAO Yong2, ZHOU Kun-peng1, LU Zhang-jian1. Research on Vinegar Brand Traceability Based on Three-Dimensional Fluorescence Spectra and Quaternion Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2163-2169. |
[2] |
ZHOU Meng-ran1, LAI Wen-hao1*, WANG Ya1, 2, HU Feng1, LI Da-tong1, WANG Rui1. Application of CNN in LIF Fluorescence Spectrum Image Recognition of Mine Water Inrush[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2262-2266. |
[3] |
CHEN Ji-wen1, XU Tao2, LIU Wei2, FANG Zhe1, QU Hua-yang1*, LIANG Yuan1, HU Xue-qiang1, LIU Ming-bo1. On-Line Determination of Light-Rare Earth Distribution by Energy Dispersive-X-Ray Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2284-2289. |
[4] |
LIU Ling1, YANG Ming-xing1, 2*, LU Ren1, Andy Shen1, HE Chong2. Study on EDXRF Method of Turquoise Composition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1910-1916. |
[5] |
ZHANG Li-jiao1,2, LAI Wan-chang1, XIE Bo2, 3, HUANG Jin-chu1, LI Dan1, WANG Guang-xi1, YANG Qiang1, CHEN Xiao-li1. The Effect of Filterson on the Determination of Trace Heavy Metal Cd in Light Matrix by Energy Dispersive X-Ray Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1917-1921. |
[6] |
Halil Oturak1*, Neslihan Kaya Kınaytürk2,Çağrı Çırak3. Experimental and Theoretical Spectral (FT-IR, Raman, NMR, UV-Vis and NLO) Analysis of a Potential Anti-Tumor Drug: 1-Methyl-6-Nitro-1H-Benzimidazole[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1963-1969. |
[7] |
TANG Zhu-rui1, 2, XI Bei-dou1, 3, 4, HE Xiao-song1, 3, TAN Wen-bing1, 3, ZHANG Hui1, 3, LI Dan1, 3, HUANG Cai-hong1, 3*. Structural Characteristics of Dissolved Organic Compounds during Swine Manure Composting[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1526-1532. |
[8] |
ZHOU Meng-ran, HU Feng*, YAN Peng-cheng, LIU Dong. Laser Induced Fluorescence Spectrum Analysis of Water Inrush in Coal Mine Based on FCM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1572-1576. |
[9] |
WANG Shi-fang, LUO Na, HAN Ping*. Application of Energy-Dispersive X-Ray Fluorescence Spectrometry to the Determination of As, Zn,Pb and Cr in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1648-1654. |
[10] |
ZHANG Qiu-hui1, GUO Zhuang-zhi1, FENG Guo-ying2. The Effect of Incident Laser Power on Raman Spectra and Photoluminescence Spectra of Silicon Nanowires[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1118-1121. |
[11] |
LI Shuang-fang1,2, GUO Yu-bao1*, SUN Yan-hui2, GU Hai-yang2. Rapid Identification of Sunflower Seed Oil Quality by Three-Dimensional Synchronous Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1165-1170. |
[12] |
ZHU Cong-hai1, 3, CHEN Guo-qing1, 3*, ZHU Chun1, 2, 3, ZHAO Jin-chen1, 3, LIU Huai-bo1, 3, ZHANG Xiao-he1, 3, SONG Xin-shu1, 3. Studies of the Fluorescence Properties of Methanol and Ethanol Based on the Density Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1133-1138. |
[13] |
OUYANG Heng1,2*, XIAO Jian-ren3, LIN Xiu-yong4, FAN Gong-duan4*. Compositional Characteristics of Dissolved Organic Matter in Water Treatment Systems of Water Source Heat Pump Based on Three-Dimensional Fluorescence Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1146-1152. |
[14] |
WANG Yu-tian, LIU Ting-ting*, LIU Ling-fei, YANG Zhe, CUI Yao-yao. Determination of Polycyclic Aromatic Hydrocarbons in Water Based on Three Dimensional Fluorescence Spectroscopy Combined with Wavelet Compression and APTLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1171-1177. |
[15] |
CHEN Jia1, YE Chang-qing1, ZHU Sai-jiang1, WANG Xiao-mei1,2*, TAO Xu-tang2. Synthesis of 9,10-Diheterocyclicanthracenes and Performance Correlations in Triplet-Triplet Annihilation Upconversion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 715-721. |
|
|
|
|