|
|
|
|
|
|
Spectral Characteristics and Concentration Quantitative Analysis of NV Center Ensembles in Diamond |
WANG Fang, MA Zong-min*, ZHAO Min, LIN Zhao-dong, ZHANG Shao-wen, QU Zhang, LIU Jun, LI Yan-jun |
Science and Technology on Electronic Test and Measurement Laboratory, School of Instruments and Electronics, North University of China, Taiyuan 030051, China |
|
|
Abstract Nitrogen-vacancy (NV-) centers of diamond can realize the function of high-sensitivity physical quantity detection with superior photo-luminescence properties. The concentration of NV- centers is one of the main factors that affect the physical quantity detection sensitivity in the macro field. The paper studied and analyzed the relationship between different electron injection doses and the concentrations of NV- centers. The research method was carried out as follows: firstly, diamonds were exposed to electron irradiation and further subjected to high temperature annealing in vacuum in order to prepare NV- centers; then, a Raman spectrometer was utilized to test the fluorescence spectra of diamond in the following three stages: before and after electron irradiation, and after annealing, so that the Raman spectral characteristic of diamond was analyzed during the NV- center preparation process; finally, the concentrations of the prepared NV- centers were estimated, and the influence rules of different electron injection doses on the concentrations of the NV- centers were also explored. The results show that after electron injection is performed on diamond, luminescence defects of 524.7, 541.1, 578 and 648.1 nm are formed, wherein centers of 524.7 nm are commonly found in HPHT synthetic diamond subjected to electron injection. After annealing at high temperature (≥800 ℃) in vacuum (≥10-7 Pa) is performed on diamond subjected to electron injection, vacancies move freely, the unstable defects disappear, and nitrogen-vacancy centers are formed when the vacancies are bound while moving close to nitrogen atoms. For diamond with a nitrogen content of 100 ppm, the relationship between the concentrations of NV- centers and the electron injection dose was in line with Boltzmann distribution when the number of vacancies produced with electron injection is smaller than 120 ppm (2.1×1019 cm-3). This study provides a reference basis for quantitative preparation of NV- centers by utilizing diamond with the nitrogen content of 100 ppm, and further lays a foundation for application of NV- centers to precision macroscopic physical quantity measurement.
|
Received: 2016-05-30
Accepted: 2016-10-12
|
|
Corresponding Authors:
MA Zong-min
E-mail: mzmncit@163.com
|
|
[1] Doherty M W, Manson N B, Delaney P, et al. Physics Reports, 2013, 528(1): 1.
[2] Doi Y, Fukui T, Kato H, et al. Physical Review B, 2016, 93(8): 081203.
[3] Appel P, Ganzhorn M, Neu E, et al. New Journal of Physics, 2015, 17(11): 112001.
[4] ZHANG Huan, MA Zong-min, XIE Yan-na, et al(张 欢, 马宗敏, 谢艳娜, 等). Micronanoelectronic Technology(微纳电子技术), 2014, 51(12): 765.
[5] Ledbetter M, Jensen K, Ran F, et al. Physical Review A, 2012, 86(5): 27454.
[6] Acosta V M, Bauch E, Ledbetter M P, et al. Physical Review B Condensed Matter, 2009, 80(11): 115202.
[7] LI Rong-bin(李荣斌). Acta Physica Sinica(物理学报), 2007, 56(1): 395.
[8] Wang Kaiyue, John Steeds, Li Zhihong. Diamond and Related Materials,2012, 23: 162.
[9] ZHANG Xiu-zhi, WANG Kai-yue, LI Zhi-hong, et al(张秀芝, 王凯悦, 李志宏, 等). Acta Physica Sinica(物理学报), 2015, 64(24): 247802.
[10] WANG Kai-yue, LI Zhi-hong, ZHANG Bo, et al(王凯悦, 李志宏, 张 博, 等). Acta Physica Sinica(物理学报), 2012, 61(12): 127804.
[11] YANG Xu-gang, WU Qi-lin(杨序纲, 吴琪琳). Raman Spectroscopy Analysis and Application(拉曼光谱的分析与应用). Beijing:National Defence Industry Press(北京:国防工业出版社), 2008. 9.
[12] Campbell B, Mainwood A. Phys. Status Solidi A, 2000, 181(1): 99.
[13] Ajoy A, Cappellaro P. Physical Review A, 2012, 86(6): 062104. |
[1] |
TAN Ai-ling1, WANG Si-yuan1, ZHAO Yong2, ZHOU Kun-peng1, LU Zhang-jian1. Research on Vinegar Brand Traceability Based on Three-Dimensional Fluorescence Spectra and Quaternion Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2163-2169. |
[2] |
ZHOU Meng-ran1, LAI Wen-hao1*, WANG Ya1, 2, HU Feng1, LI Da-tong1, WANG Rui1. Application of CNN in LIF Fluorescence Spectrum Image Recognition of Mine Water Inrush[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2262-2266. |
[3] |
CHEN Ji-wen1, XU Tao2, LIU Wei2, FANG Zhe1, QU Hua-yang1*, LIANG Yuan1, HU Xue-qiang1, LIU Ming-bo1. On-Line Determination of Light-Rare Earth Distribution by Energy Dispersive-X-Ray Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2284-2289. |
[4] |
LIU Ling1, YANG Ming-xing1, 2*, LU Ren1, Andy Shen1, HE Chong2. Study on EDXRF Method of Turquoise Composition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1910-1916. |
[5] |
ZHANG Li-jiao1,2, LAI Wan-chang1, XIE Bo2, 3, HUANG Jin-chu1, LI Dan1, WANG Guang-xi1, YANG Qiang1, CHEN Xiao-li1. The Effect of Filterson on the Determination of Trace Heavy Metal Cd in Light Matrix by Energy Dispersive X-Ray Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1917-1921. |
[6] |
TANG Zhu-rui1, 2, XI Bei-dou1, 3, 4, HE Xiao-song1, 3, TAN Wen-bing1, 3, ZHANG Hui1, 3, LI Dan1, 3, HUANG Cai-hong1, 3*. Structural Characteristics of Dissolved Organic Compounds during Swine Manure Composting[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1526-1532. |
[7] |
ZHOU Meng-ran, HU Feng*, YAN Peng-cheng, LIU Dong. Laser Induced Fluorescence Spectrum Analysis of Water Inrush in Coal Mine Based on FCM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1572-1576. |
[8] |
WANG Shi-fang, LUO Na, HAN Ping*. Application of Energy-Dispersive X-Ray Fluorescence Spectrometry to the Determination of As, Zn,Pb and Cr in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1648-1654. |
[9] |
ZHANG Qiu-hui1, GUO Zhuang-zhi1, FENG Guo-ying2. The Effect of Incident Laser Power on Raman Spectra and Photoluminescence Spectra of Silicon Nanowires[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1118-1121. |
[10] |
LI Shuang-fang1,2, GUO Yu-bao1*, SUN Yan-hui2, GU Hai-yang2. Rapid Identification of Sunflower Seed Oil Quality by Three-Dimensional Synchronous Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1165-1170. |
[11] |
ZHU Cong-hai1, 3, CHEN Guo-qing1, 3*, ZHU Chun1, 2, 3, ZHAO Jin-chen1, 3, LIU Huai-bo1, 3, ZHANG Xiao-he1, 3, SONG Xin-shu1, 3. Studies of the Fluorescence Properties of Methanol and Ethanol Based on the Density Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1133-1138. |
[12] |
OUYANG Heng1,2*, XIAO Jian-ren3, LIN Xiu-yong4, FAN Gong-duan4*. Compositional Characteristics of Dissolved Organic Matter in Water Treatment Systems of Water Source Heat Pump Based on Three-Dimensional Fluorescence Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1146-1152. |
[13] |
WANG Yu-tian, LIU Ting-ting*, LIU Ling-fei, YANG Zhe, CUI Yao-yao. Determination of Polycyclic Aromatic Hydrocarbons in Water Based on Three Dimensional Fluorescence Spectroscopy Combined with Wavelet Compression and APTLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1171-1177. |
[14] |
TANG Dong-lin1, WANG Qiao1, CHU Yi-neng2, LI Rui-hai2. Detecting H2S Gas Concentration by 1,8-Naphthalimides Fluorescent Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1319-1323. |
[15] |
WANG Xiang1, 2, 3, ZHAO Nan-jing1, 3*, YU Zhi-min2, MENG De-shuo1, 3, XIAO Xue1, 3, ZUO Zhao-lu1, 3,. Detection Method Progress and Development Trend of Organic Pollutants in Soil Using Laser-Induced Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 857-863. |
|
|
|
|