| 光谱学与光谱分析 |
|
|
|
|
|
| Elemental Analysis of Nine Herbal Drugs for Nourishing Blood by Inductively Coupled Plasma Atomic Emission Spectroscopy with Microwave Digestion |
| CHEN Lin-wei, CAI Hao*, WANG Qin, QIAO Feng-xian, QIN Kun-ming, CAI Bao-chang |
| School of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China |
|
|
|
|
Abstract An analytical method has been developed for the determination of traces of Zn, Mn, Na, K, Ca, Mg, Ni, Pb, Se, Fe, Cu, Al, B, Ti, Sn, Hg, and Li in nine herbal drugs for nourishing blood by ICP-AES. The data showed that nine herbal drugs for nourishing blood were abundant in the contents of major and trace elements which are healthy for human body, including the trace elements with higher contents, such as Fe, Se, Ni, Mn, and Zn, which are well known for nourishing blood. Elements (macro-elements, essential elements, non-essential elements, and toxic elements) classified in nine herbal drugs for nourishing blood were illustrated in cylindrical histograms. Principal component analysis and hierarchical cluster analysis were applied to the data matrix to evaluate analytical results. The results of hierarchical cluster analysis showed that dendrogram obtained by Ward’s method of hierarchical cluster analysis for seventeen variables and nine samples mainly displayed three clusters. After optimizing the microwave digestion technology, the recoveries of seventeen elements were in the ranges from 97.89% to 103.25% and the RSDs were all lower than 3.0%. ICP-AES combined with microwave digestion is accurate and precise in determining major and trace elements in nine herbal drugs for nourishing blood.
|
|
Received: 2015-06-01
Accepted: 2015-12-23
|
|
|
|
Corresponding Authors:
CAI Hao
E-mail: haocai_98@126.com
|
|
[1] Liu Y G, Wu J W, Wei W, et al. Journal of Natural Medicines, 2013, 67(4): 887.
[2] Chen L W, Qin K M, Zhu Y H, et al. China Journal of Chinese Materia Medica, 2015, 40(4): 602.
[3] Speich M, Pineau A, Ballereau F. Clinica Chimica Acta, 2001, 312(1-2): 1.
[4] Qiu P H, Ai C C, Lin L, et al. Microchemical Journal, 2007, 87(1): 1.
[5] Wang X M, Zhang J, Li T, et al. Spectroscopy and Spectral Analysis, 2015, 35(5): 1398.
[6] Xie J H, Shen M Y, Nie S P, et al. Carbohydrate Polymers, 2013, 94(1): 216.
[7] Cindric＇ I J, Zeiner M, Krppl M, et al. Microchemical Journal, 2011, 99(2): 364.
[8] Yan Q H, Yang L, Wang Q, et al. Journal of Saudi Chemical Society, 2012, 16(3): 287.
[9] Tokalolu . Food Chemistry, 2012, 134(4): 2504.
[10] Zhuang H, Ni Y N, Kokot S. Chemometrics and Intelligent Laboratory Systems, 2014, 135(11): 183.
[11] Badran M, Morsy R, Soliman H, et al. Journal of Trace Elements in Medicine and Biology, 2016, 33: 114. |
| [1] |
ZHU Zhao-zhou1*, YANG Xin-xin1, LI Jun1, HE Hui-jun2, ZHANG Zi-jing1, YAN Wen-rui1. Determination of Rare Earth Elements in High-Salt Water by ICP-MS
After Pre-Concentration Using a Chelating Resin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1862-1866. |
| [2] |
YANG Lin-yu1, 2, 3, DING Yu1, 2, 3*, ZHAN Ye4, ZHU Shao-nong1, 2, 3, CHEN Yu-juan1, 2, 3, DENG Fan1, 2, 3, ZHAO Xing-qiang1, 2, 3. Quantitative Analysis of Mn and Ni Elements in Steel Based on LIBS and GA-PLS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1804-1808. |
| [3] |
CHENG Can1, HEI Da-qian2*, JIA Wen-bao1, SHAN Qing1, LING Yong-sheng1, ZHAO Dong1. Study on Metallic Samples Determination Based on Prompt Gamma
Neutron Activation Analysis Technique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1928-1933. |
| [4] |
WANG Ling-ling1, 2, 3, WANG Bo1, 2, 3, XIONG Feng1, 2, 3, YANG Lu-cun1, 2, LI Jing-jing4, XIAO Yuan-ming1, 2, 3, ZHOU Guo-ying1, 2*. A Comparative Study of Inorganic Elements in Cultivativing Astragalus Membranaceus From Different Habitats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1407-1412. |
| [5] |
LI Xiao-li1, GAO Xin-hua2, WANG Yi-min3*, DENG Sai-wen3, WANG Yi-ya3, LI Song3. Review on the Application of X-Ray Fluorescence Spectrometry in Halogen Elements Analysis in Geological Materials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 997-1009. |
| [6] |
ZHENG Pei-chao, LIU Ran-ning, WANG Jin-mei, FENG Chu-hui, HE Yu-tong, WU Mei-ni, HE Yu-xin. Solution Cathode Glow Discharge-Atomic Emission Spectroscopy Coupled With Hydride Generation for Detecting Trace Mercury and Tin in Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1139-1143. |
| [7] |
LI Ai-yang1, FU Liang2*, CHEN Lin3. Determination of Trace Heavy Metal Elements in Plant Essential Oils by Inductively Coupled Plasma Optical Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1162-1167. |
| [8] |
LI Xue-ping1, 2, 3, ZENG Qiang1, 2, 3*. Development and Progress of Spectral Analysis in Coal Structure Research[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 350-357. |
| [9] |
GONG Ge-lian1, 2, YOU Li-bing3, LI Cong-ying4, FANG Xiao-dong3, SUN Wei-dong4, 5, 6. Advances in Equipment for Deep Ultra-Violet Excimer Laser Ablation Coupled Plasma Mass and Optical Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 555-560. |
| [10] |
LIU Qin-rong1, DU Zi-wei1, LI Jia-zhen1, WANG Yi-shuo1, 3*, GU Xuan2, CUI Xiu-mei2. Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3618-3624. |
| [11] |
LIU Hong-wei1,3, FU Liang2*. Analysis of Metal Impurity Elements in Li4Ti5O12 Through Microwave Plasma Atomic Emission Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3021-3025. |
| [12] |
ZHANG Bin-bin1, 2, LI Jing-bin1, 2, WANG Shi-ning1, 2, HE Peng-fei1, 2, ZHA Xiao-qin1, 2, 3. Determination of Lithium, Iron and Phosphorus in Carbon Composite Lithium Iron Phosphate by Perchloric Acid Digestion-Inductively Coupled Plasma Optical Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2703-2709. |
| [13] |
LIU Ming-bo1,2, LIAO Xue-liang2, CHENG Da-wei1,2, NI Zi-yue1,2, WANG Hai-zhou1,2*. An EDXRF Quantitative Algorithm Based on Fundamental Parameters and Spectrum Unfolding[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2807-2811. |
| [14] |
SHAO Ming-jie1, 2, LIU Wen-ke1, 2*, ZHOU Cheng-bo1, 2, WANG Qi1, 2, LI Bao-shi1, 2. Effects of High Light Duration and Frequencies on Growth and Nutrient Element Contents of Hydroponic Lettuce Cultivated Under LED Red and Blue Light[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2853-2858. |
| [15] |
LIU Wei, YU Qiang*, NIU Teng, YANG Lin-zhe, LIU Hong-jun, YAN Fei. Study on the Relationship Between Element As in Soil of Agricultural Land and Leaf Spectral Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2866-2871. |
|
|
|
|
