| 光谱学与光谱分析 |
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| Spectra Studies on the Interaction of Mn2+ and Poly N-Isopropylacrylamide |
| GUO Shao-fen1, CHEN Ming-qing1, LU Tian-hong2,3, HUANG Xiao-hua1,2*, Mitsuru Akashi4 |
1. School of Chemistry and Materials, Engineering, Southern Yangtze University, Wuxi 214036, China
2. College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210097, China
3. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
4. Department of Applied Chemistry, Faculty of Engineering, Kagoshima University, Kagoshima 890-0065, Japan |
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Abstract The interaction of Mn2+ and poly (N-isopropylacrylamide) (PNIPAAm) was studied by using UV-Vis, FTIR and fluorescence spectroscopic methods. The results indicated that Mn2+ could be bonded to oxygen atoms of carbonyl in PNIPAAm and form the complex of Mn2＋-PNIPAAm. It was found that there existed efficient Förster energy transfer from Mn2+ to PNIPAAm due to the emission spectra of Mn2+ overlapping the excitation spectra of PNIPAAm and that the emission peak of Mn2+ at 561 nm disappeared in Mn2＋-PNIPAAm complex. Therefore the fluorescence intensity at 307 nm was increased by 314%.
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Received: 2004-06-06
Accepted: 2004-08-26
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Corresponding Authors:
HUANG Xiao-hua
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| Cite this article: |
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GUO Shao-fen,CHEN Ming-qing,LU Tian-hong, et al. Spectra Studies on the Interaction of Mn2+ and Poly N-Isopropylacrylamide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1591-1594.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2005/V25/I10/1591 |
[1] LIU Xiao-hua, WANG Xiao-gong，LIU Deng-shan(刘晓华，王晓工，刘德山). Acta Polymerica Sinica(高分子学报), 2001, (6): 773.
[2] Kopecek Jindrich. Euroopean Journal of Pharmaceutical Sciences, 2003, 20(1): 1.
[3] Chilkoti Ashutosh, Dreher Mattew R, Meyer Dan E, et al. Advanced Drug Delivery Reviews, 2002, 54(5): 613.
[4] Barbier Valessa, Viovy Jean-Louis. Current Opinion in Biotechnology, 2003, 14(1): 51.
[5] Kohori Fukashi, Sakai Kiyotaka, Aoyagi Takao, et al. Colloids and Surfaces B: Biointerfaces, 1999, 16(1-4): 195.
[6] CHENG Rong-shi, YANG Hu，YAN Xiao-hu, et al(程时, 杨 琥，严晓虎, 等). Chemical Journal of Chinese Universities(高等学校化学学报), 2001, 22(7): 1262.
[7] LI Jun，SHI Xiang-yang，WU Shi-kang, et al(李 俊, 史向阳, 吴世康, 等). Acta Polymerica Sinica(高分子学报), 2000, (6): 763.
[8] FAN Ying，LIU Shi-zhong(樊 莹, 柳士忠). Chinese Journal of Inorganic Chemistry(无机化学学报), 2002, 18(6): 635.
[9] Kezuka T，Konishi M，Isobe T，et al. Journal of Luminescence, 2000, 87-89: 418.
[10] Taro Toyoda，Almira B Cruz, et al. Thin Solid Films, 2003, 438-439: 132.
[11] Yu J Q, Liu H M, Wang Y Y, et al. Journal of Luminescence, 1998, 76&77: 252.
[12] Konishi Isobe T, Senna M, et al. Journal of Luminescence, 2001, 93: 1.
[13] CAI Yan, CHEN Ming-qing，HUANG Xiao-hua, et al(蔡 彦, 陈明清, 黄晓华, 等). Acta Polymerica Sinica(高分子学报), 2003, (4): 599.
[14] XUE Wei-xing, LI Jian-yu(薛卫星, 李建宇). Fine Chemicals(精细化工), 2002, 19(1): 22.
[15] SUN Bo，ZHAO Ying, XU Duan-fu, WU Jin-guang, ZHOU Wei-jin, XU Guang-xian(孙 波, 赵 莹, 徐端夫, 吴瑾光, 周维金, 徐光宪). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1997, 17(2): 25.
[16] SUN Wen-xiu, XU Yi-zhuang, LIU Xue-xin, GUO Fan-xiu, WU Jin-guang, XU Duan-fu(孙文秀, 徐怡庄, 刘学新, 郭凡修, 吴瑾光, 徐端夫). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001，21(2): 204.
[17] TAO Dong-liang, HUANG Bao-gui，XU Yi-zhuang, LI Wei-hong, YANG Zhan-lan, WU Jin-guang, SUN Ling-dong, YAN Chun-hua, LIU Xue-xin, GUO Fan-xiu, XU Duan-fu(陶栋梁, 黄保贵, 徐怡庄, 李维红, 杨展澜, 吴瑾光, 孙聆东, 严纯华, 刘学新, 郭凡修, 徐端夫). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(6): 740.
[18] Okamoto Y, Ueba Y, Dzhanibekov N F, et al. Macromolecules, 1981, 14: 17.
[19] Mcgehee M D, Dergstedt T, Zhang C. Adv. Mater., 1999, 11: 1349.
[20] TAO Dong-liang, ZHANG Ting, XU Yi-zhuang, et al(陶栋梁, 张 婷, 徐怡庄, 等). Journal of the Chinese Rare Earth Society(中国稀土学报), 2001, 19(6): 543.
[21] HUANG Liang, YU De-quan(黄 量, 于德泉). Application of UV-Vis Spectrum in Organic Chemistry(紫外光谱在有机化学中的应用). Beijing: Science Press(北京: 科学出版社), 1988. 22，31.
[22] HUANG Bao-gui，TAO Dong-liang, XU Yi-zhuang, WANG Jia-jun, WENG Shi-fu, GUO Jing, WU Jin-guang, XU Duan-fu, XU Guang-xian(黄保贵, 陶栋梁, 徐怡庄, 王家君, 翁诗甫, 郭 婧, 吴瑾光, 徐端夫, 徐光宪). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(3): 506.
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