光谱学与光谱分析 |
|
|
|
|
|
Simultaneous Determination of 1-Naphthol and 2-Naphthol in Water by Spectrofluorimetry |
ZHOU Chun1,WANG Qiong-e2,ZHUANG Hui-sheng1* |
1. College of Environment Science and Engineering, Donghua University, Shanghai 201620, China 2. College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China |
|
|
Abstract A simple and sensitive method for the simultaneous determination of trace amounts of 1-naphthol and 2-naphthol by fluorescence spectrofluorimetry was established based on the fact that the excitation and emission wavelengths are different between 1-naphthol and 2-naphthol. The influencing factors, such as pH temperature and surface activator were synthetically considered in the present paper. Interference of similar organic matters and inorganic ions were also taken into account. Compared with traditional methods, the method discussed here needs no complex pretreatments and expensive equipment. So it is convenient, quick and cheap yet with a satisfactory precision and accuracy. The accuracy and precision of results obtained are satisfactory when the concentration ratio (CR) of 1-naphthol to 2-naphthol is in the range of 1:19-19:1; the detection limit (DL) of both naphthols is 8.6×1 0-3 ng·mL-1; the relative standard deviation (RSD) of 1-naphthol and 2-naphthol is 1.26% and 1.45% respectively; and the recovery ratio (RR) of both naphthols is between 95% and 105%. This proposed method has been applied to the determination of trace amounts of 1-naphthol and 2-naphthol in the man-made sample water and environmental imitative water simultaneously, and obtained a satisfactory result, showing that the method discussed here is simple, sensitive and reliable in the future use.
|
Received: 2007-05-10
Accepted: 2007-08-20
|
|
Corresponding Authors:
ZHUANG Hui-sheng
E-mail: huishengzhuang@126.com
|
|
[1] WANG Yong, ZHANG Quan-xing, CHEN Jin-long(王 勇, 张全兴, 陈金龙). Ion Exchange and Adsorption(离子交换与吸附), 1997, 13(6): 573. [2] Jandera P, Churacek J, Bartosova J. Chromatographia, 1980, 8: 485. [3] Terabe S, M iyashita Y, ShibitaO, et al. J. Chomatogr, 1990, 516: 23. [4] LI Jing-feng, LIU Ye(李景峰, 刘 晔). Chinese J. Anal. Chem.(分析化学),1992, 20(12): 1448. [5] HU Jing-tian, YANG Jing-he, ZHOU Guang-jun(胡敬田, 杨景和, 周广军). Chinese J. Anal. Chem.(分析化学),1996, 24(9): 1059. [6] Hercules D M, Rogers L B. Spectrochimica Acta, 1959, B15: 393. [7] TANG Bo, HE Xi-wen, SHEN Han-xi(唐 波, 何锡文, 沈含熙). Environmental Chemistry(环境化学), 1996, 15(1): 61. [8] LING Xiao, CAO YU-zhen, MO Cui-yun, et al(凌 晓, 曹玉珍, 莫翠云, 等). Research Report of Chinese J. Anal. Chem.(分析化学研究简报), 2001, 29(12): 1412. [9] DING Ya-ping, WU Qing-sheng, ZHU Ren-bin, et al(丁亚平, 吴庆生, 朱仁斌, 等). Journal of Anhui Agricultural University(安徽农业大学学报), 1998, 25(3): 310. [10] BAI Bao-lin, ZHANG Hai-rong(白宝林, 张海容). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 772. [11] ZHANG Xiao-song, LIN Chang-shan, HE Tian-jing(张孝松, 林长山, 何天敬). Chemical Reagent(化学试剂), 1989, 11(3): 129. [12] DUAN Wen-sheng, GAN Li-jun(段文胜, 干丽君). Shanghai Dye(上海染料), 2003, (2): 31. [13] Heranandez L M, Algarra G M, Isabel L. Talanta, 1999, 49(3): 679. [14] WANG Yan, LI Xuan-dong(王 炎, 李宣东). Journal of Instrucmental Analysis(分析测试学报), 2002, 21(6): 65. |
[1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[2] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[3] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
[4] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
[5] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
[6] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[7] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[8] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
[9] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[10] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
[11] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
[12] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
[13] |
CHEN Wen-jing, XU Nuo, JIAO Zhao-hang, YOU Jia-hua, WANG He, QI Dong-li, FENG Yu*. Study on the Diagnosis of Breast Cancer by Fluorescence Spectrometry Based on Machine Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2407-2412. |
[14] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
[15] |
LIU Xian-yu1, YANG Jiu-chang1, 2, TU Cai1, XU Ya-fen1, XU Chang3, CHEN Quan-li2*. Study on Spectral Characteristics of Scheelite From Xuebaoding, Pingwu County, Sichuan Province, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2550-2556. |
|
|
|
|