| 光谱学与光谱分析 |
|
|
|
|
|
| A Resolution to the Hydroxy Types of Nephrite and Its Near Infrared Spectroscopy |
| ZHI Ying-xue1, 2, 3, LIAO Zong-ting2, 3, ZHOU Zheng-yu1, 2, 3*, ZHAO Bo-wen2, 3, WANG Bin2, 3 |
1. State Key Laboratory of Marine Geology, Tongji University, Shanghai 200092, China
2. Shanghai Engineering & Technology Research Center for Gem and Materials Technics, Shanghai 200092, China
3. Ocean and Earth Science School, Tongji University, Lab of Gem and Technological Materials, Shanghai 200092, China |
|
|
|
|
Abstract Nephrite samples coming from various origins were investigated using Fourier transform near-infrared spectroscopy (FTNIR). The result shows that samples from some specific origins display four absorption bands of OH stretching vibrations in the 7 000~7 400 cm-1 region, which are ascribed to overtone vibrations respectively of OH(MgMgMg), OH(MgMgFe2+), OH(MgFe2+Fe2+) and OH(Fe2+Fe2+Fe2+), are related to Mg2+ and Fe2+ ion located in M1 and M3 positions of tremolite crystalline structure. With the raise of Fe2+/(Fe2++Mg2+) ratio in tremolite, splitting and redshift of OH vibration bands proceed, gaining an increase in wavenumber, band number and band intensity. Significance of the OH NIR spectra in nephrite origin identification is discussed.
|
|
Received: 2012-10-31
Accepted: 2013-02-25
|
|
|
|
Corresponding Authors:
ZHOU Zheng-yu
E-mail: adamszzyu@yahoo.com.cn
|
|
[1] WANG Shi-qi, DUAN Ti-yu(王时麒，段体玉). Jewellery Science and Technology(珠宝科技), 1998, 10(2)：46.
[2] WU Rui-hua，ZHANG Xiao-hui，LI Wen-wen(吴瑞华, 张晓晖, 李雯雯). Acta Petrologica et Mineralogica(岩石矿物学杂志)，2002，21：50.
[3] Kim Won-Sa. The Journal of Gemmology, 1995, 24(8): 547.
[4] ZHI Ying-xue, LIAO Guan-lin, CHEN Qiong, et al(支颖雪，廖冠琳，陈 琼, 等). Acta Petrologica et Mineralogica(岩石矿物学杂志)，2011，30(supp)：58.
[5] LU Wan-zhen, YUAN Hong-fu, XU Guang-tong(陆婉珍，袁洪福，徐广通). Modern Analysis Technique of NIR(现代近红外光谱分析技术). Beijing: Sinica Petro-Chemstry Press(北京：中国石化出版社)，2000. 193.
[6] CHEN Jing-zhong(陈敬中). Modern Crystal Chemistry(现代晶体化学). Beijing: Science Press(北京：科学出版社), 2010. 209.
[7] Burns R G, Strens R G J. Science, 1966, 153: 890.
[8] GUO Li-he，HAN Jing-yi(郭立鹤，韩景仪). Acta Petrologica et Mineralogica(岩石矿物学杂志)，2002, 21: 68.
[9] ZOU Tian-ren, GUO Li-he, LI Wei-hua, et al(邹天人，郭立鹤，李维华，等). Acta Petrologica et Mineralogica(岩石矿物学杂志)，2002，21：72.
[10] WANG Pu，PAN Zhao-lu, WENG Ling-bao(王 濮，潘兆撸，翁玲宝). Systematic Mineralogy(2nd ed.)(系统矿物学·中册). Beijing: Geological Publishing House(北京：地质出版社)，1984. 330.
[11] Leake B E, et al. American Mineralogist，1997, 82: 1019.
[12] LIU Fei, YU Xiao-yan(刘 飞，余晓燕). Mineral Rwsources and Geology(矿床地质)，2009，23(4): 375.
[13] WEN Luo(闻 辂). Mineral Spectroscopy(矿物光谱学). Chongqing University Publishing House(重庆大学出版社), 1989. 86.
[14] Sabine Petit, Francois Martin, Philippe De Parseval, et al. American Mineralogist, 2004, 89: 319.
[15] Alper N L, Keiser W E, Szymanski, IR-Theory and Practice of Infrared Spectroscopy. New York: Plenum Press, 1964. 380.
[16] ZHONG Hua-bang, ZHANG Hong-shi(钟华邦, 张洪石). Acta Petrologica et Mineralogica(岩石矿物学杂志)，2002，21：108.
[17] ZHOU Zheng-yu, CHEN Ying, LIAO Zong-ting, et al(周征宇，陈 盈，廖宗廷，等). Acta Petrologica et Mineralogica(岩石矿物学杂志)，2009，28(5)：491.
|
| [1] |
WANG Xue-pei1, 2, ZHANG Lu-wei1, 2, BAI Xue-bing3, MO Xian-bin1, ZHANG Xiao-shuan1, 2*. Infrared Spectral Characterization of Ultraviolet Ozone Treatment on Substrate Surface for Flexible Electronics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1867-1873. |
| [2] |
SHI Wen-qiang1, XU Xiu-ying1*, ZHANG Wei1, ZHANG Ping2, SUN Hai-tian1, 3, HU Jun1. Prediction Model of Soil Moisture Content in Northern Cold Region Based on Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1704-1710. |
| [3] |
WANG Yue1, 3, 4, CHEN Nan1, 2, 3, 4, WANG Bo-yu1, 5, LIU Tao1, 3, 4*, XIA Yang1, 2, 3, 4*. Fourier Transform Near-Infrared Spectral System Based on Laser-Driven Plasma Light Source[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1666-1673. |
| [4] |
FENG Rui-jie1, CHEN Zheng-guang1, 2*, YI Shu-juan3. Identification of Corn Varieties Based on Bayesian Optimization SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1698-1703. |
| [5] |
YU Zhi-rong, HONG Ming-jian*. Near-Infrared Spectral Quantitative Analysis Network Based on Grouped Fully Connection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1735-1740. |
| [6] |
MENG Fan-jia1, LUO Shi1, WU Yue-feng1, SUN Hong1, LIU Fei2, LI Min-zan1*, HUANG Wei3, LI Mu3. Characteristic Extraction Method and Discriminant Model of Ear Rot of Maize Seed Base on NIR Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1716-1720. |
| [7] |
PENG Yan-fang1, WANG Jun1, WU Zhi-sheng2*, LIU Xiao-na3, QIAO Yan-jiang2*. NIR Band Assignment of Tanshinone ⅡA and Cryptotanshinone by
2D-COS Technology and Model Application Tanshinone Extract[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1781-1785. |
| [8] |
LI Qing1, 2, XU Li1, 2, PENG Shan-gui1, 2, LUO Xiao1, 2, ZHANG Rong-qin1, 2, YAN Zhu-yun3, WEN Yong-sheng1, 2*. Research on Identification of Danshen Origin Based on Micro-Focused
Raman Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1774-1780. |
| [9] |
WANG Li-qi1, YAO Jing1, WANG Rui-ying1, CHEN Ying-shu1, LUO Shu-nian2, WANG Wei-ning2, ZHANG Yan-rong1*. Research on Detection of Soybean Meal Quality by NIR Based on
PLS-GRNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1433-1438. |
| [10] |
DAI Lu-lu1, YANG Ming-xing1, 2*, WEN Hui-lin1. Study on Chemical Compositions and Origin Discriminations of Hetian Yu From Maxianshan, Gansu Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1451-1458. |
| [11] |
FU Yan-hua1, LIU Jing2*, MAO Ya-chun2, CAO Wang2, HUANG Jia-qi2, ZHAO Zhan-guo3. Experimental Study on Quantitative Inversion Model of Heavy Metals in Soda Saline-Alkali Soil Based on RBF Neural Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1595-1600. |
| [12] |
LI Jia-yi1, YU Mei1, LI Mai-quan1, ZHENG Yu2*, LI Pao1, 3*. Nondestructive Identification of Different Chrysanthemum Varieties Based on Near-Infrared Spectroscopy and Pattern Recognition Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1129-1133. |
| [13] |
CHEN Chu-han1, ZHONG Yang-sheng2, WANG Xian-yan3, ZHAO Yi-kun1, DAI Fen1*. Feature Selection Algorithm for Identification of Male and Female
Cocoons Based on SVM Bootstrapping Re-Weighted Sampling[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1173-1178. |
| [14] |
LI Xue-ying1, 2, LI Zong-min3*, CHEN Guang-yuan4, QIU Hui-min2, HOU Guang-li2, FAN Ping-ping2*. Prediction of Tidal Flat Sediment Moisture Content Based on Wavelet Transform[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1156-1161. |
| [15] |
ZHANG Xiao-hong1, JIANG Xue-song1*, SHEN Fei2*, JIANG Hong-zhe1, ZHOU Hong-ping1, HE Xue-ming2, JIANG Dian-cheng1, ZHANG Yi3. Design of Portable Flour Quality Safety Detector Based on Diffuse
Transmission Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1235-1242. |
|
|
|
|
