光谱学与光谱分析 |
|
|
|
|
|
Laser Ablation and Fast Pulse Discharge Plasma Spectroscopy Analysis of Sn in Soil |
LI Ke-xue, ZHOU Wei-dong*, SHEN Qin-mei, ZHEN Yi, LI Xia-fen, QIAN Hui-guo, SHAO Jie |
Institute of Information Optics, Zhejiang Normal University, Jinhua 321004,China |
|
|
Abstract A developing technique, laser ablation and fast pulse discharge plasma spectroscopy technique (LA-FPDPS), was used for the first time to analyze the Sn concentration in soil. The peak intensity of Sn (284.0 nm) line from soil plasma emission was greatly enhanced in comparison with using the traditional single pulse (SP) LIBS system. Using the technique, calibration curve of Sn in soil was derived. The limit of detection (LOD) for Sn in soil was reduced to be 0.16 μg·g-1. The value is significantly improved compared with the results reported in literature when using LIBS technique, which usually was between 8.2 to 54 μg·g-1 depending on the experimental condition, indicating that this technique possibly will be useful for rapid quantitative elemental analysis in soil.
|
Received: 2010-10-09
Accepted: 2011-02-21
|
|
Corresponding Authors:
ZHOU Wei-dong
E-mail: wdzhou@zjnu.cn
|
|
[1] Loree T R, Radziemski L J. J. Plasma Chem. Plasma Proc., 1981, 1(3): 271. [2] Loree T R, Radziemski L J. Proc. SPIE-Int. Soc. Opt. Eng., 1981, 288: 241. [3] Winefordner J D, Gornushkin I B, Correl T. J. Anal. At. Spectrom., 2004, 19: 1061. [4] Radziemski L J. Spectrochim. Acta Part B, 2002, 57(7): 1109. [5] Cremers D A, Radziemski L J, Loree T R. Appl. Spectrosc, 1984, 38(5): 721. [6] Nakamura S, Ito Y, Sone K. Anal. Chem., 1996, 68: 2981. [7] Gautiera Ce′line, Ficheta Pascal, Menuta Denis. Spectrochim. Acta Part B, 2005, 60(2): 265. [8] Stratis D N, Eland K L, and Angel S M. Appl. Spectrosc., 2000, 54(12): 1719. [9] Measures R M, Kwong H S. Appl. Opt., 1979, 18: 281. [10] Telle H H, Beddows D C, Morris G W. Spetrochim. Acta Part B, 2001, 56(6): 947. [11] Zhou Weidong, Li Kuexue, Shen Qinmei. Optics Express, 2010, 18(3): 2573. [12] Li Kexue, Zhou Weidong, Shen Qinmei. Spectrochimica Acta Part B, 2010, 65(5): 420. [13] Li Kexue, Zhou Weidong, Shen Qinmei. Journal of Analytical Atomic Spectrometry, 2010, 25: 1475. [14] Sabsabi M, Cielo P. Appl. Spectrosc., 1995, 49(4): 499. [15] Oh S Y, Yueh F Y, et al. Appl. Opt., 2010, 49(13): C36. [16] Cremers D A, Radziemski L J. Handbook of Laser-Induced Breakdown Spectroscopy, West Sussex, England; John Wiley & Sons Ltd, 2006, Appendix, C2.
|
[1] |
TIAN Yuan-sheng1, ZHANG Yue1, SUN Wen-yi1, 2*, MU Xing-min1, 2, GAO Peng1, 2, ZHAO Guang-ju1, 2. Spectral Characteristics of Biological Soil Crusts under the Different Types in the Water-Wind Erosion Crisscross Region on the Loess Plateau[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2215-2220. |
[2] |
CAI Liang-hong1, 2, DING Jian-li1, 2*. Prediction for Soil Water Content Based on Variable Preferred and Extreme Learning Machine Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2209-2214. |
[3] |
MU Si-tu1,2, LIU Chun2, WANG Shu3, FAN Hui-ju3, HAN Bing-jun1, XIAO Kang1*. Spectroscopic Characteristics of Hydrophilic/Hydrophobic Fractions of Natural Organic Matters at Various Critical Retention Factors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2221-2226. |
[4] |
FAN Hua1, YAO Gao-yang2, LIU Wei3, XING Zi-hui4, SHI Jin-ming5, GAO Bai1*, CHEN Yang6. Experimental Study on the Treatment of Mercury Contained Soil by Thermal Analytical Low Temperature Plasma Based on Cold Atomic Absorption Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2279-2283. |
[5] |
ZHANG Yan-jun, ZHANG Fang-cao, FU Xing-hu*, XU Jin-rui. Raman Spectra Based on QPSO-MLSSVM Algorithm to Detect the Content of Four Components Blent Oil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1437-1443. |
[6] |
FAN Hua1, ZHANG Chun-yan2, LI Yan-mei1, YI Ling1, SHEN Wei1, ZAN Jin-jing1, GAO Bai1*. Distribution Characteristics and Pollution Evaluation of Soil Uranium in a Tailings Reservoir Based on ICP-OES Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1563-1566. |
[7] |
ZHOU Xiu-qi, LI Run-hua, DONG Bo, HE Xiao-yong, CHEN Yu-qi*. Analysis of Aluminum Alloy by High Repetition Rate Laser Ablation Spark-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1577-1581. |
[8] |
WANG Shi-fang, LUO Na, HAN Ping*. Application of Energy-Dispersive X-Ray Fluorescence Spectrometry to the Determination of As, Zn,Pb and Cr in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1648-1654. |
[9] |
YU Wu1, JIA Xiao-lin2, CHEN Song-chao2, ZHOU Lian-qing1, 2*, SHI Zhou2. Feasibility Analysis of Rapid Estimation of Soil Erosion Factor Using Vis-NIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1076-1081. |
[10] |
ZHANG Guang-na1, LIN Xiang-jie2, LI Yun-mei3, XU Shu-jian1, ZHANG Yu-lan4*. Fourier Transform Infrared Spectroscopy Analysis of Humic Acids from Brown and Cinnamon Soils under Robinia pseudoacacia Forest[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1298-1302. |
[11] |
YANG Yi-fan1, CAI Hong-xing1, WANG Zhao-xuan1, LI Yan2, LI Shuang1*. Inversion Research on the Spectrum Emissivity Based on Slowing Varying Properties of Emissivity[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 702-707. |
[12] |
CHENG Hang1,2, WAN Yuan3, CHEN Yi-yun2,4,5*, WAN Qi-jin1,6,7*, SHI Tie-zhu8, SHEN Rui-li9, GUO Kai2, HU Jia-meng2. Study on the Characteristics and Mechanism of Visible and Near Infrared Reflectance Spectra of Soil Heavy Metals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 771-778. |
[13] |
CHEN Si-ming1, 3, 4, ZOU Shuang-quan1, 4*, MAO Yan-ling2, 4, LIANG Wen-xian1, 4, DING Hui1, 4. Inversion of Soil Organic Matter Content in Wetland Using Multispectral Data Based on Soil Spectral Reconstruction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 912-917. |
[14] |
CONG Lin-xiao1,2, HUANG Min1*, LIU Xiang-lei1, QI Yun-song1. Retrieval of Soil Organic Carbon Based on Bi-Continuum Removal Combined with Orthogonal Partial Least Squares[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 941-947. |
[15] |
GU Yan-hong1,2,3, ZHAO Nan-jing1,3*, MA Ming-jun1,3, MENG De-shuo1,3, JIA Yao1,3, FANG Li1,3, LIU Jian-guo1,3, LIU Wen-qing1,3. Mapping Analysis of Heavy Metal Elements in Polluted Soils Using Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 982-989. |
|
|
|
|