光谱学与光谱分析 |
|
|
|
|
|
The Influence of the Redox Conditions on the Three-Dimensional Excitation-Emission Matrix (3DEEM) Fluorescence Spectroscopy of the Dissolved Organic Matter (DOM) in the Overlying Water |
ZHU Wei-huang, HUANG Ting-lin*, ZHANG Ya-ning |
Key Laboratory of Northwest Water Resources, Environment and Ecology, Ministry of Education, Xi’an University of Architecture and Technology, Xi’an 710055, China |
|
|
Abstract In the present study three-dimensional excitation-emission matrix (3DEEM) fluorescence spectroscopy was applied to characterize the dissolved organic matter (DOM) in the overlying water under aerobic and anaerobic condition. The effects of redox condition were significant on 3DEEM fluorescence spectra of DOM, and in the aerobic condition, the peak intensities of protein-like fluorophores were both higher than those of the humic-like fluorophores, however, the phenomenon of the oxidative degradation of humic-original DOM could be seen. While in anaerobic condition, the peak intensities of the humic-like fluorescence were increased with increasing the incubation time. After the 21 day anaerobic incubation, the peak intensities of the humic-like fluorescence can be as 3.51 and 3.78 times higher than those of protein-like fluorescence. The differences in the DOM fluorescence parameters, e.g., peak intensities, locations and fluorescence index, indicate the difference in the chemical structures and various origins of the DOM in the overlying water between sediment-water interfaces.
|
Received: 2010-02-22
Accepted: 2010-05-26
|
|
Corresponding Authors:
HUANG Ting-lin
E-mail: Huangtinglin@gmail.com
|
|
[1] Coble P G. Marine Chemistry, 1996, 51(4): 325. [2] HAO Rui-xia, CAO Ke-xin,DENG Yi-wen(郝瑞霞, 曹可心, 邓亦文). Chinese Journal of Analysis Laboratory(分析试验室), 2007, 26: 41. [3] OUYANG Er-ming, ZHANG Xi-hui, WANG Wei(欧阳二明, 张锡辉, 王 伟). Water Resources Protection(水资源保护), 2007, 23: 56. [4] WANG Zhi-gang, LIU Wen-qing, LI Hong-bin(王志刚, 刘文清, 李宏斌). Acta Scientiae Circumstantiae(环境科学学报), 2006, (26): 275. [5] Wang Z, Wu Z, Tang S. Water Research, 2009, 43(6): 1533. [6] Sheng G P, Yu H Q. Water Research, 2006, 40(6): 1233. [7] Wu F, Evans R, Dillon P. Environ. Sci. Technol., 2003, 37(16): 3687. [8] FU Ping-qing, LIU Cong-qiang, WU Feng-chang(傅平青, 刘丛强, 吴丰昌). Quaternary Sciences(第四纪研究), 2004, 24(6): 695. [9] Cowie G L, Hedges J I. Organic Geochemistry, 1992, 19(1-3): 229. [10] Claus H, Filip Z. Acta Hydrochimica et Hydrobiologica, 1998, 26(3): 180. [11] Kelton N, Molot L A, Dillon P J. Water Research, 2007, 41(3): 638. [12] McKnight D, Boyer E, Westerhoff P, et al. Limnology and Oceanography, 2001, 46: 38. [13] Godshalk G L, Wetzel R G. Aquatic Botany, 1978, 5: 281. [14] Chen W, Westerhoff P, Leenheer J, et al. Environmental Science & Technology, 2003, 37(24): 5701. [15] Kristensen E, Ahmed S, Devol A. Limnology and Oceanography, 1995, 40(8): 1430. [16] Hertkorn N, Claus H, Schmitt-Kopplin P, et al. Environmental Science & Technology, 2002, 36(20): 4334. [17] Swietlik J, Sikorska E. Water Research, 2004, 38(17): 3791. [18] Cowie G L, Hedges J I. Chemical Geology, 1993, 107(3-4): 447.
|
[1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[2] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[3] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[4] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[5] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[6] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
[7] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
[8] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
[9] |
QIU Cun-pu1, 2, TANG Xiao-xue2, WEN Xi-xian4, MA Xin-ling2, 3, XIA Ming-ming2, 3, LI Zhong-pei2, 3, WU Meng2, 3, LI Gui-long2, 3, LIU Kai2, 3, LIU Kai-li4, LIU Ming2, 3*. Effects of Calcium Salts on the Decomposition Process of Straw and the Characteristics of Three-Dimensional Excitation-Emission Matrices of the Dissolved Organic Matter in Decomposition Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2301-2307. |
[10] |
SHI Chuan-qi1, LI Yan2, HU Yu3, YU Shao-peng1*, JIN Liang2, CHEN Mei-ru1. Fluorescence Spectral Characteristics of Soil Dissolved Organic Matter in the River Wetland of Northern Cold Region, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1517-1523. |
[11] |
LI Yuan-jing1, 2, CHEN Cai-yun-fei1, 2, LI Li-ping1, 2*. Spectroscopy Study of γ-Ray Irradiated Gray Akoya Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1056-1062. |
[12] |
LIU Xia-yan1, CAO Hao-xuan1, MIAO Chuang-he1, LI Li-jun2, ZHOU Hu1, LÜ Yi-zhong1*. Three-Dimensional Fluorescence Spectra of Dissolved Organic Matter in Fluvo-Aquic Soil Profile Under Long-Term Composting Treatment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 674-684. |
[13] |
LÜ Yang1, PEI Jing-cheng1*, ZHANG Yu-yang2. Chemical Composition and Spectra Characteristics of Hydrothermal Synthetic Sapphire[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3546-3551. |
[14] |
ZHANG Yong-bin1, ZHU Dan-dan1, CHEN Ying1*, LIU Zhe1, DUAN Wei-liang1, LI Shao-hua2. Wavelength Selection Method of Algal Fluorescence Spectrum Based on Convex Point Extraction From Feature Region[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3031-3038. |
[15] |
PAN Hong-wei, TONG Wen-bin, LEI Hong-jun*, YANG Guang, SHI Li-li. Spectral Analysis of the Effect of Organic Fertilizer Application on the
Evolution of Organic Matter and Nitrogen in Farmaland[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3116-3123. |
|
|
|
|