光谱学与光谱分析 |
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Analysis of Influence Effect between Every Two Elements of Ni,Cu and Zn in EDXRF and Correction Method Research |
LI Zhe1,2, TUO Xian-guo1,2, YANG Jian-bo1,LIU Chun-lai1,HUANG Lian-mei1 |
1. Applied Nuclear Techniques in Geoscience Key Laboratory of Sichuan Proviance Chengdu University of Technology, Chengdu 610059, China 2. Key Laboratory of Earth Exploration and Information Technology of Ministry of Education, Chengdu University of Technology, Chengdu 610059, China |
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Abstract For problems of matrix effect and correction method in EDXRF technique, three kinds of bogus binary system of Ni-Cu, Ni-Zn and Cu-Zn were chosen as research analyte. Firstly, Lachance-Trail algorithm was employed to get binary influence coefficient. Then, experimental measurement was taken to achieve qualitative analysis of binary influence effect, and good coherence was obtained after comparison. Meanwhile, exponential fitting and logarithm fitting correction equation were established to correct the effects in (bogus) binary sample. Three groups of Ni-Cu duality samples were used to test the fitting method. Compared to the actual results, the relative error of Ni and Cu was less than 4% except the one influenced by branch-ratio deduction method.
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Received: 2009-10-08
Accepted: 2010-01-12
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Corresponding Authors:
LI Zhe
E-mail: lizhe3017@163.com
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[1] TUO Xian-guo, LIANG Xing-zhong, ZHENG Jian-an(庹先国, 梁兴中, 郑建安). Nuclear Thechniques(核技术), 1998, 21(8): 482. [2] Lorc Perring, Daniel Andrey, Marija Basic-Dvorzak, et al. Journal of Food Composition and Analysis,2005, 18: 655. [3] Morgenstern P, Bruggemann L, Wennrich R. Spectrochimica Acta Part B, 2005, 60: 1373. [4] TUO Xian-guo, MU Ke-liang, LI Zhe, et al(庹先国,穆克亮,李 哲,等). Spectroscopy And Spectral Analysis(光谱学与光谱分析), 2009, 29(11):3158. [5] Lachance G R, Traill R J. Can. J. Spectrosc., 1966, 11: 43. [6] Rousseau Richard M. Spectrochimica Acta Part B,2006,61:759. [7] CAO Li-guo, DING Yi-min, HUANG Zhi-qi(曹利国, 丁益民,黄志琦). Method of Energy Dispersive X-ray Fluorescence(能量色散X射线荧光方法). Chengdu:Chengdu University of Science and Technology Press(成都:成都科技大学出版社),1998. 137. [8] Broll N. X-ray Spectrom., 1986, 15: 271. [9] Bambynek W, Crasemann B, Fink R W, Rev. Mod. Phys.,1972,44:716. [10] Rao D V, Cesareo R, Gigante G E. Appl. Phys. A, 1996, 62: 381. [11] Rousseau R M. Concepts of Influence Coefficients in XRF Analysis and Calibration, GAC-MAC Annual Meeting, Montreal, QC, Canada, May, 15-17, X-ray Fluorescence Analysis in the Geological Sciences, Advances in Methodology, Short Course, Vol. 7, 1989, 141. [12] Rousseau R M, Bouchard M. X-ray Spectrometry,1986,15:207.
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