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Examination of Polymeric Azomethine Compounds and Their Transition Metal Complexes by Using XRF and XRD Technique |
Ömer Söğüt1*, Betül Demirezen Kara1, Gökhan Apaydın2, Erhan Cengiz3, Ayşe Kazancı4 |
1. Kahramanmaraş Sutcu Imam University, Faculty of Science and Letters, Department of Physics, Kahramanmaraş, Turkey
2. Karadeniz Technical University, Faculty of Science, Department of Physics, Trabzon, Turkey
3. Alanya Alaaddin Keykubat University, Faculty of Engineering, Engineering Basic Sciences Department, Antalya, Turkey
4. Kahramanmaraş Sutcu Imam University, Faculty of Science and Letters, Department of Chemistry, 46100 Kahramanmaraş, Turkey |
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Abstract In this study, the electronic transition properties and structural analysis of the metal complexes (Ni(Ⅱ), Co(Ⅱ), Cu(Ⅱ) and Mn(Ⅱ)) of three different polymer ligands were performed by using XRF and X-ray diffraction (XRD) techniques, respectively. The structural analysis of the polymers and their complexes were performed by XRD technique and some of the polymers were found to be in the face-centred cubic (fcc) structure. In addition, the values of the present K X-ray intensity ratios are significantly greater than the values reported in literature.
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Received: 2017-02-23
Accepted: 2018-01-02
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Corresponding Authors:
Ömer Söğüt
E-mail: osogut@ksu.edu.tr
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[1] Bal M, Ceyhan G, Avar B, et al. Turk. J. Chem., 2014, 38: 222.
[2] Sebastian O, Thapa A. Journal of Chemical and Pharmaceutical Research, 2015, 7(10): 953.
[3] Gupta K C, Sutar A K. Coordination Chemistry Reviews, 2008, 252: 1420.
[4] Vidigal R O, Valério P, Araújo M F, et al. X-Ray Spectrometry, 2016, 45: 63.
[5] Krishnananda S M, Mutturaj H, Badiger N M, et al. X-Ray Spectrometry, 2016, 45: 72.
[6] Towett E K, Shepherd K D, Drake B L. X-Ray Spectrometry, 2016: 45.
[7] Söğüt O, Dönük Ç, Apaydın G, et al. Canadian Journ of Physics, 2014, 92: 435.
[8] Söğüt Ö, Büyükkasap E, Küçükönder A, et al. Applied Spectroscopy Reviews, 1995, 30(3): 175.
[9] Aylıkc V, Ünver Y, Aylıkcı N K, et al. Spectroscopy and Spectral Analysis, 2016, 36(12): 4120.
[10] Söğüt Ö. Radiochimica Acta, 2009, 97(12): 695.
[11] Sögüt Ö, Büyükkasap E, Erdoğan H. Radiation Physics and Chemistry, 2002, 64: 343.
[12] Sapozhnikova I N, Chalykh A Y. Polymer Science U.S.S.R., 1991, 33(8): 1677.
[13] Vrielink J A M, Tiggelaar R M, Gardeniers J G E, et al. Thin Solid Films, 2012, 520: 1740.
[14] Mtioui-Sghaier O, Mendoza-Merono R, Fernandez-Zapico E, et al. Journal of Molecular Structure, 2016, 1105: 105.
[15] Catenescu O, Grigoras M, Colotin G, et al. European Polymer Journal, 2001, 37: 2213.
[16] Jiang H, Sun W, Zheng R. European Polymer Journal, 2006, 42: 425.
[17] Kazanci A, Saribiyik O Y, Serin S. Designed Monomers and Polymers, 2011, 14: 559.
[18] Kazanci A. PhD Thesis, Çukurova University, Institute of Natural and Applied Science, Department of Chemistry, 2010.108.
[19] Demirezen B M. Sci. Thesis, Kahramanmaras Sutcu Imam University, Graduate School of Natural and Applied Sciences, 2014. 68.
[20] Ertugrul M, Sogut O, Simsek O, et al. J. Phys. B- Mol. Opt., 2001, 34: 909.
[21] Scofield J H. Atomic Data Nuclear Data Tables, 1974, 14: 121.
[22] Hansen J S, Freund H U, Fink R W. Nucl. Phys. A, 1970, 142: 604.
[23] Khan M R, Karimi M. X-Ray Spectrometry, 1980, 9 (1): 33.
[24] Rao N V, Reddy S B, Raghavaiah C V, et al. Port. Phys., 1986, 17: 143. |
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