| 光谱学与光谱分析 |
|
|
|
|
|
| UV-Vis Spectrometric Characterization of the Composition of Active Complex in the Ni-P Plating Solution |
| WANG Xu-cheng, CAI Wen-bin, WANG Wei-jiang, LIU Hou-tian* |
| Department of Chemistry, Fudan University, Shanghai 200433, China |
|
|
|
|
Abstract A strong complex agent is normally used in the alkaline chemical plating solution for Ni-P plating in order to prevent Ni ion from precipitation by hydrolysis. To keep a stable pH condition, an NH3-NH4Cl buffer system is used. Traditionally, it is considered that NH3 does not participate in the complex becaｕse of the relativelｙ low Ni-NH3 compleｘinｇ constant，bｕt some eｘperimental resｕlts cannot be eｘplained reasonablｙ. Toｕhami etc. have proposed a ternarｙ Ni-citrate-NH3 compleｘ involved in the discharｇe process，however theｙ cannot ｇive the direct sｕpport on the presence of this compleｘ in solｕtion. In this paper, a UV-Vis spectrometric study was carried out to identify the nickel complex in the Ni-P plating solution, and the results indicated the presence of both Ni-cit binary complex and Ni-cit-ammonia ternary complex. After the systematic investigation of the dependence of UV-Vis spectra on the two ligands (cit and ammonia), the composition of this Ni-cit-ammonia ternary complex was supposed to be Ni(Ⅱ)(C6H5O3-7)(NH3)3.
|
|
Received: 2003-05-06
Accepted: 2003-08-26
|
|
|
|
Corresponding Authors:
LIU Hou-tian
|
|
| Cite this article: |
|
WANG Xu-cheng,CAI Wen-bin,WANG Wei-jiang, et al. UV-Vis Spectrometric Characterization of the Composition of Active Complex in the Ni-P Plating Solution [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(07): 837-840.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I07/837 |
[1] JIANG Xiao-xia, SHEN Wei(姜晓霞, 沈 伟著). Theory and Practice of Chemistry Plating(化学镀理论与实践). Beijing: National Defence Press(北京：国防工业出版社), 2000. 1.
[2] Lee Sheng-Long，Liang Han-His，Plating & Surface Finishing，1991，78(9)：82.
[3] Wang Y，Geng C H，Deng Z H. Platinｇ & Surface Finishing，1992，79(3)：57.
[4] Lee Sheng-Long，Liang Han-His. Platinｇ & Surface Finishing，1992，79(2)：56.
[5] Lu Guojin，Zangari Giovanni. Electrochimica Acta，2002，47：2969.
[6] Lu Guojin，Zangari G. The 199<sup>th</sup> Electrochemical Society Meetings. Meeting Abstracts, Washington DC, 2001. Abstract 31.
[7] Touhami Ebn M，Cherkaoui M et al. Journal of Applied Electrochemistry，1996，26：487.
[8] Touhami Ebn M，Chassaing E，Cherkaoui M. Electrochimica Acta，1998，43：1721.
[9] Abrantes L M，Correia J P. J. Electrochem. Soc.，1994，141：2356.
[10] Younes O，Gileadi E. J. Electrochem. Soc.，2002，149：C100.
[11] Mallory G O，Hajdu J B. Electroless Plating. Sponsored and Published by AESF. Orlando Florida, 1990，30.
|
| [1] |
LIU Jia-cheng1, 2, HU Bing-liang1, YU Tao1*, WANG Xue-ji1, DU Jian1, LIU Hong1, LIU Xiao1, HUANG Qi-xing3. Nonlinear Full-Spectrum Quantitative Analysis Algorithm of Complex Water Based on IERT[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3922-3930. |
| [2] |
WANG Yu-yan1, YANG Ling-yue1, LI Ming2, YANG Peng-tao3, Andy Hsitien Shen1, WANG Chao-wen1*. Spectral Characteristics and Color Origin of Unstable Yellow Sapphire[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2611-2617. |
| [3] |
LI Qing-bo1, HE Lin-qian1, CUI Hou-xin2, HAO Long-teng2, SUN Dong-sheng2. Determination of Nitrite Nitrogen Concentration in Surface Water Based on UV-Vis Spectral Analysis Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1127-1131. |
| [4] |
ZHANG Jin-qiu, SHAO Tian, Andy Hsitien Shen*. The UV-Vis Spectral Study on Thermal Treatment of Yellowish-Green Apatites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 147-151. |
| [5] |
WANG Xue-ji1, 2, HU Bing-liang1*, YU Tao1, LIU Qing-song1, 2, LI Hong-bo1, 2, FAN Yao1. Analysis of Nitrate in Seawater of Wheat Island Based on LLE-BPNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1503-1508. |
| [6] |
LIU Jia1, YANG Ming-xing1, 2*, DI Jing-ru1, 2, HE Chong2. Spectra Characterization of the Uvarovite in Anorthitic Jade[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1758-1762. |
| [7] |
MAI Wei1, 2, ZHAO Xiao-ming1, 2, ZHANG Jian-fei1, 2*, XU Zhi-wei1, 2, LI Zheng1, 2. Multivariate Calibration of a UV-Vis Spectrophotometer Used for Online Measurements of Chemical Oxygen Demand in Dyeing Wastewater[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2105-2109. |
| [8] |
ZHOU Kun-peng1, 2, BI Wei-hong1*, XING Yun-hai1, CHEN Jun-gang1, ZHOU Tong1, FU Xing-hu1 . Multi Spectral Detection of Ethanol Content in Gasoline Based on SiPLS Feature Extraction and Information Fusion [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 429-434. |
| [9] |
CAO Hong1, QU Wen-tai2*, YANG Xiang-long1, 2, JIA Sheng-yao1, WANG Chun-long1, LU Chen1 . Research on Rapid Determination of Organic Matter Concentration in Aquaculture Water Based on Ultraviolet/Visible Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(11): 3015-3019. |
| [10] |
LIU Xue-mei, ZHANG Hai-liang* . Rapid Determination of COD in Aquaculture Water Based on LS-SVM with Ultraviolet/Visible Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(10): 2804-2807. |
| [11] |
DONG Xue-yan, YAO Hui-fang, REN Fa-zheng, JING Hao* . Characteristics and Antioxidant Activity of Bovine Serum Albumin and Quercetin Interaction in Different Solvent Systems [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(01): 162-166. |
| [12] |
CHEN Tao1, 2, YANG Ming-xing1. Gemology Characterization and Identification of Beryllium Diffused, Heated and Untreated Bicolor Sapphires from Changle City, China [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(03): 651-654. |
| [13] |
FANG Ru, LENG Xiao-jing*, WU Xia, LI Qi, HAO Rui-fang, REN Fa-zheng, JING Hao* . Intermolecular Hydrogen Bond between Protein and Flavonoid and Its Contribution to the Stability of the Flavonoids[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 108-112. |
| [14] |
LI Ya-peng1, ZHAO Yi-li1, SONG Yan-tao1, CHANG Yu-lei1, LIU Lin-lin1,2* . The Study on the UV and Fluorescence Properties of PAMAM Dendrimers [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(02): 422-426. |
| [15] |
ZHENG Huai-li, JIAO Shi-jun, HE Qiang, CHEN Rong, ZHANG Peng, FANG Hui-li . Study of Ferric Species Distribution in Polymeric Phosphate Ferric Sulfate (PPFS) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(02): 551-554. |
|
|
|
|
