| 光谱学与光谱分析 |
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| Rapid Determination of COD in Aquaculture Water Based on LS-SVM with Ultraviolet/Visible Spectroscopy |
| LIU Xue-mei, ZHANG Hai-liang* |
| School of Civil Engineering, East China Jiaotong University, Nanchang 330013, China |
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Abstract Ultraviolet/visible (UV/Vis) spectroscopy was studied for the rapid determination of chemical oxygen demand (COD), which was an indicator to measure the concentration of organic matter in aquaculture water. In order to reduce the influence of the absolute noises of the spectra, the extracted 135 absorbance spectra were preprocessed by Savitzky-Golay smoothing (SG), EMD, and wavelet transform (WT) methods. The preprocessed spectra were then used to select latent variables (LVs) by partial least squares (PLS) methods. Partial least squares (PLS) was used to build models with the full spectra, and back-propagation neural network (BPNN) and least square support vector machine (LS-SVM) were applied to build models with the selected LVs. The overall results showed that BPNN and LS-SVM models performed better than PLS models, and the LS-SVM models with LVs based on WT preprocessed spectra obtained the best results with the determination coefficient (r2) and RMSE being 0.83 and 14.78 mg·L-1 for calibration set, and 0.82 and 14.82 mg·L-1 for the prediction set respectively. The method showed the best performance in LS-SVM model. The results indicated that it was feasible to use UV/Vis with LVs which were obtained by PLS method, combined with LS-SVM calibration could be applied to the rapid and accurate determination of COD in aquaculture water. Moreover, this study laid the foundation for further implementation of online analysis of aquaculture water and rapid determination of other water quality parameters.
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Received: 2014-05-26
Accepted: 2014-07-30
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Corresponding Authors:
ZHANG Hai-liang
E-mail: hailiang.zhang@163.com
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