光谱学与光谱分析 |
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The Determination of Chromium in Feeds by Flame Atomic Absorption Spectrophotometry |
WANG Jian, JIA Bin, GUO Li-ping,LIN Qiu-ping |
The Supervision and Test Centre of Agricultural Product Quality, Ministry of Agriculture, Zhengzhou 450002, China |
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Abstract Chromium in feeds is regulated by China Standard GB 13078-2001.A method of flame atomic absorption spectrophotometry for the determination of Cr in feeds has been developed in allusion to shortage of China standard method.Several acetylene flow-rate, burner-high and the additive of interference suppressor NH4Cl were studied respectively on the effect of sensitivities of Cr(Ⅲ) and Cr(Ⅵ).The two sets analytical average results of Cr in feed sample determined by calibration curves of Cr(Ⅲ) and Cr(Ⅵ) were tested by t test, no marked discrepancy was found.Optimum instrumental conditions of Cr(Ⅲ) and Cr(Ⅵ) with same sensitivity were confirmed.Sensitivity was 0.014 μg·mL-1 with detection limit 0.70 mg·kg-1.The recoveries were 94.4%-104.9%.Relative standard deviation of sample determination (5-6 times) was 1.90%-4.08%.This method is simply, fast and exact, the detection limit was answered for Cr limit in feeds regulated by GB 13078-2001, it can be applied to the analysis of Cr in feeds.
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Received: 2003-12-26
Accepted: 2004-05-08
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Corresponding Authors:
WANG Jian
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Cite this article: |
WANG Jian,JIA Bin,GUO Li-ping, et al. The Determination of Chromium in Feeds by Flame Atomic Absorption Spectrophotometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(07): 1142-1144.
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URL: |
https://www.gpxygpfx.com/EN/Y2005/V25/I07/1142 |
[1] LIU Hui-fang,SONG Zhi-li(刘惠芳,宋志利).China Feed(中国饲料),2002,(12): 19. [2] John W.Steiner, David C Moy, et al.Analyst, 1987, 112: 1113. [3] TENG Bing,HAN You-wen(滕 冰,韩友文).China Feed(中国饲料),2000,(6): 7. [4] YUAN Jian-min,XING Feng-ying(袁建民,邢凤英).China Feed(中国饲料),2000,(16): 12. [5] The First Compiler of China Standard Press(中国标准出版社第一编辑室).China Agricultural Standard Compilation Feed Volume(中国农业标准汇编饲料卷).Beijing: China Standard Press(北京: 中国标准出版社),2001.20. [6] The First Compiler of China Standard Press(中国标准出版社第一编辑室).China Agricultural Standard Compilation Feed Volume(中国农业标准汇编饲料卷).Beijing: China Standard Press(北京: 中国标准出版社), 2001.164. [7] DENG Bo(邓 勃).Flame Atomic Absorption Spectrophotometry(原子吸收分光光度法).Beijing: Tsinghua University Press(北京: 清华大学出版社),1981. [8] SUN Rui-xia, ZHOU Ling-zhu, XUE Wan-gang, SUN Jian-hui(孙瑞霞,周玲珠,薛万刚,孙剑辉).Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(5): 853.
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