| 光谱学与光谱分析 |
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| Infrared Spectra and Coordinated Mode of Manganese(Ⅱ)，Iron(Ⅱ)，Cobalt(Ⅱ) Complexes with Dithiolene and 1, 10-Phenanthroline-5, 6- Dione Ligands |
| PAN Qing-cai1，ZHAO Yong-he1，PENG Zheng-he2 |
1.Department of Chemistry and Chemical Engineering, Huanghuai College，Zhumadian 463000，China
2.College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072，China |
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Abstract The infrared spectra and far-infrared spectra of M(mnt)(phen-5，6-dione) [M=Manganese(Ⅱ), Iron(Ⅱ), Cobalt(Ⅱ).mnt2-=1, 2-dicyano-1, 2-ethylenedithiolate or maleonitriledithiolate，phen-5，6-dione＝1, 10-phenanthroline-5，6-dione] are reported in detail.In infrared spectra and far-infrared, characteristic ν(CN)，ν(CO)，ν(CC)，ν(CN)，ν(C—S)，ν(M—S) and ν(M—N) are very strong.Far-infrared spectra shows that M—S bond is slightly strong than M—N bond.Through comparing infrared spectra, simple regular coordinate mode of M(mnt)(phen-5，6-dione) is analysed.The relation between infrared spectra and structure of the title complexes is discussed.In the title complexes, transition metals ion with 1, 2-dicyano-1, 2-ethylenedithiolate and 1, 10-phenanthroline-5，6-dione form quadridentate distortion tetrahedral configuration molecules.The symmetry is approximate to C2 and C2V.
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Received: 2004-03-28
Accepted: 2004-06-06
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Corresponding Authors:
PAN Qing-cai
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| Cite this article: |
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PAN Qing-cai,ZHAO Yong-he,PENG Zheng-he. Infrared Spectra and Coordinated Mode of Manganese(Ⅱ)，Iron(Ⅱ)，Cobalt(Ⅱ) Complexes with Dithiolene and 1, 10-Phenanthroline-5, 6- Dione Ligands[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(08): 1253-1256.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2005/V25/I08/1253 |
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