光谱学与光谱分析 |
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Spectral Studies of Novel Na Specific Adsorbent Li1+xAlxTi2-x(PO4)3 |
SUN Jian-zhi1, 2,DENG Xiao-chuan1,SONG Shi-tao1, 2,WEI Shu-bin1, 2,MA Pei-hua1 |
1. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China 2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China |
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Abstract A novel Na specific adsorbent Li1+xAlxTi2-x(PO4)3 was synthesized by high temperature solid state reaction method. The samples were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM). Raman and FTIR spectroscopic studies of these materials were carried out, and the vibrational bands were assigned. Their adsorption performances were investigated. The results indicate that the low concentration(x<0.6) Al dopant does not affect the structure of the material but makes it able to selectively adsorb sodium. The adsorbing test results show that its exchange capacity is high with the maximum value of adsorption capacity of 11.76 mg·g-1 at x=0.4 and pH=10.0-11.0. So it can be used to remove the microamounts impurity-sodium in the production of high purity lithium salt.
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Received: 2005-08-10
Accepted: 2005-10-29
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Corresponding Authors:
SUN Jian-zhi
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Cite this article: |
SUN Jian-zhi,DENG Xiao-chuan,SONG Shi-tao, et al. Spectral Studies of Novel Na Specific Adsorbent Li1+xAlxTi2-x(PO4)3 [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(10): 1943-1947.
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https://www.gpxygpfx.com/EN/Y2006/V26/I10/1943 |
[1] Brown Patrick M, Beckerman Susan G. U.S. Pat., No.4, 980, 136, 1990. [2] Deberitz Jurgen, Kobele Klaus, et al. U.S. Pat., No.6, 063, 345. 2000. [3] Frianeza-Kullberg Teresita C, Barnette Darrish. U. S. Pat., No.4, 859, 343. 1989. [4] Katesa A J, Condrate R A. Spectroscopy Letters, 1997, 30(8): 1561. [5] Baran E J, Vassallo M B, Liii K H. Vibrational Spectroscopy, 1996, 10: 331. [6] ZHANG Han-hui, LIN Zheng-zhong, HUANG Chang-cang, et al(张汉辉, 林郑忠, 黄长沧, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(5): 557. [7] BAI Ying, WU Feng, WU Chuan(白 莹, 吴 锋, 吴 川). Chinese Journal of Light Scattering(光散射学报), 2003, 15(4): 231. [8] ZHAO Ji-shou, LIU Fen-zhen, YAN Li, et al(赵吉寿, 刘粉珍, 颜 莉, 等). Journal of Yunnan University for Nationalities(云南民族大学学报), 2003, 12(4): 212. [9] Mogus-Milankovic A, Pivac B, Furic K, et al. Phys. Chem. Glasses, 1997, 38(2): 74. [10] Nyquist R A, Kagel R O. Infrared Spectra of Inorganic Compounds(3 800-45 cm<sup>-1</sup>). NewYork: Academic Presss, 1997. [11] WU Xiao-yuan, ZHANG Han-hui, HUANG Chang-cang, et al(吴小园, 张汉辉, 黄长沧, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(6): 694. [12] YU Xi-bin, WANG Gui-hua, LUO Yan-qing, et al(余锡宾, 王桂华, 罗衍庆, 等). Acta Chm. Sin.(化学学报), 2000, 58(6): 548. [13] LIN Xuan-ying, HUANG Chuang-jun, LIN Kui-xun, et al(林璇英, 黄创君, 林揆训, 等). Acta Phy. Sin.(物理学报), 2004, 53(5): 1558. [14] WANG Hai-zeng, XU Hua-wei, PANG Wen-qin, et al(王海增, 徐华伟, 庞文琴, 等). Journal of Salt Lake Research(盐湖研究), 2003, 11(3): 31. [15] ZHANG Yu-rong, WANG Wen-ji(张玉荣, 王文继). Journal of Inorganic Materials(无机材料学报), 2004, 19(2): 349.
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