光谱学与光谱分析 |
|
|
|
|
|
Spectral Research on the Effect Various Metal Ions on the of Photocatalytic Degradation Properties of TiO2 Nanocrystal |
CHEN You-cun1, ZHU Jing-miao1, ZHANG Yuan-guang1, ZHOU Geng-tao2 |
1. Department of Chemistry, Anqing Teachers Colledge, Anqing 246011, China 2. Department of Chemistry, University of Science and Technology of China, Hefei 230026, China |
|
|
Abstract TiO2 nanocrystalline was prepared by a emulsion method in the mixed solvent of cyclohexane and acetic anhydride using titanyl organic compound as the precursor. The prepared product was characterized by means of X-ray diffraction (XRD) and Fourier transform infrared spectrum (FTIR). The photocatalytic oxidation of methyl orange with TiO2 loaded with various metal ions was discussed. The spectral research results showed that the photocatalytic reaction of methyl orange with TiO2 loaded with Bi3+ was promoted, some metal ions caused almost no promotion of TiO2 oxidation of methyl orange, and Ni2+ and Fe3+ ions caused a little promotion. The best mass proportion of Bi3+ and TiO2 was defined as 1∶8, which has a good photocatalytic activity. The photocatalytic degradation reaction of methyl orange was affected by the concentration of TiO2 nanocrystal, and when the mass proportion of Bi3+ and TiO2 is 1∶8, the best photocatalytic activity concentration of TiO2 is about 1.6 g·L-1.
|
Received: 2003-12-26
Accepted: 2004-05-11
|
|
Corresponding Authors:
CHEN You-cun
|
|
Cite this article: |
CHEN You-cun,ZHU Jing-miao,ZHANG Yuan-guang, et al. Spectral Research on the Effect Various Metal Ions on the of Photocatalytic Degradation Properties of TiO2 Nanocrystal [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(09): 1475-1477.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2005/V25/I09/1475 |
[1] Yu J G, Zhao X J, Zhao Q G. Thin Solid Films, 2000, 379: 7. [2] ZHAO Xiu-feng, SUN Xiao-dong, ZHANG Gui-bin(赵秀峰, 孙晓冬, 张贵彬). Chinese Journal of Applied Chemistry(应用化学), 1998, 15(4): 25. [3] Fujishima A, Rao T N, Tryk D A. J Photochem Photobiol C, 2000, 1(1): 1. [4] Marta I L. Appl Catal B, 1999, 23: 89. [5] WANG Yan-qin, ZANG Li, CHENG Hu-min(王艳芹,张 莉,程虎民). Chemical Journal Chinese Universities(高等学校化学学报), 2000,21:958. [6] ZHAO Jin-wei, YUAN Min, LIU Xiao-heng, WANG Xin(赵金伟,袁 敏,刘孝恒,汪 信). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2003,23(5):1035. [7] WANG Yi-zhong, FU Yan, TANG Hong-xiao(王怡中, 符 雁, 汤鸿宵). Environmental Science(环境科学), 1998, 19(1): 1. [8] ZHANG Guang-yin, LAN Guo-xiang(张光寅, 蓝国祥). Spectroscopy of Lattice Vibration(晶格振动光谱学). Beijing: China Higher Education Press(北京: 高等教育出版社), 1991: 166. [9] HUANG Cong, WANG Liang-yan, Xu Yue-hue(黄 琮,王良焱 ,徐悦华). Chemical World(化学世界), 2002,43:495. [10] WU Feng-qing, RUAN Sheng-ping, LI Xiao-ping(吴凤清, 阮圣平, 李晓平). Function Mater(功能材料), 2001, 32(1):69.
|
[1] |
LENG Jun-qiang, LAN Xin-yu, JIANG Wen-shuo, XIAO Jia-yue, LIU Tian-xin, LIU Zhen-bo*. Molecular Fluorescent Probe for Detection of Metal Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2002-2011. |
[2] |
DENG Ya-li1, LI Mei2, WANG Ming2*, HAO Hui1*, XIA Wei1. Surface Plasmon Resonance Gas Sensor Based on Silver/Titanium Dioxide Composite Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 743-748. |
[3] |
FENG Ai-ming1, WANG Fu-qiang1, ZHANG Hong1*, AN Peng2, LI Yang-hui1, 3, WANG Le1*. Significantly Improved Luminescence Properties of YAG Phosphor via Localized Surface Plasmon Resonance of Nanotitania[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3081-3085. |
[4] |
JI Bang1,2, ZHAO Wen-feng3, DUAN Jie-li4, FU Lan-hui1, MA Li-zhe3, YANG Zhou1*. Spectral Characteristics of Ag3PO4/GO on Nickel Foam and Photocatalytic Degradation of Ethylene Under Visible Light[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2743-2750. |
[5] |
YANG Li-zhi, HE Li, HE Xu, PENG Sheng-han, WANG Rong, CHEN Zhao-qiong, YANG Xiao-hong, LIU Xin*. Biosorption of Lead, Copper, Cadmium, Zinc and Chromium Ions from Aqueous Solutions by Tartary Buckwheat Tea Particles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 269-277. |
[6] |
TANG Xiao-yu, LUO Yun-jing*, WEI An-qi, WANG Yan. Application of Synchronous and Three-Dimensional Fluorescent Spectrometry in Studies on Interaction Between Sunset Yellow and Human Serum Albumin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(10): 3129-3135. |
[7] |
YAN Fang, ZOU Liang-hui*,WANG Zhi-chun*. Detection of Adsorption for Heavy Metals Ions Based on Terahertz Time Domain Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1044-1048. |
[8] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
[9] |
ZHANG Xiao-lei, ZHU Yong*, DING Yi-min, ZHANG Jie. TiO2/Graphene/Ag Composite Structure for Surface-Enhanced Raman Scattering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3441-3445. |
[10] |
ZHANG Cai-hong, ZHOU Guang-ming*, CHENG Hong-mei, ZHANG Lu-tao, YU Lu, GAO Yi. Surface Enhanced Raman Spectroscopy Study of Complexes of Metal Ions with L-Cysteine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2079-2086. |
[11] |
CHEN Jun-yu, JIANG Gui-min, TENG Yuan, CHEN Dong-dong, YAN Ji-kang*, GAN Guo-you. Research on Infrared Spectra of (Fe, N) Doped TiO2 by the Electronegativity Principle[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2305-2310. |
[12] |
ZHAO Shan1,2,3, YIN Gao-fang1,3, ZHAO Nan-jing1,3*, YANG Rui-fang1,3, XIAO Xue1,3, LIU Jian-guo1,3, LIU Wen-qing1,3. Metal Ions Fluorescence Quenching and Correcting on Dissolved Organic Matter in Drinking Water Using Fluorescence Excitation-Emission Matrix and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2317-2324. |
[13] |
QIN Cui-fang, LI Lei, YU Xian-tong, CHANG Meng-fang, CAO Xiao-dan, PAN Hai-feng*, ZHANG San-jun, CHEN Jin-quan, XU Jian-hua. Fluorescence Properties of Single-Trp Peptide: Response to pH and Metal Ions [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 476-480. |
[14] |
LI Li-xia1, 2, CAO Bing1, 2*, SUN Yu-meng1, 3, LI Hong-yan1, 2, XIAO Qiang1, 2, NI Xiao-hui1, 2, YI Wen-ping1, 2 . Infrared Spectrum Studies of Coatings under Irradiation of Sunlight and Ultraviolet [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3159-3162. |
[15] |
DENG Feng-yu1, HU Tao-ying1, ZHOU Shan-shan1,2, LIU Ying1,2*. Characterization of the Interaction between Acetylisovaleryltylosin Tartrat and Bovine Serum Albumin without or with Zn2+ and Cu2+ by Spectroscopic Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(07): 2351-2357. |
|
|
|
|