| 光谱学与光谱分析 |
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| Synthesis，Characterization and Fluorescent Properties of Copper Phthalocyanine Derivates Substituted by Aliphatic Alcohol |
| ZHANG Liang1,XU Qing-feng1,LU Jian-mei1,2*,YAO She-chun1 |
1. Key Laboratory of Organic Synthesis of Jiangsu Province，School of Chemistry and Chemical Engineering，Suzhou University， Suzhou 215006，China
2. Jiangsu Polytechnic University，Changzhou 213016，China |
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Abstract A series of copper phthalocyanine derivatives substituted by aliphatic chain were obtained by the reaction of tetra-formyl chloride copper phthalocyanine and aliphatic alcohol such as n-butyl alcohol，n-amyl alcohol，n-hexyl alcohol，n-caprylic alcohol and lauryl alcohol. IR，UV-Vis，elemental analysis and 1H NMR verified the structures and substituting degree. The solubility and the relationship between fluorescence and concentration and substituting group were studied in organic solution. It was confirmed that the solubility in organic solution was improved greatly, the fluorescence did not change in linear according to the concentration and the fluorescence of copper phthalocyanine derivatives substituted by the long alkyl was stronger than that substituted by the relatively short alkyl.
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Received: 2005-10-06
Accepted: 2006-01-08
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Corresponding Authors:
LU Jian-mei
E-mail: lujm@suda.edu.cn
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| Cite this article: |
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ZHANG Liang,XU Qing-feng,LU Jian-mei, et al. Synthesis，Characterization and Fluorescent Properties of Copper Phthalocyanine Derivates Substituted by Aliphatic Alcohol[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(04): 773-776.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2007/V27/I04/773 |
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