|
|
|
|
|
|
Detection Sensitivity Improvement Study of LIBS by Combining Au-Nanoparticles and Magnetic Field |
HAO Xiao-jian*, TANG Hui-juan, HU Xiao-tao |
Science and Technology on Electronic Test and Measurement Laboratory, North University of China, Taiyuan 030051, China |
|
|
Abstract In order to enhance the intensity of emission spectra of laser-induced plasma, a method of combining magnetic field enhanced laser induced breakdown spectroscopy(LIBS) with nanoparticle enhanced LIBS (NELIBS) was proposed. 20 nm in diameter Au-nanoparticles(Au NPs) was deposited on the surface of the sample by thermal evaporation. Copper and brass were induced to breakdown by a pulsed Nd∶YAG laser (1 064 nm, maximum energy 200 mJ) at room temperature and under standard atmospheric pressure. Laser-induced breakdown of copper was performed respectively using conventional LIBS, magnetic field-enhanced LIBS, NELIBS, and combining of the magnetic field enhanced LIBS and NELIBS with changing laser energy of 30~110 mJ. The enhancement factor and SNR for Cu Ⅰ 521.8 nm were obtained and the enhancement mechanism was analyzed. Brass and copper were induced to breakdown under four different constrains in the same environment to detect trace elements in the sample. When Au NPs were precipitated on the surface of the sample or the sample precipitated with the Au NPs was put in a magnetic field, the characteristic line of Mg Ⅱ 279.569 nm was found in the spectrum of the copper sample and the characteristic line of Si 251.611 nm was found in the spectrum of the brass sample. The experimental results showed that applying a magnetic field alone or add the Au NPs on the sample surface can effectively enhance the spectral intensity of the plasma, but the enhancement effect is weaker than the combination of the two methods. Magnetic field confinement enhancement of the spectrum is weaker than that of NELIBS. When the NELIBS is combined with magnetic field enhanced LIBS, the highest enhancement factor is up to 14.3 (CuⅠ 521.8 nm) and increased by 28% and 59% compared to magnetic field-enhanced LIBS and NELIBS, respectively. In the four cases, when the laser pulse energy was gradually increased, the Lorentz force that was generated by the magnetic field to restrain the plasma reduced relatively due to the increased expansion intensity of plasma, at the same time, the enhancement effect of the Au NPs on the emission spectrum of the plasma was weakened, the line intensity decreased, and the enhancement factor of plasma gradually decreased and tended to be stable. The combination of NELLBS and magnetic field enhanced LIBS can not only effectively increase the emission line intensity of the plasma and improve SNR of spectral , but also trace elements that cannot be detected in the conventional LIBS due to the low intensity of the spectral line and large background noise can be detected, and the ability of LIBS to detect trace elements is significantly improved, and the limit of detection of trace elements becomes lower. The method of combining NELIBS with magnetic field enhanced LIBS has higher sensitivity and accuracy, providing a new idea for the enhancement method of laser induced breakdown spectroscopy. It has broad application prospects in this field.
|
Received: 2018-03-26
Accepted: 2018-07-30
|
|
Corresponding Authors:
HAO Xiao-jian
E-mail: 15536867445m@sina.com
|
|
[1] YUAN Di, GAO Xun, YAO Shuang, et al(袁 迪, 高 勋, 姚 爽,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016, 36(8): 2617.
[2] ZHAO Xiao-yan(赵晓燕). Chemical Enterprise Management(化工管理), 2016,(5): 129.
[3] ZHONG Xia, HE Yong, QIU Kun-zan, et al(钟 厦, 何 勇, 邱坤赞,等). High Power Laser and Particle Beams(强激光与粒子束), 2015, 27(9): 99002.
[4] LI Zhan-feng, WANG Rui-wen, DENG Hu, et al(李占锋, 王芮雯, 邓 琥,等). Infrared and Laser Engineering(红外与激光工程), 2016, 45(10): 1006003.
[5] HU Li, ZHAO Nan-jing, LIU Wen-qing, et al(胡 丽, 赵南京, 刘文清,等). Chinese Journal of Lasers(中国激光), 2014, 41(7): 715003.
[6] YANG Yu-xiang, KANG Juan, WANG Ya-rui, et al(杨宇翔, 康 娟, 王亚蕊,等). Acta Optica Sinica(光学学报), 2017, 37(11): 1130001.
[7] CHEN Jin-zhong, BAI Jin-ning, WANG Jing, et al(陈金忠, 白津宁, 王 敬,等). High Power Laser and Particle Beams(强激光与粒子束), 2014, 26(1): 12002.
[8] LI Bai-hui, GAO Xun, SONG Chao, et al(李百慧, 高 勋, 宋 超,等). Chinese Journal of Physics(物理学报), 2016, 65(23): 235201.
[9] Giacomo A D, Gaudiuso R, Koral C, et al. Spectrochimica Acta Part B Atomic Spectroscopy, 2014, 98(8): 19.
[10] Sldkov L, Prochazka D, Poízka P, et al. Spectrochimica Acta Part B Atomic Spectroscopy, 2017, 127:48.
[11] LIU Shan-shan(刘杉杉). Guangxi Journal of Light Industry(广西轻工业), 2011,(11): 34.
[12] De Giacomo A, Gaudiuso R, Koral C, et al. Analytical Chemistry,2013,85:10180.
[13] LI Cheng, GAO Xun, LIU Lu, et al(李 丞, 高 勋, 刘 潞,等). Chinese Journal of Physics(物理学报), 2014, 63(14): 145203.
[14] Prochazka D, Bilík M, Prochazková P, et al. Spectrochim. Acta B At. Spectrosc.,2015,108:1. |
[1] |
ZHANG Quan-zhe1, ZOU Sheng1, ZHANG Hong1, 2*. Application and Progress of Residual Magnetometry Based on Electron Paramagnetic Resonance Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 22-28. |
[2] |
HE Yan1, TAO Ran1, YANG Ming-xing1, 2*. The Spectral and Technology Studies of Faience Beads Unearthed in Hubei Province During Warring States Period[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3700-3709. |
[3] |
WANG Wei-en. Analysis of Trace Elements in Ophiocordyceps Sinensis From
Different Habitats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3247-3251. |
[4] |
YE Zi-yi, LIU Shuang, ZHANG Xin-feng*. Screening of DNA Dyes for Colorimetric Sensing Via Rapidly Inducing Gold Nanoparticles Aggregation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2805-2810. |
[5] |
WANG Yan1, HUANG Yi1, 2*, YANG Fan1, 2*, WU Zhong-wei2, 3, GUAN Yao4, XUE Fei1. The Origin and Geochemical Characteristics of the Hydrothermal Sediments From the 49.2°E—50.5°E Hydrothermal Fields of the Southwest Indian Ocean Ultra-Slow Spreading Ridge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2868-2875. |
[6] |
CHEN Chao-yang1, 2, LIU Cui-hong1, 2, LI Zhi-bin3, Andy Hsitien Shen1, 2*. Alexandrite Effect Origin of Gem Grade Diaspore[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2557-2562. |
[7] |
LI Shi-lun1, LIU Tao2, SONG Wen-min3, WANG Tian-le2, LIU Wei1, CHEN Liang1, LI Zhi-gang2*, FENG Shang-shen1*. Study of Two-Dimensional Ordered Magnetic Co Nanosphere Array Film Construction and Its Optical Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2037-2042. |
[8] |
CHEN Di, SONG Chen, SONG Shan-shan, ZHANG Zhi-jie*, ZHANG Hai-yan. The Dating of 9 Batches of Authentic Os Draconis and the Correlation
Between the Age Range and the Ingredients[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1900-1904. |
[9] |
LI Jia-jia, XU Da-peng *, WANG Zi-xiong, ZHANG Tong. Research Progress on Enhancement Mechanism of Surface-Enhanced Raman Scattering of Nanomaterials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1340-1350. |
[10] |
HE Yan1, SU Yue1, YANG Ming-xing1, 2*. Study on Spectroscopy and Locality Characteristics of the Nephrites in Yutian, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3851-3857. |
[11] |
QIAN Cheng1, WANG Bo1, FEI Xue-lian1, YIN Pan-cheng1, HUANG Bo-tao2, XING Hai-bo1*, HU Xiao-jun1*. Detection of Melamine and Cyromazine in Raw Milk by
Aptamer-Facilitated Gold Nanoparticle-Based Logic Gates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2423-2431. |
[12] |
LI Meng-jun1, FANG Hui2. Research of Electromagnetic Field Enhancement of Surface Plasmon
Resonant Mode in Metal Nanosphere-Nanodisc Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1098-1103. |
[13] |
CONG Jian-han1, LUO Yun-jing1*, QI Xiao-hua2, ZOU Ming-qiang2, KONG Chen-chen1. Sensitive Detection of Uric Acid Based on BSA Gold Nanoclusters by Fluorescence Energy Resonance Transfer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 483-489. |
[14] |
ZHANG Can, ZHANG Jie*, DOU Xin-yi, ZHU Yong. Connection of Absorption and Raman Enhancement Characteristics of Different Types of Ag Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1816-1820. |
[15] |
CHEN Chao-yang1,HUANG Wei-zhi1,SHAO Tian1,LI Zhi-bin2,Andy Hsitien Shen1*. Characteristics of Visible Spectrum of Apatite With Alexandrite Effect[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1483-1486. |
|
|
|
|