|
|
|
|
|
|
Analysis of Trace Elements in Wild Artemisia Selengensis Using Inductively Coupled Plasma Tandem Mass Spectrometry |
LIU Hong-wei, NIE Xi-du* |
College of Material and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China |
|
|
Abstract An analytical method for the accurate determination of 12 kinds of trace elements in wild Artemisia Selengensis by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS) was established. In the MS/MS mode, AsO and SeO were formed by mass shift reaction of As and Se with O2, and AsO and SeO were used to eliminate mass spectral interferences. Using NH3/He as the reaction gas, Cr, Mn, Fe, Co, Ni, Cu, and Zn were reacted with NH3/He to form clusters ions, by measuring the cluster ions to eliminate mass spectral interferences. Cd, Hg and Pb were measured using standard mode. The calibration curves of analytes in the 0~200 μg·L-1 range has a good linear relationship, and the detection limit is 0.64~49.61 ng·L-1. By analyzing the national standard material celery (GBW 10048), the difference test was carried out by t test, and the results showed that there was no significant difference between the measured value and the certified value, and the method was proved to be accurate and reliable. The spike recovery was 92.0%~106.1%, and the RSD was 1.6%~4.9% for twelve elements. Analyzing from 4 samples of wild Artemisia Selengensis in different areas of China, according to the results, different sources of 12 elements content in the samples vary, the contents of Mn, Fe, Zn are much higher than the rest of the 9 kinds of elements, and poison rational elements of As, Cd, Hg, Pb content are very low. The method can accurately determine a variety of trace elements in the wild Artemisia Selengensis, and provide scientific theoretical basis for the edible nutrition and safety of the wild Artemisia Selengensis.
|
Received: 2017-12-01
Accepted: 2018-04-11
|
|
Corresponding Authors:
NIE Xi-du
E-mail: nxd1922@163.com
|
|
[1] ZOU Zheng-rong, CHEN Yong-zhong, HUANG Yong-ming(邹峥嵘, 陈永忠, 黄永明). Food Science(食品科学), 2008, 29(10): 453.
[2] Zhang L, Tu Z, Wang H, et al. J. Food Biochem., 2016, 40(4): 603.
[3] Seo J M, Kang H M, Son K H, et al. Planta Med., 2003, 69(3): 218.
[4] Peng L, Wang Y Z, Zhu H B, et al. Food Chem., 2011, 125(3): 1064.
[5] DONG Meng, ZHAO Yun-lin, LEI Cun-xi, et al(董 萌, 赵运林, 雷存喜, 等). Ecology and Environmental Sciences(生态环境学报), 2010, 19(6): 1322.
[6] Santos J, Oliva-Teles M T, Delerue-Matos C, et al. Food Chem., 2014, 151: 311.
[7] Junior J B P, Dantas K G F. Food Chem., 2016, 196, 331.
[8] JIANG Bo, TANG Li-juan, HUANG Jian-hua(江 波, 唐莉娟, 黄建华). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016, 36(5): 1468.
[9] Khan N, Jeong I S, Hwang I M, et al. Food Chem., 2014, 147: 220.
[10] Franze B, Engelhard C. Anal. Chem., 2014, 86(12): 5713.
[11] Jeong S, Lee H, Kim Y T, et al. Microchem. J., 2017, 134: 295.
[12] Choi M S, Ryu J S, Park H Y, et al. J. Anal. Atom. Spectrom., 2013, 28(4): 505.
[13] Barela P S, Silva N A, Pereira J S F, et al. Fuel, 2017, 204: 85.
[14] FU Liang, SHI Shu-yun(符 靓,施树云). Chinese Journal of Analytical Chemistry(分析化学), 2017, 45(8): 1222.
[15] Fu L, Shi S Y, Chen X Q. Spectrochim. Acta B, 2017, 133: 34.
[16] Fu L, Shi S Y, Chen X Q. Food Chem., 2018, 245: 692. |
[1] |
HE Yan1, TAO Ran1, YANG Ming-xing1, 2*. The Spectral and Technology Studies of Faience Beads Unearthed in Hubei Province During Warring States Period[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3700-3709. |
[2] |
WANG Wei-en. Analysis of Trace Elements in Ophiocordyceps Sinensis From
Different Habitats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3247-3251. |
[3] |
WANG Yan1, HUANG Yi1, 2*, YANG Fan1, 2*, WU Zhong-wei2, 3, GUAN Yao4, XUE Fei1. The Origin and Geochemical Characteristics of the Hydrothermal Sediments From the 49.2°E—50.5°E Hydrothermal Fields of the Southwest Indian Ocean Ultra-Slow Spreading Ridge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2868-2875. |
[4] |
CHEN Chao-yang1, 2, LIU Cui-hong1, 2, LI Zhi-bin3, Andy Hsitien Shen1, 2*. Alexandrite Effect Origin of Gem Grade Diaspore[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2557-2562. |
[5] |
ZHANG Hao-yu1, FU Biao1*, WANG Jiao1, MA Xiao-ling2, LUO Guang-qian1, YAO Hong1. Determination of Trace Rare Earth Elements in Coal Ash by Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2074-2081. |
[6] |
CHEN Di, SONG Chen, SONG Shan-shan, ZHANG Zhi-jie*, ZHANG Hai-yan. The Dating of 9 Batches of Authentic Os Draconis and the Correlation
Between the Age Range and the Ingredients[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1900-1904. |
[7] |
HE Yan1, SU Yue1, YANG Ming-xing1, 2*. Study on Spectroscopy and Locality Characteristics of the Nephrites in Yutian, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3851-3857. |
[8] |
CAI Song-tao1, XIE Hua-lin2, HUANG Jian-hua3*. Analysis of Heavy Metal Cd in Cereal-Based Complementary Foods for
Infants and Young Children by Inductively Coupled Plasma Tandem
Mass Spectrometry (ICP-MS/MS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2818-2823. |
[9] |
CHEN Chao-yang1,HUANG Wei-zhi1,SHAO Tian1,LI Zhi-bin2,Andy Hsitien Shen1*. Characteristics of Visible Spectrum of Apatite With Alexandrite Effect[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1483-1486. |
[10] |
LIU Yan-de, GAO Xue, JIANG Xiao-gang, GAO Hai-gen, LIN Xiao-dong, ZHANG Yu, ZHENG Yi-lei. Detection of Anthracnose in Camellia Oleifera Based on Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2815-2820. |
[11] |
LU Xiao-ke1, LI Wei-dong1, LI Xin-wei2. Spectroscopic Analysis of Relics Unearthed from Xipo Site[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1186-1194. |
[12] |
LIANG Piao-piao1, ZHOU Shan-shan1, XING Yun-xin1, LIU Ying1, 2*. Quantification of Trace Elements in Hair Samples from 156 Women Living in the Low-Selenium Region of Inner Mongolia by ICP-AES and AFS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2217-2222. |
[13] |
HAO Xiao-jian*, TANG Hui-juan, HU Xiao-tao. Detection Sensitivity Improvement Study of LIBS by Combining Au-Nanoparticles and Magnetic Field[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1599-1603. |
[14] |
ZHOU Xue-zhong, LIU Hong-wei*. Accurate Determination of Calcium and Chlorine in Food with Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3567-3571. |
[15] |
FU Liang1,3, ZHAO Feng-xuan2, WANG Hai-yan3, WANG Huan-zhe2, CHEN Tao2, XU Jian-hua1, LI Bing1, XIE Hua-lin1*. Impurity Elements Analysis of Catalyst Precursor Ruthenium Nitrosyl Nitrate Using Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3572-3577. |
|
|
|
|