光谱学与光谱分析 |
|
|
|
|
|
Study on Three-Dimensional Fluorescence Spectral Characteristics of Heterocyclic Pesticides in Different Environmental Conditions |
WU Wen-tao1, CHEN Yu-nan1,2,3, XIAO Xue2,3, YANG Rui-fang2,3, ZHAO Nan-jing2,3* |
1. Hefei University of Technology, Hefei 230009, China 2. Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China 3. Key Laboratory of Environmental Optics Monitoring Technology of Anhui Province, Hefei 230031, China |
|
|
Abstract The impact analysis of different environments on the fluorescence emission spectrum of pesticides is critical in detecting the concentration of pesticides. In this paper, three kinds of pesticides, carbendazim, carbaryl and fuberidazole, were selected as the research objects. Under different environment, such as different pH values and the presence of different common anion or cation, three-dimensional fluorescence spectral emission (EEM) characteristic of pesticides were analyzed. The experimental results showed that the primary fluorescence peaks for three kinds of pesticides were at λex/λem=280/300, 310/340 and 280/335 nm (respectively); Carbendazim and fuberidazole had a secondary peak at 245/305 nm (PeakB) and 250/340 nm (PeakB). We can come to the conclusion that with the change of pH value, the characteristic of fluorescence emission of carbendazim and fuberidazole is similar. We can find that the fluorescence intensities of carbendazim and fuberidazole were enhanced with the declining of the solution acidity or alkalinity and the fluorescence intensity of carbaryl had not changed with the declining of the solution acidity, but it increased with the declining of the solution alkalinity; the fluorescence emission spectra of the three kinds of pesticides had good fluorescence characteristics with the scope of the pH varying from 6.16 to 7.4. Twelve common ions in water (CO2-3,SO2-4,NO-3,Cl-,HPO2-4,HCO-3,Mg2+,Zn2+,NH+4,Na+,Ca2+,K+) had no significant effect on fluorescence emission characteristics of carbendazim and fuberidazole. The fluorescence intensities were seriously influenced by Fe3+ and Cu2+. The results showed that the pesticides fluorescence intensities were decreased with the ion concentration increasing. It was necessary to consider the quenching effects on pesticides of Fe3+ and Cu2+for the analytic results. The obtained results provided the basic research for improving the accuracy of the heterocyclic pesticides measurement in water.
|
Received: 2016-04-27
Accepted: 2016-09-12
|
|
Corresponding Authors:
ZHAO Nan-jing
E-mail: njzhao@aiofm.ac.cn
|
|
[1] Phansawan Buran, Prapamontol Tippawan, Thavornyutikarn Prasak, et al. Chiang Mai Journal of Science, 2015, 42(3): 681. [2] Caroline Raeppel, Marie Fabritius, Marie Nief, et al. Environmental Science and Pollution Research, 2015, 22: 2726. [3] Choi Minkyu, Lee In-Seok, Jung Rae-Hong. Food Chemistry, 2016, 205: 1. [4] ZHANG Fan, HUANG Zhi-qiang, ZHANG Ying, et al(张 帆, 黄志强, 张 莹, 等). Chinese Journal of Chromatography(色谱), 2010, 28(4): 348. [5] Edwar Fuentesn, Camila Cid, María E Báez. Talanta, 2015,134: 8. [6] OUYANG Jing-yi, XIAO Hai-bin(欧阳静怡,肖海斌). Chinese Journal of Analysis Laboratory(分析试验室), 2014, 33(2): 167. [7] ZHONG Xiu-di, LIU Yi-hong, LI Yong, et al(钟秀娣, 刘怡虹, 李 勇, 等). Life Science Instruments(生命仪器科学), 2015, 13: 38. [8] Gu Yingchun, Lin Dayong, Li Ran, et al. Luminescence, 2016, 31(2): 380. [9] Pablo Santa-Cruz, Alejandro García-Reiriz. Talanta, 2014, 128: 450. [10] Sharma Devender Kumar, Dharmani Tilak, Sharma Nisha. Bulletin of The Chemical Society of Ethiopia, 2015, 29(2): 173. [11] HE Xiao-song, XI Bei-dou, WEI Zi-min, et al(何小松,席北斗,魏自民,等). Chinese Journal of Analytical Chemistry(分析化学), 2010, 10: 1417. [12] Karunakaran C, Jayabharathi J, Jayamoorthy K. Spectrochimica Acta Part A—Molecular and Biomolecular Spectroscopy, 2013, 112: 417. |
[1] |
ZHANG Yu-yang, CHEN Mei-hua*, YE Shuang, ZHENG Jin-yu. Research of Geographical Origin of Sapphire Based on Three-Dimensional Fluorescence Spectroscopy: A Case Study in Sri Lanka and Laos Sapphires[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1508-1513. |
[2] |
BAI Lu1, 2, XU Xiong1, LIU Quan-zhen1, 2, DU Yan-jun1, 2, 3, WANG Dong-hong1, 2*. Characterization and Analysis of Dissolved Organic Matter in Different
Types of Natural Water in Wuhan by Three-Dimensional
Fluorescence Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1642-1647. |
[3] |
YANG Xin1, 2, WU Zhi-hang3, YE Yin1, 2*, CHEN Xiao-fang1, 2, YUAN Zi-ran1, 2, WANG Jing1, 2. Parallel Factor Analysis of Fluorescence Excitation Emission Matrix Spectroscopy of DOM in Waters of Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 978-983. |
[4] |
SHI Chuan-qi1, 2, LI Yan3, 4, YU Shao-peng1*, HU Bao-zhong1, 2, WANG Hui1, JIN Liang4. Study on the Effect of Foundation Pit Drainage on Water Dissolved Organic Matter in Urban River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 498-504. |
[5] |
WU Yan-han, CHEN Quan-li*, ZHAO An-di, LI Xuan, BAO Pei-jin. Study on the Gemmological Characteristics of Filled Morganite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 575-581. |
[6] |
LIU Tian-shun1, 2, LI Peng-fa1, 2, LI Gui-long1, 2, WU Meng1, LIU Ming1, LIU Kai1, 2, LI Zhong-pei1, 2*. Using Three-Dimensional Excitation-Emission Matrix to Study the Compositions of Dissolved Organic Matter in the Rhizosphere Soil of Continuous Cropping Peanuts With Different Health States[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 634-641. |
[7] |
ZENG Wei-ji1, GOU Si-yu1, CAO Jie-ru1, JIANG Tian-jiu1*, BI Wei-hong2*. Identification of Paralytic Shellfish Algae by Three-Dimensional Fluorescence Spectral[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 130-135. |
[8] |
LOU Meng-han1, 2, JIN Hong-mei2, 3, 4*, LIANG Dong2, 3, ZHU Yan-yun2, 3, ZHU Ning2, 3, 4, LI Dan-yang2, 3. Fluorescence Spectra Characteristics of Dissolved Organic Matter in Mesophilic Anaerobic Digestion of Pig and Dairy Manure Slurries[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 141-146. |
[9] |
CHENG Cheng1,2,3, QIAN Yu-ting4, HUANG Zhen-rong4, JIANG Jing4, SHAO Li4, WANG Zhong-xi4, LÜ Wei-ming4, WU Jing1,2,3*. Fluorescence Excitation Emission Matrix Properties of the Effluents From the Wastewater Treatment Plants in Jiangyin City, Jiangsu Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3791-3796. |
[10] |
LI Yan1, BAI Yang1, WEI Dan1,2*, WANG Wei3, LI Yu-mei3, XUE Hong4, HU Yu1, CAI Shan-shan5. Fluorescence Spectrum Characteristics of Fulvic Acid in Black Soil Under Different Ratios of Organic-Inorganic Fertilizers Combined Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3518-3523. |
[11] |
KONG De-ming1, CHEN Hong-jie1, CHEN Xiao-yu2*, DONG Rui1, WANG Shu-tao1. Research on Oil Identification Method Based on Three-Dimensional Fluorescence Spectroscopy Combined With Sparse Principal Component Analysis and Support Vector Machine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3474-3479. |
[12] |
WANG Si-yuan1, ZHANG Bao-jun1, WANG Hao1, GOU Si-yu2, LI Yu1, LI Xin-yu1, TAN Ai-ling1, JIANG Tian-jiu2, BI Wei-hong1*. Concentration Monitoring of Paralytic Shellfish Poison Producing Algae Based on Three Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3480-3485. |
[13] |
CHEN Xiao-yu1, ZHANG kun1, KONG De-ming2*. Three-Dimensional Fluorescence Partial Derivative Spectroscopy Combined With Parallel Factor Algorithm for Detection of Mixed Oil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3506-3511. |
[14] |
SHEN Yi-jun1, YANG Zi-chen2,3, WANG Ting-yu2,3, WANG Cheng-wei2,3, LI Lei2,3, CHEN Guo-qing2,3*. Study on Fluorescence and Raman Spectral Characteristics of Lipstick[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2665-2669. |
[15] |
LI Yan1,2, WEI Dan1, 2*, WANG Wei3, JIN Liang2, DING Jian-li2, CAI Shan-shan4, HU Yu1, BAI Yang1. Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter Analysis of Straw-Cow Dung Fermentation in Different Proportion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2846-2852. |
|
|
|
|