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Synthesis and Characterization of 4,8,15,22-Tetra[3,3- Bis(P-hydroxyphenyl) Phthalide] Phthalocyanines |
XIA Dao-cheng1, LI Jie-jun1, LI Wan-cheng2, FENG Feng1, LI Dan1 |
1. Datong University,Datong 037009, China
2. State Key Laboratory of Integrated Optoelectronics, Jilin University, Changchun 130021, China |
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Abstract Due to the widely application of Pcs in the fields, such as the communication, medical treatment, chemical industry and so on, therefore, it have been a hot research topic over several decades by scientists. However, along with the human society development and the progress in science and technology, the new phthalocyanine with novle characteristics is still the goal of the scientists. In this dissertion, the synthetic methods of the phthlocyanine are improved. The 4,8,15,22-tetra[3,3-bis(p-hydroxyphenyl)phthalide] phthalocyanines were synthesized and characterized. Using 3-[3,3-bis(p-hydroxyphenyl) phthalide] 2,3-dicyanonitrobenzene and copper acetate monohydrate, dehydrate nicle acetate as starting materials in n-pentanol, DBU as a catalyst, to synthesize 4,8,15,22-tetra[3,3-bis(p-hydroxyphenyl) phthalide] phthalocyanines. The phthalocyanines were characterized, then the results proved that compounds were the target products. And the relevant ultraviolet spectrum, fluorescence spectroscopy and optical luminescence spectroscopy properties were studied..
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Received: 2015-07-10
Accepted: 2016-02-05
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[1] ZHANG Ya-hui, WU Jin-guo, WU Ya-nan, et al(张雅慧, 吴金国, 吴亚男, 等). Chinese Journal of Pharmaceutical Analysis(药物分析杂志), 2007, 27(4): 525.
[2] XIA Dao-cheng, YU Shu-kun, MA Chun-yu, et al(夏道成, 于书坤, 马春雨, 等). Chimical Journal of Chinese Universities(高等学校化学学报), 2008, 29(2): 224.
[3] Cynthia M A, Wesley M S, Johan E V L. Porphyrins and Phthalocyanine, 2001, 5(2): 161.
[4] XU Ming-sheng, LI Zhen-guo(徐明生, 李振国). Journal of Materials Science and Engineering(材料科学与工程学报), 1999, 17(2): 1.
[5] Leznoff C, Lever A B P. Phthalocyanines: Proprities and Applications. New York: Cambridge University Press, 1996. 32.
[6] Mckeown N B. Phthalocyanine Materials: Synthesis, Structure and Function. New York: Cambridge University Press, 1998. 105.
[7] XIA Dao-cheng(夏道成). Synthesis and Optical Character Study of New Substituted Phthalocyanines and Phthalocyanines Crystal(新型取代基酞菁与酞菁晶体的合成及光学性质研究). Changchun: Jilin Unviersity Press(长春:吉林大学出版社), 2009. 15.
[8] Norihito Iida. Chemistry Open, 2015, 4(2): 102.
[9] Torsten Golo Linben, Michel Hanack. European Journal of Inorganic Chemistry, 1994,127(10): 2051.
[10] Jiang Yang, Michael R, Van De Mark. Journal of Heterocyclic Chemistry, 1995, 32(5): 1521. |
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