| 光谱学与光谱分析 |
|
|
|
|
|
| Synthesis, Crystal Structure and Fluorescence Properties of Two Tb(Ⅲ) Complexes |
| FAN Ting-ting1, SONG Shuang1, 2, ZHANG Yi-hua1, 3, HUO Rui1, LI Xia1*, DING Xing-yi1, LIU Yang1, ZHAO Xu1, YAN Chun-hui1 |
1. Department of Chemistry, Capital Normal University, Beijing 100048, China
2. National Institute of Occupational Health and Poison Control, Chinese Center for Disease Control and Prevention, Beijing 100050, China
3. Jinan Daoyi Information Consulting Co., Ltd., Ji’nan 250101, China |
|
|
|
|
Abstract Two coordination polymers with formula of [Tb(3-SBA)(IP)OH(H2O)]·H2O(1) and [Tb(dpdc)1.5(IP)(H2O)]n (2) (3-SBA=3-sulfobenzoate, dpdc=2,2′-diphenyldicarboxylate and IP=1H-imidazo[4,5-f][1,10]-phenanthroline) have been synthesised under hydrothermal condition and characterizated by X-ray single crystal diffraction. The complex 1 possesses a 1D chain structure constructed from Tb(Ⅲ) ions by 3-SBA ligands and OH groups. Complex 2 shows a 1D chain structure constructed from Tb(Ⅲ) ions by dpdc ligands. The two complexes display the characteristic 5D4→7FJ(J=6-3) transitions at 492, 544 584 and 619 nm of Tb(Ⅲ) ion, respectively. No emission from the ligand could be observed, which indicates that the ligands absorb and transfer energy efficiently to central Tb(Ⅲ) ion. The emission decay curves reveal a monoexponential behaviour yielding the lifetime values of 0.287 ms for 1 and 0.439 ms for 2. The quantum yields of luminescence are 9.28% for 1 and 7.07% for 2.
|
|
Received: 2014-08-12
Accepted: 2014-11-15
|
|
|
|
Corresponding Authors:
LI Xia
E-mail: xiali@mail.cnu.edu.cn
|
|
[1] Nicholas F C, Stuart K L, Boujemaa M, et al. Chem. Sci., 2013, 4(4)：1719.
[2] Wu Mingyan, Jiang Feilong, Kong Xiangjian, et al. Chem. Sci., 2013, 4(8): 3104.
[3] Liu Yu, Pan Mei, Yang Qingyuan, et al. Chem. Mater. 2013, 24(10): 1954.
[4] Jiang Hailong, Tsumori N, Xu Qiang. Inorg. Chem., 2010, 49(21): 10001.
[5] Zheng Min, Tan Huaqiao, Xie Zhigang, et al. ACS Appl. Mater. Interfaces, 2013, 5(3): 1078.
[6] Pushkarev A P, Ilichev V A, Maleev A A, et al. J. Mater. Chem. C: Materials for Optical and Electronic Devices, 2014, 2(8), 1532.
[7] Song Shuang, Li Xia, Zhang Yihua, et al. Dalton Trans., 2014, 43(16): 5974.
[8] Zhang Yihua, Li Xia, Song Shuang. Chem. Commun., 2013, 49: 10397.
[9] Song Shuang, Li Xia, Zhang Yihua. Dalton Trans., 2013, 42(29): 10409.
[10] Ma Aiqing, Zhu Longguan. RSC Advances, 2014, 4(28): 14691.
[11] Bhattacharya S, Goswami A, Gole B, et al. Cryst. Growth Des., 2014, 14(6): 2853.
[12] Yesilel O Z, Gunay G, Ng S W. J. Coord. Chem., 2014, 67(15): 2564. |
| [1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [2] |
XIA Ming-ming1, 2, LIU Jia3, WU Meng1, 2, FAN Jian-bo1, 2, LIU Xiao-li1, 2, CHEN Ling1, 2, MA Xin-ling1, 2, LI Zhong-pei1, 2, LIU Ming1, 2*. Three Dimensional Fluorescence Characteristics of Soluble Organic Matter From Different Straw Decomposition Products Treated With Calcium Containing Additives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 118-124. |
| [3] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [4] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [5] |
LIU Wei1, 2, ZHANG Peng-yu1, 2, WU Na1, 2. The Spectroscopic Analysis of Corrosion Products on Gold-Painted Copper-Based Bodhisattva (Guanyin) in Half Lotus Position From National Museum of China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3832-3839. |
| [6] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
| [7] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
| [8] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2，WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
| [9] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
| [10] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
| [11] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
| [12] |
QI Guo-min1, TONG Shi-qian1, LIN Xu-cong1, 2*. Specific Identification of Microcystin-LR by Aptamer-Functionalized Magnetic Nanoprobe With Laser-Induced Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3813-3819. |
| [13] |
HE Yan-ping, WANG Xin, LI Hao-yang, LI Dong, CHEN Jin-quan, XU Jian-hua*. Room Temperature Synthesis of Polychromatic Tunable Luminescent Carbon Dots and Its Application in Sensitive Detection of Hemoglobin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3365-3371. |
| [14] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
| [15] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
|
|
|
|
