| 光谱学与光谱分析 |
|
|
|
|
|
| The Synthesis and Luminescence Measurement of YAG∶Ce3+ Phosphors by High Temperature Solid Phase Method |
| TONG Yi-ping, CHEN Teng |
| Department of Chemical Engineering, Huizhou University, Huizhou 516007, China |
|
|
|
|
Abstract YAG∶Ce3+ luminescence materials were prepared by a high-temperature solid state method. Different influencing factors, e.g., the doping amount of Ce3+, sintering temperature, and sintering time, were investigated by the orthogonal experiment method. The results showed that: (1) the influence of three factors on light-emitting intensity of YAG∶Ce3+ phosphors is in the following order, sintering temperature>>sintering time>the doping amount of Ce3+; (2) the optimum conditions for YAG∶Ce3+ phosphors are: sintering temperature 1 600 ℃, the doping amount of Ce3+ 0.10 mol, and sintering time 4 h. Under these conditions, the light-emitting intensity of YAG∶Ce3+ phosphors prepared is the largest. Furthermore, another optimum conditions are: sintering temperature 1 600 ℃, the doping amount of Ce3+ 0.08 mol, and sintering time 4 h, and the YAG∶Ce3+ phosphors prepared are also excellent based on them. The transition properties and spectral features of excitation and luminescence spectra of these synthesized phosphors were analyzed in detail and assigned as Ce3+ 4f—5d transition.
|
|
Received: 2013-01-24
Accepted: 2013-04-15
|
|
|
|
Corresponding Authors:
TONG Yi-ping
E-mail: typ2469@163.com
|
|
[1] Pan Y, Wu M, Su Q. Journal of Physics and Chemistry of Solids, 2004, 65: 845.
[2] WU Hao, PAN Yue-xiao, GUO Chong-feng, et al(吴 昊, 潘跃晓, 郭崇峰, 等). Chinese Journal of Luminescence(发光学报), 2006, 27(2): 201.
[3] Jiao H, Ma Q, He L, et al. Powder Technology, 2010, 198(2): 229.
[4] Purwanto A, Wang W N, Ogi T, et al. Journal of Alloys and Compounds, 2008, 463(1–2): 350.
[5] WANG Hai-bo, ZHU Xian-zhong, REN Ju-guang(王海波, 朱宪忠, 任巨光). China Light & Lighting(中国照明电器), 2004, (5): 1.
[6] Kang Y C, Lenggoro I W, Park S B, et al. Materials Research Bulletin, 2000, 35: 789.
[7] Yamada M, Narukawa Y, Tamaki H, et al. Ieice Trans. Electron., 2005, E88-C(9): 1860.
[8] ZHOU Zhou, FENG Shi-wei, GUO Chun-sheng, et al(周 舟，冯士维，郭春生，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(10): 2611.
[9] ZHANG Xu-dong, XU Guo-gang, WU Zuo-gui, et al(张旭东, 徐国纲, 吴作贵, 等). Rare Metal Materials and Engineering(稀有金属材料与工程), 2009, 38: 75.
[10] LI Xia, LIU Hong, WANG Ji-yang, et al(李 霞, 刘 宏, 王继扬, 等). Journal of Inorganic Materials(无机材料学报), 2004, 19(5): 1169.
[11] Gao W, Hu Y, Zhuang W, et al. Journal of Rare Earths, 2009, 27(6): 886.
[12] Hassanzadeh-Tabrizi S A. Advanced Powder Technology, 2012, 23(3): 324.
[13] Zhang L, Lu Z, Zhu J, et al. Journal of Rare Earths, 2012, 30(4): 289.
[14] MU Zhong-fei, WANG Yin-hai, HU Yi-hua, et al(牟中飞, 王银海, 胡义华, 等). Acta Phys. Sin.(物理学报), 2011, 60(1): 013201-1.
[15] Wu Z, Zhang X, He W, et al. Journal of Alloys and Compounds, 2009, 468(1-2): 571.
[16] Luo Y, Guo S P, Maksimov O, et al. Applied Physics Letters, 2000, 77(26): 4259. |
| [1] |
LI Zhao, WANG Ya-nan, XU Yi-pu, CAO Jing, WANG Yong-feng, WU Kun-yao, DENG Lu. Synthesis and Photoluminescence of Blue-Emitting Phosphor
YVO4∶Tm3+ for White Light Emitting Diodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 623-628. |
| [2] |
LIU Pan1, 2, LI Jing-bin1, ZHANG Jian-hao1, ZHANG Yi1, CHANG Guo-liang1, HE Peng-fei1, ZHANG Bin-bin1, ZHANG Xin-yao1, 3. Determination of Phosphorus in Welding Flux by Inductively Coupled Plasma Atomic Emission Spectrometry With Ultrasonic Assisted
Hydrochloric Acid Extraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2824-2829. |
| [3] |
ZHANG Yuan-zhe1, LIU Yu-hao1, LU Yu-jie1, MA Chao-qun1, 2*, CHEN Guo-qing1, 2, WU Hui1, 2. Study on the Spectral Prediction of Phosphor-Coated White LED Based on Partial Least Squares Regression[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2347-2352. |
| [4] |
LI Zhao, WU Kun-yao, WANG Ya-nan, CAO Jing, WANG Yong-feng, LU Yuan-yuan. Synthesis and Luminescence Properties of Yellow-Emitting Phosphor Y2.93Al5O12∶0.07Ce3+ Under Blue Light Excitation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 381-385. |
| [5] |
SHEN Xue-jing1，2, LI Dong-ling1，2*, PENG Ya3, WEI Min4, ZHAO Lei1，2, WANG Hai-zhou2，3. Quantitative Distribution Analysis of P/M Super Alloy Composition Based on Micro Beam X-Ray Fluorescence Spectroscopy and Its Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 727-733. |
| [6] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
| [7] |
SHI Qi1, DING Long1, LONG Hong-ming1,2*, CHUN Tie-jun1. Study on Catalytic Combustion of Dioxins From Iron Ore Sintering Flue Gas Over Ce-V-Ti Catalysts by XRD and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 327-332. |
| [8] |
LI Zhao, WANG Yong-feng, CAO Jing, WU Kun-yao, WANG Ya-nan. Preparation and Performance of Red Phosphor ScVO4∶Eu3+ for White LEDs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3077-3080. |
| [9] |
FENG Ai-ming1, WANG Fu-qiang1, ZHANG Hong1*, AN Peng2, LI Yang-hui1, 3, WANG Le1*. Significantly Improved Luminescence Properties of YAG Phosphor via Localized Surface Plasmon Resonance of Nanotitania[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3081-3085. |
| [10] |
YIN Han-di, LI Zhao-xia, SUN Yue, RUAN Yin-jie, ZHUO Shang-jun, CHENG Guo-feng*. In-situ Raman Spectroscopy Study on the Phase Transformation of BiFeO3 Ceramics in the Reaction Sintering Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1162-1167. |
| [11] |
ZHANG Hao1,2, FAN Wei-wei1. Spectroscopic Analysis of Activated Carbon Mixed with Steel Slag Composite Material in Sintering Flue Gas of Desulfurization and Denitration[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1195-1200. |
| [12] |
XU Jian-wen1, 2 , CHEN Guo-qing1, 2*, WU Ya-min1, 2, MA Chao-qun1, 2, GU Jiao1, 2. Establishment of the Spectral Equation of Two Phosphor-Coated White LEDs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 799-803. |
| [13] |
ZHANG Nan, LIU Chun-guang*, ZHANG Meng, YANG Jian, LI Sheng-nan, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation and Optical Properties of Near Infrared Persistentluminescent CaGdAlO4∶Cr3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 373-378. |
| [14] |
FAN Bin1, LIU Jun2, QI Shi-mei3, ZHAO Wen-yu1*. Preparation and Luminescent Properties of Green Phosphors LaGaO3∶Tb3+,Sn4+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 65-70. |
| [15] |
ZHANG Hong1, WANG Le1*, LUO Dong1, ZHENG Zi-shan1, LI Yang-hui1, 2, PAN Gui-ming1. Structural and Luminescence Properties of Eu2+ Doped CaAlSiN3 Silicon Nitride Red Emitting Phosphor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 59-64. |
|
|
|
|
