光谱学与光谱分析 |
|
|
|
|
|
Detection of Organophosphorus Pesticide Residue on the Surface of Apples Using SERS |
LI Xiao-zhou1, YU Zhuang1, YANG Tian-yue1, DING Jian-hua2 |
1. School of Science, Shenyang Ligong University, Shenyang 110159, China 2. School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, China |
|
|
Abstract Traditional pesticide residue detection methods are usually complicated, time-consuming, and destructive. Rapid, nondestructive, online real-time is the development direction of the pesticide testing. In the present paper, we use surface enhanced Raman spectroscopy (SERS) technique to detect the organophosphorus pesticide residue of phorate and fenthion on apple to investigate a fast, nondestructive detection method for the pesticide of phorate and tiguron on apples. The results show that the characteristic frequencies of the two organophosphorus pesticides are easier to identify using surface-enhanced Raman spectroscopy. We select Raman signal at 728 cm-1 for phorate and that at 1 512 cm-1 for fenthion as target peak for quantitative analysis, and use an internal standard to establish phorate and fenthion linear regression model. This method can be used as a quantitative analysis reference of phorate and fenthion.
|
Received: 2013-01-20
Accepted: 2013-03-30
|
|
Corresponding Authors:
LI Xiao-zhou
E-mail: biophy@163.com
|
|
[1] Nollet L M L, Rathore H S. Handbook of Pesticides: Methods of Pesticide Residues Analysis, Boca Raton: CRC Press, 2009. [2] Amine A, Mohammadi H, Bourais I, et al. Biosensors and Bioelectronics, 2006, 21(8): 1405. [3] Jiang X, Li D, Xu X, et al. Biosensors & Bioelectronics, 2008, 23(11): 1577. [4] Marty J L, Garcia D, Rouillon R. Trac Trends in Analytical Chemistry, 1995, 14(7): 329. [5] ZHOU Xiao-fang, FANG Yan, ZHANG Peng-xiang(周小芳,方 炎,张鹏翔). Chinese Journal of Light Scattering(光散射学报). 2004, 16(1): 11. [6] Xie Y, Mukamurezi G, Sun Y, et al. European Food Research and Technology, 2012, 234(6): 1. [7] Saute B, Premasiri R, Ziegler L D, et al. Analyst, 2012, 137(21): 5082. [8] Carrillo-Carrión C, Simonet B M, Valcárcel M, et al. Journal of Chromatography A, 2012, 1225(17): 55. [9] Wang X T, Shi W S, She G W, et al. Applied Physics Letters, 2010, 96(5): 053104. [10] Dolincy F, Futley W, Bentley F. Characteristic Raman Frequency of Organic Compounds(有机化合物的特征拉曼频率). Beijing: Chinese Chemical Society(中国化学会), 1980. [11] LIU Wen-han, YANG Wei, WU Xiao-qiong, et al(刘文涵,杨 未,吴小琼,等). Chinese Journal of Analytical Chemistry(分析化学), 2007, 35(3): 416. |
[1] |
FU Qiu-yue1, FANG Xiang-lin1, ZHAO Yi2, QIU Xun1, WANG Peng1, LI Shao-xin1*. Research Progress of Pathogenic Bacteria and Their Drug Resistance
Detection Based on Surface Enhanced Raman Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1339-1345. |
[2] |
TAN Yang1, WU Xiao-hong2, 3*, WU Bin4, SHEN Yan-jun1, LIU Jin-mao1. Qualitative Analysis of Pesticide Residues on Chinese Cabbage Based on GK Improved Possibilistic C-Means Clustering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1465-1470. |
[3] |
FU Ying-ying, ZHANG Ping, ZHENG Da-wei , LIN Tai-feng*, WANG Hui-qin, WU Xi-hao, SONG Jia-chen. Preparation and SERS Performance of Au-Nylon Flexible Membrane Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 692-698. |
[4] |
SONG Hong-yan, ZHAO Hang, YAN Xia, SHI Xiao-feng, MA Jun*. Adsorption Characteristics of Marine Contaminant Polychlorinated Biphenyls Based on Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 704-712. |
[5] |
LI Wei, ZHANG Xue-li, SU Qin, ZHAO Rui, SONG Hai-yan*. Qualitative Analysis of Chlorpyrifos Pesticide Residues in Cabbage Leaves Based on Visible Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 80-85. |
[6] |
ZHANG Lin1, WEN Bao-ying2, LIU Wei-wei1, FU Wen-xiang1, KONG Jing-lin1*, LI Jian-feng2*. Rapidly Detection of Chemical Warfare Agent Simulants by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 110-114. |
[7] |
XU Yang1, LEI Lei2, YAN Jun1*, CHEN Yu-yun1, TAN Xue-cai1, LIU Yu-qian1, WANG Qi3. Determination of Glutaraldehyde in Water by Surface Enhanced Raman Spectroscopy Based on Metal Organic Framework Composite Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 115-123. |
[8] |
SHI Si-qian, YANG Fang-wei, YAO Wei-rong, YU Hang, XIE Yun-fei*. Rapid Detection of Levamisole Residue in Pork by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3759-3764. |
[9] |
YU Guo-wei1, MA Ben-xue1,2*, CHEN Jin-cheng1,3, DANG Fu-min4,5, LI Xiao-zhan1, LI Cong1, WANG Gang1. Vis-NIR Spectra Discriminant of Pesticide Residues on the Hami Melon Surface by GADF and Multi-Scale CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3701-3707. |
[10] |
QIU Meng-qing1, 2, XU Qing-shan1*, ZHENG Shou-guo1*, WENG Shi-zhuang3. Research Progress of Surface-Enhanced Raman Spectroscopy in Pesticide Residue Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3339-3346. |
[11] |
TAN Ai-ling1, ZHAO Rong1, SUN Jia-lin1, WANG Xin-rui1, ZHAO Yong2*. Detection of Chlorpyrifos Based on Surface-Enhanced Raman Spectroscopy and Density Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3462-3467. |
[12] |
ZHANG Yan-jun, KANG Cheng-long, LIU Ya-qian, FU Xing-hu*, ZHANG Jin-xiao, WANG Ming-xue, YANG Liu-zhen. Rapidly Detection of Total Nitrogen and Phosphorus Content in Water by Surface Enhanced Raman Spectroscopy and GWO-SVR Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3147-3152. |
[13] |
JIN Xiang-peng, LI Xing-jia, ZHANG Chen-jie, YUAN Ya-xian, YAO Jian-lin*. Surface Enhanced Raman Spectroscopic Investigation on SPR Catalyzed Decarboxylation of Ortho-Mercaptobenzoic Acid at Au Nanoparticles Monolayer Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3153-3158. |
[14] |
ZOU Jing-xin1, LIU Yan-qin1, YUAN Ming-zhe1, WANG Qi-hang1, FAN Zhou2, WAN Fu3. Study on the Raman Spectral Characteristics in Ageing Condition Discrimination of Oil-Paper Insulation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3159-3165. |
[15] |
ZHANG Ya-li1, 2, YAN Kang-ting1, 2, WANG Lin-lin2, 3, CHEN Peng-chao2, 3, HAN Yi-fang2, 3, LAN Yu-bin2, 3*. Research Progress of Pesticide Residue Detection Based on Fluorescence Spectrum Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2364-2371. |
|
|
|
|