| 光谱学与光谱分析 |
|
|
|
|
|
| Surface-Enhanced Raman Spectroscopy of Thiuram Pesticide |
| MA Shu-rong1, ZHANG Hai-shan1*, ZHOU Chang-yu1, CHEN Lei2, YU Zhi2, WANG Bing2, ZHAO Bing2* |
1. China-Japan Union Hospital, Jilin University, Changchun 130033, China
2. The State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China |
|
|
|
|
Abstract In the present paper, two SERS-active substrates (silver mirror and HNO3 etched Ag foil) were prepared for thiuram detecting and studying. SERS can provide the molecular vibrational model and structure information of thiuram at low concentration, thus providing very valuable information regarding the structure of the adsorbed molecules. This technique also allows for the in situ study of this molecule when adsorbed on a silver surface and the identification of the chemical state when they are adsorbed on the surface of silver substrate. The SERS study of thiuram was carried out at several adsorbtion concentrations, revealing that two different coordination complexes having different geometries (monodentate and bidentate) are possible adsorbed on the silver surface. These results have a significant importance regarding the understanding of the potential environmental impact of these molecules.
|
|
Received: 2013-01-04
Accepted: 2013-03-21
|
|
|
|
Corresponding Authors:
ZHANG Hai-shan,ZHAO Bing
E-mail: zhanghs@jlu.edu.cn;zhaobing@jlu.edu.cn
|
|
[1] QIN Shu, QIAO Xiong-wu, WANG Xia, et al(秦 曙, 乔雄梧, 王 霞，等). Chinese Journal of Chromatography(色谱), 2010, 28(12): 1162.
[2] WANG Jian, CUI Yan-mei, ZHAO Wei-jun, et, al(王 健, 崔艳梅, 赵伟军，等). Chinese Journal of Analytical Chemistry(分析化学), 2008, 36(4): 533.
[3] Nie S M, Emory S E. Science 1997, 275: 1102.
[4] Kneipp K, Moskovits M, Kneipp H. Surface-Enhanced Raman Scattering-Physics and Applications, Springer, Berlin, Heidelberg, 2006.
[5] Aroca R. Surface-Enhanced Vibrational Spectroscopy, John Wiley & Sons, Ltd, Chichester, 2006.
[6] Li J F, Huang Y F, Ding Y, et al. Nature, 2010, 464(7287): 392.
[7] Han X X, Zhao B, Ozaki Y. Anal. Bioanal. Chem., 2009, 394: 1719.
[8] ZHAO Bing, XU Wei-qing, RUAN Wei-dong, et al(赵 冰, 徐蔚青, 阮伟东，等). Chemical Journal of Chinese Universities(高等学校化学学报)，2008, 29(12): 2591.
[9] Sánchez-Cortés S, Vasina M, Francioso O, et al. Vib. Spectrosc.，1998, 17: 133.
[10] Sánchez-Cortés S, Domingo C, García-Ramos J V, et al. Langmuir，2001, 17: 1157.
[11] Kang J S, Hwang S Y, Lee C J, et al. Bull. Korean Chem. Soc.，2002, 23: 1604.
[12] Zhao Y, Pérez-Segarra W, Shi Q, et al. J. Am. Chem. Soc.，2005, 127: 7328.
[13] Guerrini L, Garcia-Ramos J V, Domingo C, et al. Langmuir，2006, 22: 10924.
[14] Domingo C, Resta V, Sanchez-Cortes S, et al. J. Phys. Chem. C，2007, 111: 8149.
[15] Song W, Wang Y, Hu H L, et al. J. Raman Spectrosc.，2007, 38: 1320.
[16] Wang Y, Zhang J, Jia H Y, et al. J. Phys. Chem. C，2008, 112: 996.
[17] Guerrini L, Garcia-Ramos J V, Domingo C, et al. Phys. Chem. Chem. Phys.，2009, 11: 1787. |
| [1] |
WANG Zi-xiong, XU Da-peng*, ZHANG Yi-fan, LI Jia-jia. Research Progress of Surface-Enhanced Raman Scattering Detection Analyte Molecules[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 341-349. |
| [2] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 470-477. |
| [3] |
HUANG Hui1, 2, TIAN Yi2, ZHANG Meng-die1, 2, XU Tao-ran2, MU Da1*, CHEN Pei-pei2, 3*, CHU Wei-guo2, 3*. Design and Batchable Fabrication of High Performance 3D Nanostructure SERS Chips and Their Applications to Trace Mercury Ions Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3782-3790. |
| [4] |
FU Xing-hu, WANG Zhen-xing, MA Shuang-yu, ZHAO Fei, LU Xin, FU Guang-wei, JIN Wa, BI Wei-hong. Preparation and Properties of Micro-Cavity Silver Modified Fiber SERS Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2800-2806. |
| [5] |
GUI Bo1, 2, YANG Yu-dong1, ZHAO Qian1, 2, SHI Meng1, MAO Hai-yang1, 3*, WANG Wei-bing1, CHEN Da-peng1, 3. A SERS Substrate for On-Site Detection of Trace Pesticide Molecules Based on Parahydrophobic Nanostructures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2499-2504. |
| [6] |
YU Chun-mei, ZHANG Nan, TENG Hai-peng. Investigation of Different Structures of Coals Through FTIR and Raman Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2050-2056. |
| [7] |
SUN Ning, CHEN Jun-fan, ZHANG Jie*, ZHU Yong. The Forming Mechanism of Surface Morphology of Nanostructures and Its Effect on Graphene Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1821-1827. |
| [8] |
ZHANG Can, ZHANG Jie*, DOU Xin-yi, ZHU Yong. Connection of Absorption and Raman Enhancement Characteristics of Different Types of Ag Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1816-1820. |
| [9] |
DOU Xin-yi, ZHANG Can, ZHANG Jie*. Effects of Process Parameters on Double Absorption Resonance Peaks of Au Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1446-1451. |
| [10] |
ZHANG Lei, ZHANG Xia*, WENG Yi-jin, LIU Xiao. Preparation and Properties of Ag/PANI Multifunction Nanozymes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3399-3403. |
| [11] |
XIANG Ying1, FENG An-di2, ZHAO Zheng-zhuo1, SUN Cong-dan1, XU Hao-peng1, SUN Li-na1, XIE Feng-ying1, 3*. Infrared Spectrum and Thermodynamic Studies of Catechin-Black Rice Anthocyanin Complex[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3416-3419. |
| [12] |
TIAN Hui-yan1，LIU Yu1, HUANG Jiao-qi1, XIE Feng-xin1, HUANG Guo-rong1, LIAO Pu1, FU Wei-ling1, ZHANG Yang2*. Research Progress and Application of Surface-Enhanced Raman Scattering Technique in Nucleic Acid Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3021-3028. |
| [13] |
LIU Xiao-hong1,2, DENG Hua1, CHANG Lin2, ZHANG Wei2, JIANG Shan2*. Recent Progress of SERS for Environmental Estrogen Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3038-3047. |
| [14] |
XING Hao-jian, YIN Zeng-he, ZHANG Jie*, ZHU Yong. Theoretical Analysis and Experiment of Raman Enhancement of Graphene-Ordered Silver Nanopores[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2339-2344. |
| [15] |
ZHAO Qian1,2, YANG Yu-dong1, GUI Bo1,2, MAO Hai-yang1,2,3*, LI Rui-rui1, CHEN Da-peng1,2,3. Surface-Enhanced Raman Scattering Transparent Devices Based on Nanocone Forests[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1168-1173. |
|
|
|
|
