光谱学与光谱分析 |
|
|
|
|
|
An Authentication Method of Bear Bile Powder Based on the Near Infrared Spectroscopy |
LI Wen-long1, XING Li-hong1, XUE Dong-sheng2, QU Hai-bin1* |
1. Pharmaceutical Informatics Institute,Zhejiang University,Hangzhou 310058,China 2. Shanghai Kaibao Pharmacy Co., Ltd., Shanghai 201418, China |
|
|
Abstract A method based on the near infrared (NIR) spectroscopy was established for the authentication of bear bile powder and the quantitative analysis of the proportion in the counterfeits. The NIR spectra of 30 bear bile powder samples from 4 different origins, 6 pig gall powder samples, and 65 mixed samples of bear bile powder and pig gall powder with different proportions range from 0 to 100% were collected. The principal component analysis (PCA) was done and well-marked boundaries were observed between the bear bile and the counterfeits, also the bear bile samples from different origins. Partial least squares discriminant analysis (PLS-DA) was used to differentiate the bear bile and the counterfeits, and the rate of accuracy is 95%. Finally, the PLS calibration model was established for the quantitative analysis of the bear bile proportion in the counterfeits, the coefficient of determination of the prediction set is 0.975 9, and the root-mean-square prediction error is 4.25%, which indicated that the result was satisfied. This research contributes to the rapid and undamaged identification of bear bile powder, and also offers reference for the quality identification of other expensive medicinal materials.
|
Received: 2010-04-24
Accepted: 2010-07-10
|
|
Corresponding Authors:
QU Hai-bin
E-mail: quhb@zju.edu.cn
|
|
[1] WANG Li-ying, GAO Xin, TONG Zi-lin, et al(王丽影,高 昕,佟子林,等). Information on Traditional Chinese Medicine(中医药信息), 2005, 22(4): 30. [2] TAN Zheng-jun(谭正军). Information on Traditional Chinese Medicine(中医药信息),1998, 15: 30. [3] YANG Ling-jia, DENG Yong, GU Hong-wei, et al(杨令家,邓 勇,谷宏伟,等). Lishizhen Medicine and Medica Research(时珍国医国药), 1997, 8(3): 239. [4] ZHAO Xu(赵 旭). Journal of Chinese Medicine(中医学报), 2009, 24(5): 35. [5] HE Jian-qing(和建清). Lishizhen Medicine and Medica Research(时珍国医国药), 2001, 12(6): 517. [6] ZHANG Gui-jun, ZHANG Li-hua, YANG Chun-hua, et al(张贵君,张黎化,杨春华,等). Information on Traditional Chinese Medicine(中医药信息), 1995, 12: 17. [7] LI Feng, ZHANG Zhen-qiu, FENG Xia-hong, et al(李 锋,张振秋,冯夏红,等). China Journal of Chinese Materia Medica(中国中药杂志), 1996, 21(10): 589. [8] WANG Shu-chun, Lü Yang, WU Nan, et al(王树春,吕 杨,吴 楠,等). Chinese Herbal Medicine(中草药), 2000, 31(3): 214. [9] ZHAO Yong,JIU Li-xia,SUN Wen-ji(赵 勇,咎丽霞,孙文基). Chinese Journal of Pharmaceutical Analysis(药物分析杂志), 2006, 26(1): 127. [10] ZHANG Yun-hua, LIU Jian-zhong, PENG Xia, et al(张贇华,刘建忠,彭 霞,等). Chinese Journal of Pharmaceutical Analysis(药物分析杂志), 2009, 29(3): 487. [11] ZHU Li-fen, HONG Xiao-kun(朱丽玢,洪筱坤). Chinese Herbal Medicine(中草药), 2004, 35(11): 1255. [12] WANG Yong, WU Chun-min, LU Duan-ping(王 勇,吴春敏,卢端萍). Strait Pharmaceutical Journal(海峡药学), 2006, 18(4): 61. [13] LIU Ping, GU Jin, FENG Jian-yong(刘 萍,古 今,冯建涌). Chinese Journal of Drug Application and Monitoring(中国药物应用与监测), 2005, 4: 17. [14] Kemsley E K. Chemometrics and Intelligent Laboratory Systems, 1996, 33(1): 47. [15] Chan C O, Chu C C, Mok D K W, et al. Analytica Chimica Acta, 2007, 592(2): 121.
|
[1] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
[2] |
LI Yu1, ZHANG Ke-can1, PENG Li-juan2*, ZHU Zheng-liang1, HE Liang1*. Simultaneous Detection of Glucose and Xylose in Tobacco by Using Partial Least Squares Assisted UV-Vis Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 103-110. |
[3] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
[4] |
BAO Hao1, 2,ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
[5] |
WANG Cai-ling1,ZHANG Jing1,WANG Hong-wei2*, SONG Xiao-nan1, JI Tong3. A Hyperspectral Image Classification Model Based on Band Clustering and Multi-Scale Structure Feature Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 258-265. |
[6] |
HE Qing-yuan1, 2, REN Yi1, 2, LIU Jing-hua1, 2, LIU Li1, 2, YANG Hao1, 2, LI Zheng-peng1, 2, ZHAN Qiu-wen1, 2*. Study on Rapid Determination of Qualities of Alfalfa Hay Based on NIRS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3753-3757. |
[7] |
HU Cai-ping1, HE Cheng-yu2, KONG Li-wei3, ZHU You-you3*, WU Bin4, ZHOU Hao-xiang3, SUN Jun2. Identification of Tea Based on Near-Infrared Spectra and Fuzzy Linear Discriminant QR Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3802-3805. |
[8] |
LIU Xin-peng1, SUN Xiang-hong2, QIN Yu-hua1*, ZHANG Min1, GONG Hui-li3. Research on t-SNE Similarity Measurement Method Based on Wasserstein Divergence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3806-3812. |
[9] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
[10] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
[11] |
LUO Li, WANG Jing-yi, XU Zhao-jun, NA Bin*. Geographic Origin Discrimination of Wood Using NIR Spectroscopy
Combined With Machine Learning Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3372-3379. |
[12] |
ZHANG Shu-fang1, LEI Lei2, LEI Shun-xin2, TAN Xue-cai1, LIU Shao-gang1, YAN Jun1*. Traceability of Geographical Origin of Jasmine Based on Near
Infrared Diffuse Reflectance Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3389-3395. |
[13] |
YANG Qun1, 2, LING Qi-han1, WEI Yong1, NING Qiang1, 2, KONG Fa-ming1, ZHOU Yi-fan1, 2, ZHANG Hai-lin1, WANG Jie1, 2*. Non-Destructive Monitoring Model of Functional Nitrogen Content in
Citrus Leaves Based on Visible-Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3396-3403. |
[14] |
FANG Zheng, WANG Han-bo. Measurement of Plastic Film Thickness Based on X-Ray Absorption
Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3461-3468. |
[15] |
HUANG Meng-qiang1, KUANG Wen-jian2, 3*, LIU Xiang1, HE Liang4. Quantitative Analysis of Cotton/Polyester/Wool Blended Fiber Content by Near-Infrared Spectroscopy Based on 1D-CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3565-3570. |
|
|
|
|