光谱学与光谱分析 |
|
|
|
|
|
Hydrophobic Ionic Liquid Extraction-Flame Atomic Absorption Spectrophotometry for Separation/Analysis Trace Gold |
WU Jun,FU Hao,LI Bin-jian,ZHU Xia-shi* |
School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China |
|
|
Abstract In the present paper, the hydrophobicity ionic liquid 1-butyl-3- methylimidazolium hexafluorophosphate ([C4mim][PF6]) was synthesized with 1-methylimidazole and butylbromide and equimolar ammonium hexafluorophosphate, which was applied to preconcentration for trace gold. The factors which may affect preconcentration of gold were investigated. The experimental results showed that the absorbance was linear when the concentration of gold was in the range of 0.40~16.00μg·mL-1, with linear equation A = 0.007 63c +0.073 87(c:μg·mL-1), correlation coefficient r = 0.999 1,and detection limit 0.072 μg·mL-1. The method was applied to the determination of trace gold in water samples satisfactorily.
|
Received: 2010-02-16
Accepted: 2010-05-18
|
|
Corresponding Authors:
ZHU Xia-shi
E-mail: xszhu@yzu.edu.cn
|
|
[1] Liang P, Zhao E, Ding Q, et al. Spectrochim. Acta Part B, 2008,63: 714. [2] Lopez-Garcia I, Campillo N, Arnau-Jerez I, et al. Spectrochim. Acta Part B, 2003, 58: 1715. [3] Kagaya Shigehiro, Takata Daisuke, Yoshimori Torajiro, et al. Talanta,2010, 80: 1364. [4] Wu Y W, Jiang Z C, Hu B, et al. Talanta, 2004, 63: 585. [5] Shamsipur M, Ramezani M. Talanta, 2008, 75: 294. [6] Chakrapani G, Mahanta P L, Murty D S R, et al. Talanta, 2001, 53: 1139. [7] Zhang S M, Pu Q S, Liu P, et al. Anal. Chim. Acta, 2002, 452: 223. [8] Yu M, Sun D, Huang R, et al. Anal. Chim. Acta, 2003, 479: 225. [9] Pohl P, Prusisz B. Microchim. Acta, 2005, 150: 159. [10] Senturk H B, Gundogdu A, Bulut V N, et al. J. Hazard. Mater., 2007, 149: 317. [11] Komarek J, Houserova P. Spectrochim. Acta Part B, 2003, 58: 1525. [12] Konecná M, Komárek J. Spectrochim. Acta Part B, 2007, 62: 283. [13] Srncik M, Kogelnig D, Stojanovic A, et al. Applied Radiation and Isotopes, 2009, 67(12): 2146. [14] SHEN Xing-hai, XU Chao, LIU Xin-qi, et al(沈兴海, 徐 超, 刘新起, 等). Journal of Nuclear and Radiochemistry(核化学与放射化学), 2006, 28(3): 129. [15] Visser A E, Swatloski R P, Griffin S T, et al. Sep. Sci. Technol., 2001, 36(526): 785. [16] CAI Yue-qin, PENG Yan-qing, SONG Gong-hua, et al(蔡月琴, 彭延庆, 宋恭华, 等). Chemical Reagents(化学试剂), 2005, 27(1): 1. [17] ZHAO Feng-yun, WANG Jian-ying, LIU Hong-jie, et al(赵风云, 王建英, 刘洪杰, 等). Chemical Reagents(化学试剂), 2007, 29(4): 229. [18] LU Ze-xiang, YUAN Xia, WU Jian, et al(卢泽湘, 袁 霞, 吴 剑, 等). Chemical World(化学世界), 2005,46(3): 148.
|
[1] |
LIANG Ye-heng1, DENG Ru-ru1, 2*, LIANG Yu-jie1, LIU Yong-ming3, WU Yi4, YUAN Yu-heng5, AI Xian-jun6. Spectral Characteristics of Sediment Reflectance Under the Background of Heavy Metal Polluted Water and Analysis of Its Contribution to
Water-Leaving Reflectance[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 111-117. |
[2] |
LAN Yan1,WANG Wu1,XU Wen2,CHAI Qin-qin1*,LI Yu-rong1,ZHANG Xun2. Discrimination of Planting and Tissue-Cultured Anoectochilus Roxburghii Based on SMOTE and Inception-CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 158-163. |
[3] |
WANG Ling-juan, OU Quan-hong, YAN Hao, TANG Jun-qi*. Preparation and Catalytic Properties of Gold Nanoflowers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3747-3752. |
[4] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
[5] |
LAI Niu, HUANG Qi-qiang, ZHANG Qin-yang, ZHANG Bo-wen, WANG Juan, YANG Jie, WANG Chong, YANG Yu, WANG Rong-fei*. Introduction to Perovskite Quantum Dots and Metal-Organic Frameworks and the Development of Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3321-3329. |
[6] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
[7] |
WANG Peng1, GAO Yong-bao1*, KOU Shao-lei1, MEN Qian-ni1, ZHANG Min1, HE Tao1, YAO Wei2, GAO Rui1, GUO Wen-di1, LIU Chang-rui1. Multi-Objective Optimization of AAS Conditions for Determination of Gold Element Based on Gray Correlation Degree-RSM Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3117-3124. |
[8] |
YU Run-tian1, MA Man-man1, QIN Zhao2*, LIU Guan-nan1, ZHANG Rui1, LIU Dong1*. Study on Diagnostics of Nano Boron-Based Composite Metal Particles in Dispersion Combustion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3252-3259. |
[9] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
[10] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
[11] |
JIN Xu-guang1, 2, WANG Jin-zhuan1, 2*, LI Bei1, 2, QUE Wan-ting1, 2, WANG Liang1, 2, ZHANG Fan1, 2, ZHANG Chi1, ZHOU Jun-gui1, FU Rong-jin1. Quantification of Au in Gold Ornaments Obtained by Different Electroformed Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2755-2760. |
[12] |
LI Xin1, LIU Jiang-ping1, 2*, HUANG Qing1, HU Peng-wei1, 2. Optimization of Prediction Model for Milk Fat Content Based on Improved Whale Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2779-2784. |
[13] |
YE Zi-yi, LIU Shuang, ZHANG Xin-feng*. Screening of DNA Dyes for Colorimetric Sensing Via Rapidly Inducing Gold Nanoparticles Aggregation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2805-2810. |
[14] |
LI Yu-tang1, WANG Lin-zhu1, 2*, LI Xiang3, WANG Jun1. Characterization and Comparative Analysis of Non-Metallic Inclusions in Zirconium Deoxidized Steel[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2916-2921. |
[15] |
ZHANG Zhi-fen1, LIU Zi-min1, QIN Rui1, LI Geng1, WEN Guang-rui1, HE Wei-feng2. Real-Time Detection of Protective Coating Damage During Laser Shock Peening Based on ReliefF Feature Weight Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2437-2445. |
|
|
|
|