| 光谱学与光谱分析 |
|
|
|
|
|
| Synthesis and Spectroscopic Studies of Supermolecules of PWxV12-x-MV |
| WU Xiao-yuan1，ZHANG Han-hui1，2*，HUANG Chang-cang1，SUN Rui-qing1，YANG Qi-yu1，LIN Zhi-hua1，CHEN You-xing1 |
1. Department of Chemistry, Fuzhou University，Fuzhou 350002，China
2. State Key Laboratory of Structral Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China |
|
|
|
|
Abstract A series of supermolecules of PWxV12-x-MV( PWxV12-x: polyoxometalates x=2, 4, 6, 8, 10; MV: methyl violet ) with Keggin structure were prepared and their characters were studied by electronic spectra, infrared spectra and fluorescence spectra. As a result, the supermolecules were formed by the cooperating action between polyoxometalates and methyl violet. In the supermolecule, the structures of cation and anion are not destroyed. With the content of V increasing, the oxidation ability of polyoxometalates anion is enhanced, and the interaction of methyl violet cation and polyoxometalates anion is enhanced too. The FTIR absorption peaks of νas(MOt), νas(M—Ob—M) and νas(M—Oc—M) move from 966, 886, and 804 cm-1 to 955, 875 and 786 cm-1，respectively; the UV-Vis absorption peak moves from 519 to 506 nm; the emission peak excited at 530 nm moves from 692 to 644 nm too. These changes are according with the degree of the interaction of polyoxometalates and methyl violet.
|
|
Received: 2002-11-06
Accepted: 2003-03-26
|
|
|
|
Corresponding Authors:
ZHANG Han-hui
|
|
| Cite this article: |
|
WU Xiao-yuan,ZHANG Han-hui,HUANG Chang-cang, et al. Synthesis and Spectroscopic Studies of Supermolecules of PWxV12-x-MV [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(05): 565-568.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I05/565 |
[1] 王恩波，胡 林. 多酸化学导论. 北京： 化学工业出版社，1998. 125.
[2] Dimitris E. Katsoulis. Chem. Rev.，1998, 98: 359.
[3] 柏 艳，党东宾，王敬平等. 第四届全国配位化学会议论文集. 桂林，2001. 146.
[4] 柳士忠，王 娟，张凌云等. 第四届全国配位化学会议论文集. 桂林，2001. 159.
[5] 柳士忠，张凌云，张贞文. 第四届全国配位化学会议论文集. 桂林，2001. 166.
[6] LIN Zhi-hua, ZHANG Han-hui, GUO Chung-hua et al(林志华，张汉辉，郭春华等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2002, 22(5): 752.
[7] LIN Zheng-zhong, ZHANG Han-hui, YANG Rong-sheng et al(林郑忠，张汉辉，杨融生等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2000, 20(5): 593.
[8] ZHAO Shi-long, ZHANG Han-hui, HUANG Chang-cang(赵士龙，张汉辉，黄长沧). Chemical Journal of Chinese Universities(高等学校化学学报)，2002, (4): 525.
[9] LIN Zheng-zhong, ZHANG Han-hui, HUANG Chang-cang(林郑忠，张汉辉，黄长沧). Chinese Journal of Structural Chemistry(结构化学)，2001, 20(6): 447.
[10] LIN Zheng-zhong, ZHANG Han-hui, HUANG Chang-cang(林郑忠，张汉辉，黄长沧). Chinese Journal of Structural Chemistry(结构化学)，2002, 21(1): 42.
[11] SUN Rui-qing, ZHANG Han-hui, ZHAO Shi-long et al(孙瑞卿，张汉辉，赵士龙等). Chinese Journal of Structural Chemistry(结构化学)，2001, 20(5): 413.
[12] ZHAO Shi-long, ZHANG Han-hui, HUANG Chang-cang et al(赵士龙，张汉辉，黄长沧等). Chinese Journal of Structural Chemistry(结构化学)，2001, 20(6): 451.
[13] HE Xiao-wei, LIU Xiao-ying(贺晓唯，刘晓英). Chinese Journal of Analytical Laboratory(分析试验室)，1996, 15: 63.
|
| [1] |
SUN Rui-qing, SHI Lin, CHEN Yi-ping*, SUN Yan-qiong. Syntheses and Spectral Study of the Polyoxosilicotungstate and Its Complex Reaction With RhB[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2455-2461. |
| [2] |
PAN Ying-min1, CHEN Yi-ping1, 2*, SHI Lin1, GONG Zhi-hui1, BI Wen-chao1, SUN Yan-qiong1. Two-Dimensional Infrared Spectroscopic Study of Three Isomorphic Rare Earth/Polyoxotungstates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2104-2109. |
| [3] |
SUN Rui-qing, LIU Ting-yu, CHEN Yi-ping*, PAN Ying-min, LIN Hui-yun, SUN Yan-qiong. Syntheses and Spectral Experiment of Two Novel Polyoxotungstates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3514-3519. |
| [4] |
SONG Gui-xian1, TANG Qing2, HUANG Ying2*, ZHANG Jian-xin3, TAO Zhu1, XUE Sai-feng1, ZHU Qian-jiang1, WEI Gang4*. Interaction of Cucurbit[8]uril with β-Indoleacetic Acid and Methylviologen[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3134-3139. |
| [5] |
FENG Chang-gen1, XIONG Yu-di1, LIU Xia2. Synthesis, Spectroscopy and Antibacterial Activity of Charge Transfer Complexes of Heteropolytungstate Containing Sulfanilamide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(06): 1441-1445. |
| [6] |
HE Xiao-song1, LIU Xiao-yu2, WEI Dong3, WEI Zi-min1*, XI Bei-dou2, JIANG Yong-hai2, LI Ming-xiao1, YANG Tian-xue1. Fluorescence Spectroscopic Chracterization of the Complexation between Mercury(Ⅱ) and Dissolved Organic Matter [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(08): 2204-2207. |
| [7] |
SI Wen-hui1, ZI Yan-qin2. Studies on the Interaction between RNA with Methyl Violet and Determination of RNA by Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(11): 1846-1849. |
| [8] |
CHEN Yi-ping1，ZHAO Shi-long1，ZHANG Han-hui1，2*，SUN Rui-qing1，YANG Qi-yu1 . Spectral Study of Three Compounds of Tungstosilicic Salt with Keggin Structure [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 257-260. |
|
|
|
|
