光谱学与光谱分析 |
|
|
|
|
|
Synthesis, Spectroscopy and Antibacterial Activity of Charge Transfer Complexes of Heteropolytungstate Containing Sulfanilamide |
FENG Chang-gen1, XIONG Yu-di1, LIU Xia2 |
1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China 2. College of Science, China Agricultural University, Beijing 100193, China |
|
|
Abstract Two charge transfer complexes of heteropolytungstate with Keggin structure, (C6H9N2O2S)3PW12O40·6H2O (SPW12) and (C6H9N2O2S)4SiW12O40·5H2O (SSiW12) were synthesized with 12-tungstophosphoric (silicic) acid and sulfanilamide in aqueous phase. The title complexes were characterized by means of elementary analysis, FTIR, UV, 1H NMR, XRD and TG-DSC. The results indicate that the title complexes are new heteropoly compounds, and the UV results reveal that there is a charge transfer interaction between sulfanilamide and heteropoly anion. Thermal analysis shows that the process of mass loss of the title complexes is carried out in four stages, and the two complexes begin to decompose at 272.8 ℃ and 330.4 ℃, respectively. The intermediates of the thermal decomposition were identified by FTIR. Antibacterial test results show that the title complexes both have good antibacterial activity, and the inhibition rate of SPW12 to Escherichia coli, Staphylococcus aurous is 73.28% and 99.36%, respectively.
|
Received: 2009-08-29
Accepted: 2009-12-02
|
|
Corresponding Authors:
FENG Chang-gen
E-mail: cgfeng@cast.org.cn
|
|
[1] Yamaguchi K, Kamata K, Yamaguchi S, et al. Journal of Catalysis, 2008, 258(1): 121. [2] XIONG Yu-di, LIU Xia, FENG Chang-gen(熊宇迪,刘 霞,冯长根). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(1): 231. [3] Mitsui S, Ogata A, Yanagie H, et al. Biomedecine & Pharmacotherapy, 2006, 60(7): 353. [4] WANG Li, WANG Fang, LIU Zong-rui(王 力,王 芳,刘宗瑞). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2008,28(9):2130. [5] WANG Dun-jia, WEI Xian-hong, FANG Zheng-dong(汪敦佳,魏先红,方正东). Journal of Chemical Industry Engineering(化工学报), 2007, 58(3): 646. [6] Ajibade P A, Kolawole G A, O’Brien P, et al. Inorganica Chimica Acta, 2006, 359(10): 3111. [7] LIU Xia, ZHAO Jun, FENG Chang-gen(刘 霞,赵 军,冯长根). Acta Chimica Sinica(化学学报), 2006, 64(19): 1988. [8] DENG Ling-juan, YANG Chun(邓玲娟,杨 春). Journal of Nanjing Normal University(Natural Science)(南京师范大学学报·自然科学版), 2006, 29(1): 48. [9] DU Jian-ke, YANG Rong-jie(杜建科,杨荣杰). Transactions of Beijing Institute of Technology(北京理工大学学报), 2007, 27(4): 358. [10] Ito T, Inumaru K, Misono M. J. Phys. Chem. B, 1997, 101(48): 9958. [11] FENG Jiang-hua, LI Xiao-jing, JING Feng-ying, et al(冯江华,李晓晶,景凤英,等). Acta Chimica Sinica(化学学报), 2000, 58(4): 423. [12] FANG Guang-rong, ZHU Yuan-yuan, DU Chun-fang, et al(方光荣,祝媛媛,杜春芳,等). Journal of Molecular Science(分子科学学报), 2006, 22(6): 367. [13] Pizzio L R, Blanco M N. Microporous and Mesoporous Materials, 2007, 103(1-3): 40.
|
[1] |
FAN Dan-yang1, ZHANG Xue-cheng1, GAO Jun1, WANG Jia-bin2, LÜ Hai-xia1*. Study on Specific Detection of Sulfadimethoxine Based on Aptamer-Modified Up-Conversion Fluorescent Nanomaterial[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3409-3414. |
[2] |
SUN Rui-qing, SHI Lin, CHEN Yi-ping*, SUN Yan-qiong. Syntheses and Spectral Study of the Polyoxosilicotungstate and Its Complex Reaction With RhB[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2455-2461. |
[3] |
XU Ning1, 2, LIU Mu-hua1, 2, YUAN Hai-chao1, 2, HUANG Shuang-gen1, 2, WANG Xiao1, 2, ZHAO Jin-hui1, 2*, CHEN Jian1, 2, WANG Ting1, 2, HU Wei1, 2, SONG Yi-xin1, 2. Rapid Identification of Sulfamethazine and Sulfadiazine Residues in Chicken Based on SERS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 924-931. |
[4] |
PAN Ying-min1, CHEN Yi-ping1, 2*, SHI Lin1, GONG Zhi-hui1, BI Wen-chao1, SUN Yan-qiong1. Two-Dimensional Infrared Spectroscopic Study of Three Isomorphic Rare Earth/Polyoxotungstates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2104-2109. |
[5] |
YANG Lei, LIN Bin-bin, ZHENG Qi-wei, WU Shu-lan, ZHENG Bing-yun, ZHU Zhi-fei, HU Wen-ying. Its Photochemical Recognition to Hg2+ and Preparation of Nitrogen and Sulfur-Codoped Carbon Dots by Sulfanilamide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(11): 3388-3394. |
[6] |
SUN Rui-qing, LIU Ting-yu, CHEN Yi-ping*, PAN Ying-min, LIN Hui-yun, SUN Yan-qiong. Syntheses and Spectral Experiment of Two Novel Polyoxotungstates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3514-3519. |
[7] |
LIU Ju-tao, LU Yan-fei, FAN Sheng-di. Synthesis, Spectroscopic Characterization and Antitumoral Activities of Cyclopentadienylvanadium Derivatives of Polyoxotungstates [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(09): 2512-2514. |
[8] |
WANG Yan-lou1,2,FU Xu-chun3,LEI Qun-fang1,CHEN Wei1,WANG Guo-ping1*. Synthesis, Spectral Analysis, Antibacterial and Antitumor Activities of Co(Ⅱ) and Ni(Ⅱ) Ofloxacin Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(10): 2388-2391. |
[9] |
WANG Zhan-hui,ZHANG Su-xia,SHEN Jian-zhong*. Development of a Fluorescence Polarization Immunoassay for Sulfamerazine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(07): 1621-1625. |
[10] |
WANG Yi-bing,WU Wei-hong,LU Fei,WANG Hai-shui*,XI Shi-quan. Preparation and Structural Characterization of mixed LB Films of TMB·TCNQ and Stearic Acid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(05): 1140-1144. |
[11] |
XIONG Yu-di1,LIU Xia2,FENG Chang-gen1*. Study on Applications of Heteropoly Acids (Blue) Spectrophotometry to Determination of Trace Elements[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(01): 231-234. |
[12] |
DONG Xiao-li,ZHANG Zhen-cheng,AN Qing-da*,ZHANG Shao-yin,WANG Shao-jun*. New Iron-Porphyrin/Vanadium-Substituted Polyoxometalate Catalyst: Synthesis, Characterization and Catalytic Activity[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(12): 2562-2565. |
[13] |
LIU Xia1,ZHAO Jun2,FENG Chang-gen2*,LI Hong-zhen3. Synthesis and Spectral Study of Amine Salt of Tungstovanadophosphoric Heteropolyacid with Dawson Structure [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(08): 1584-1586. |
[14] |
LIU Hui-jun1,XU Wei-jian2,LIU Yao-chi1,XIONG Yuan-qin2 . Preparation and Spectral Characteristic of Molecularly Imprinted Polymers for Sulfamethazine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(08): 1596-1599. |
[15] |
YU Yun, SHI Wen-jian*,YANG Ning-fei. Study and Spectrophotometric Determination of Nitrite with Sulfanilamide and N-Phenyl J-Acid System [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(03): 573-576. |
|
|
|
|