光谱学与光谱分析 |
|
|
|
|
|
Applications of Near-Infrared Spectroscopy to Analysis of Traditional Chinese Herbal Medicine |
LI Yan-zhou,MIN Shun-geng,LIU Xia* |
College of Science, China Agricultural University, Beijing 100094, China |
|
|
Abstract Analysis of traditional Chinese herbal medicine is of great importance to its quality control. Conventional analysis methods can not meet the requirement of rapid and on-line analysis because of complex process more experiences or needed. In recent years, near-infrared spectroscopy technique has been used for rapid determination of active components, on-line quality control, identification of counterfeit and discrimination of geographical origins of herbal medicines and so on, due to its advantages of simple pretreatment, high efficiency, convenience to use solid diffuse reflection spectroscopy and fiber. In the present paper, the principles and methods of near-infrared spectroscopy technique are introduced concisely. Especially, the applications of this technique in quantitative analysis and qualitative analysis of traditional Chinese herbal medicine are reviewed.
|
Received: 2007-05-10
Accepted: 2007-08-20
|
|
Corresponding Authors:
LIU Xia
E-mail: liuxia6680@sohu.com
|
|
[1] LU Wan-zhen, YUAN Hong-fu, XU Guang-tong, et al(陆婉珍, 袁洪福, 徐广通等). Modern Analysis Technique of Near Infrared Spectra(现代近红外光谱分析技术). Beijing:Chinese Petrochemical Press(北京:中国石化出版社), 2000:69. [2] (a) LU Yong-jun, QU Yan-ling, PIAO Ren-guan, et al(芦永军, 曲艳玲, 朴仁官, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(2):158. (b)LI Yan-zhou, MIN Shun-geng, LIU Xia(李彦周,闵顺耕,刘 霞). Journal of Analytical Chemistry(分析化学),2001,35(9):1331. [3] Kennard R W, Stone L A. Technometrics, 1969, 11(1):137. [4] WU Jing-zhu, WANG Yi-ming, ZHANG Xiao-chao, et al(吴静珠, 王一鸣, 张小超, 等). Transactions of the Chinese Society for Agricultural Machinery(农业机械学报), 2006, 37:80. [5] Inge S. Helland, Tormod Ns, Tomas Isaksson. Chemometrics and Intelligent Laboratory Systems, 1995, 29:233. [6] TIAN Gao-you, YUAN Hong-fu, LIU Hui-ying, et al(田高友, 袁洪福, 刘慧颖, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(6):1111. [7] Barnes R J, Dhanoa M S, Lister S J. Applied Spectroscopy, 1989, 43:772. [8] Svante Wold, Henrik Antti, Fredrik Lindgren, et al. Chemometrics and Intelligent Laboratory Systems, 1998, 44:175. [9] Vapnik V. Statistical Learning Theory. New York:Wiley-Interscience Publication, 1998. [10] ZHANG Lu-da, JIN Ze-chen, SHEN Xiao-nan, et al(张录达, 金泽宸, 沈晓南, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(9):1400. [11] Johnson S C. Psychometrika, 1967, 32:241. [12] Hartigan John, M Athony Wong. Applied Statistics, 1979, 28:100. [13] Athony Wong M, Tom Lane. Journal of the American Statis. Asso., 1983, 45:362. [14] YANG Nan-lin, QU Hai-bin, CHENG Yi-yu(杨南林,瞿海斌,程翼宇). Journal of Zhejiang University(Engineering Science)(浙江大学学报·工学版),2002,36(4):463. [15] YANG Nan-lin, CHENG Yi-yu, WU Yong-jiang(杨南林,程翼宇,吴永江). Acta Chimica Sinica(化学学报),2003, 61(3):393. [16] LIU Xue-song, QU Hai-bin, CHENG Yi-yu. Chem. Research in Chinese Universities, 2005, 21(1):36. [17] REN Gui-xing, CHEN Feng. J. Agri. Food Chem., 1999, 47(7):2771. [18] LU Yong-jun, QU Yan-ling, CAO Zhi-qiang, et al(芦永军, 曲艳玲, 曹志强, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(8):1457. [19] LU Yong-jun, QU Yan-ling, FENG Zhi-qing, et al(芦永军, 曲艳玲, 冯志庆, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(3):490. [20] LIU Li-li, XING Wang-xing, JIA Nuan, et al(刘荔荔, 邢旺兴,贾 暖, 等). China Journal of Chinese Materia Medica(中国中药杂志), 2003, 28(2):178. [21] CHEN Bin, ZHAO Long-lian, LI Jun-hui, et al(陈 斌, 赵龙莲, 李军会, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(6):976. [22] QU Hai-bin, LIU Quan, CHENG Yi-yu(瞿海斌,刘 全,程翼宇). Chinese Journal of Analytical Chemistry(分析化学), 2004, 32(4):477. [23] BAI Yan, YU Zhen-xi, SUN Su-qin, et al(白 雁,余振喜,孙素琴, 等). Chinese Traditional and Herbal Drugs(中草药),2005, 36(9):1391. [24] HU Gang-liang, L Xiu-yang, LUO Ling, et al(胡钢亮,吕秀阳,罗 玲, 等). Chinese Journal of Analytical Chemistry(分析化学), 2004, 32(8):1061. [25] WANG Li, HE Ying, QIU Zhao-chai, et al(王 丽, 何 鹰, 邱招钗, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(9):1397. [26] YU Xiao-hui, ZHANG Zhuo-yong, MA Qun, et al(于晓辉, 张卓勇, 马 群, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(3):481. [27] SONG Li-li, XU Xiao-jie, FAN Bing-yi, et al(宋丽丽,徐晓杰,范丙义, 等). Chinese Traditional and Herbal Drugs(中草药), 2005, 36(8):1174. [28] YANG Nan-lin, CHENG Yi-yu, QU Hai-bin(杨南林,程翼宇, 瞿海斌). Acta Chimica Sinica(化学学报),2003, 61(5):742. [29] LIU Quan, QU Hai-bin, CHENG Yi-yu(刘 全,瞿海斌,程翼宇). Journal of Chemical Indurstry and Engineering(China)(化工学报),2003, 54(11):1586. [30] QU Hai-bin, LI Bin, LIU Xue-song, et al(瞿海斌,李 斌,刘雪松, 等). Chin. Pharm. J.(中国药学杂志),2005,40(24):1897. [31] Yang-ah Woo, Chang-hee Cho, Hyo-jin Kim, et al. Microchemical Journal, 2002, 73:299. [32] LIU Shu-hua, ZHANG Xue-gong, SUN Su-qin. Chinese Science Bulletin, 2005, 50(2):179. [33] LIU Shu-hua, ZHANG Xue-gong, ZHOU Qun, et al(刘沭华,张学工,周 群, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006, 26(4):629. [34] Yang-ah Woo, Hyo-jin Kim, JungHwan Cho, et al. Journal of Pharmaceutical and Biomedical Analysis, 1999,21:407. [35] Yang-Ah Woo, Hyo-Jin Kim, Keum-Ryon, et al. Journal of Pharmaceutical and Biomedical Analysis, 2005, 36:955. [36] YU Ke, CHENG Yi-yu(虞 科,程翼宇). Chinese Journal of Analytical Chemistry(分析化学),2006, 34(4):561. [37] Yang-ah Woo, Hyo-jin Kim, Jung Hwan Cho. Microchemical Journal, 1999, 63:61. [38] MAO Jian-jiang, XU Jing-wei. Spectrochimica Acta Part, A-Molecular and Biomolecular Spectroscopy, 2006, 65:497. [39] XIAO Jie, WU Yu-tian, LEI Chang-hai(肖 杰,吴玉田,雷长海). Chinese Journal of Analytical Chemistry(分析化学), 2003, 31(11):1295. [40] Magali Laasonen, Tuulikki Harmia-Pulkkinen, Christine L Simard. Analytical Chemistry, 2002, 74(11):2493. [41] LIU Guo-lin, CAI Jin-na, LI Wei, et al(刘国林,蔡金娜,李 伟, 等). Computers and Applied Chemistry(计算机与应用化学),2000, 17(2):109. [42] WU Yong-jun, LI Wei, XIANG Bing-ren, et al(吴拥军,李 伟,相秉仁). Journal of Chinese Medicinal Materials(中药材),2001,24(1):26. [43] LIU Li-li, YUAN Yuan, CHEN Wan-sheng, et al(刘荔荔,原 源,陈万生, 等). Chinese Traditional and Herbal Drugs(中草药),2001, 32(11):1024. [44] XIANG Lan, FAN Guo-qiang, LI Jun-hui, et al. Phytochemical Analysis, 2002, 13:272. [45] TANG Yan-feng, ZHANG Zhuo-yong, FAN Guo-qiang(汤彦丰,张卓勇,范国强). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(11):1348. [46] YANG Hai-lei, LIU Xue-song, QU Hai-bin, et al(杨海雷,刘雪松,瞿海斌, 等). Chinese Traditional and Herbal Drugs(中草药), 2005, 36(6):912. [47] GAO Yue, CAI Yi-feng, WU Yu-tian(高 越,柴逸峰,吴玉田). Chinese Traditional Patent Medicine(中成药),2005, 27(12):1440. [48] LIU Xue-song, CHENG Yi-yu(刘雪松,程翼宇). Acta Chimica Sinica(化学学报),2005, 63(24):2216. [49] YAN Shi-kai, LUO Guo-an, WANG Yi-ming, et al(严诗楷,罗国安,王义明, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006, 26(6):1026. |
[1] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
[2] |
BAO Hao1, 2,ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
[3] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
[4] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
[5] |
HU Cai-ping1, HE Cheng-yu2, KONG Li-wei3, ZHU You-you3*, WU Bin4, ZHOU Hao-xiang3, SUN Jun2. Identification of Tea Based on Near-Infrared Spectra and Fuzzy Linear Discriminant QR Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3802-3805. |
[6] |
LIU Xin-peng1, SUN Xiang-hong2, QIN Yu-hua1*, ZHANG Min1, GONG Hui-li3. Research on t-SNE Similarity Measurement Method Based on Wasserstein Divergence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3806-3812. |
[7] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1,ZHAO Yan-jie1*,NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
[8] |
LUO Li, WANG Jing-yi, XU Zhao-jun, NA Bin*. Geographic Origin Discrimination of Wood Using NIR Spectroscopy
Combined With Machine Learning Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3372-3379. |
[9] |
ZHANG Shu-fang1, LEI Lei2, LEI Shun-xin2, TAN Xue-cai1, LIU Shao-gang1, YAN Jun1*. Traceability of Geographical Origin of Jasmine Based on Near
Infrared Diffuse Reflectance Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3389-3395. |
[10] |
YANG Qun1, 2, LING Qi-han1, WEI Yong1, NING Qiang1, 2, KONG Fa-ming1, ZHOU Yi-fan1, 2, ZHANG Hai-lin1, WANG Jie1, 2*. Non-Destructive Monitoring Model of Functional Nitrogen Content in
Citrus Leaves Based on Visible-Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3396-3403. |
[11] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
[12] |
HUANG Li, MA Rui-jun*, CHEN Yu*, CAI Xiang, YAN Zhen-feng, TANG Hao, LI Yan-fen. Experimental Study on Rapid Detection of Various Organophosphorus Pesticides in Water by UV-Vis Spectroscopy and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3452-3460. |
[13] |
HUANG Meng-qiang1, KUANG Wen-jian2, 3*, LIU Xiang1, HE Liang4. Quantitative Analysis of Cotton/Polyester/Wool Blended Fiber Content by Near-Infrared Spectroscopy Based on 1D-CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3565-3570. |
[14] |
HUANG Zhao-di1, CHEN Zai-liang2, WANG Chen3, TIAN Peng2, ZHANG Hai-liang2, XIE Chao-yong2*, LIU Xue-mei4*. Comparing Different Multivariate Calibration Methods Analyses for Measurement of Soil Properties Using Visible and Short Wave-Near
Infrared Spectroscopy Combined With Machine Learning Algorithms[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3535-3540. |
[15] |
KANG Ming-yue1, 3, WANG Cheng1, SUN Hong-yan3, LI Zuo-lin2, LUO Bin1*. Research on Internal Quality Detection Method of Cherry Tomatoes Based on Improved WOA-LSSVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3541-3550. |
|
|
|
|