| 光谱学与光谱分析 |
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| Partial Least-Squares Regression Analysis for Simultaneous Spectrophotometric Determination of Fe3+ and Al3+ |
| PENG Shu-chuan,HUANG Chuan-hui,CHEN Tian-hu,JIANG Shao-tong, FENG You-liang |
| School of Resources and Environment, Hefei University of Technology, Hefei 230009, China |
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Abstract Adding hexodecyltrimethylammonium bromide(CTMAB) to improve solubility and delicacy, and using chromazurol S as a chromogenic reagent, and acetone as a stabilizing reagent, partial least-squares regression(PLS) was used to determine simultaneously trace amounts of Fe(Ⅲ) and Al(Ⅲ) in sythetic samples. Considering the stability of the rays, and the absorption properties of the two ingredients, seven wavelengths between 610 and 670 nm were selected for data collection. As a comparison, the methods of CPA and PLS were used respectively for analysing the data obtained from the experiment, and the results suggested that the latter was much better.
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Received: 2003-10-18
Accepted: 2004-03-06
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Corresponding Authors:
PENG Shu-chuan
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| Cite this article: |
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PENG Shu-chuan,HUANG Chuan-hui,CHEN Tian-hu, et al. Partial Least-Squares Regression Analysis for Simultaneous Spectrophotometric Determination of Fe3+ and Al3+ [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(06): 942-944.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2005/V25/I06/942 |
[1] WANG Hui-wen(王惠文). Partial Least-Squares Regression Method and Applications(偏最小二乘回归法及其应用). Beijing: National Defence Industry Press(北京：国防工业出版社)，1999. 1.
[2] LIU De-long, MA Li-mei(刘德龙，马丽梅). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001，21(3)：353.
[3] DONG Hui-ru, ZHU Hong-bo(董慧茹，朱洪波). Chinese J. Anal. Chem. (分析化学)，1991，19(4)：474.
[4] WANG Hui-wen(王惠文). Partial Least-Squares Regression Method and Applications(偏最小二乘回归法及其应用). Beijing: National Defence Industry Press (北京：国防工业出版社)，1999. 150.
[5] ZHOU Tong, ZHONG Jia-yue, FENG Jiang(周 彤，钟家跃，冯 江). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2004，24(5)：616.
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