光谱学与光谱分析 |
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Fluorescence Spectra and Photo-Generating Rate of Singlet Oxygen of Phthalocyaninatopalladium |
XU Xiu-zhi,WANG Jun-dong,FANG Xin,CHEN Nai-sheng*,HUANG Jin-ling |
Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou 350002, China |
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Abstract The absorption spectral properties, fluorescence spectral properties and the abilities of photo-generating singlet oxygen of four phthalocyanines, namely tetra-α-(2,2,4-trimethyl-3-pentoxy) phthalocyaninatopalladium (zinc) and tetra-α-(2,4-diterbutylphenoxy) phthalocyaninatopalladium (zinc), were determined. Experimental results show that the ability of photo-generating singlet oxygen of phthalocyaninatopalladium is similar to that of phthalocyaninatozincx, though palladium(Ⅱ) is an open shell electron structure and zinc(Ⅱ) is a closed shell structure. This may be concerned with a weak flourescence intensity and a strong inter-crossing transition of phthalocyaninatopalladium.
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Received: 2005-10-08
Accepted: 2006-01-18
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Corresponding Authors:
CHEN Nai-sheng
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Cite this article: |
XU Xiu-zhi,WANG Jun-dong,FANG Xin, et al. Fluorescence Spectra and Photo-Generating Rate of Singlet Oxygen of Phthalocyaninatopalladium[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(12): 2280-2282.
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URL: |
https://www.gpxygpfx.com/EN/Y2006/V26/I12/2280 |
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