| 光谱学与光谱分析 |
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| Synthesis and Characterization of Phenyl-Acetylmethylene Sulfoxide Complexes with Light Rare Earth and Fluorescence Spectrum of Eu(Ⅲ) Complex |
| LI Wen-xian, WANG Hong-sheng, QI Qi-ge, ZHANG Rui-ping |
| College of Chemistry and Chemical Industry, Inner Mongolia University, Huhhot 010021, China |
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Abstract Five solid complexes of phenyl-acetylmethylene sulfoxide(L) with light rare earth(La, Pr, Nd, Sm, Eu) were synthesized and characterized. Elemental analysis and molar conductivities show that the complexes have a composition of RE(ClO4)3·L5·2H2O; two ClO-4 anions coordinated with rare earth ions and the other did not. IR spectra suggested that the ligand coordinated with RE3+ by oxygen atom in sulfinyl group, and the oxygen atom in carbonyl group did not bond. The phosphorescence and 1H NMR and TG-DTA of the ligand and complexes were determind. Fluorescence spectra of Eu(Ⅲ) complex with the sulfoxide indicated that the complex has no symmetrical center. All the complexes have good solubility.
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Received: 2004-08-23
Accepted: 2005-01-16
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Corresponding Authors:
LI Wen-xian
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| Cite this article: |
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LI Wen-xian,WANG Hong-sheng,QI Qi-ge, et al. Synthesis and Characterization of Phenyl-Acetylmethylene Sulfoxide Complexes with Light Rare Earth and Fluorescence Spectrum of Eu(Ⅲ) Complex [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(01): 30-32.
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https://www.gpxygpfx.com/EN/Y2006/V26/I01/30 |
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